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The History of the Atom Democritus 400 BC • Greek philosopher • Believed matter could be cut and cut until you get the smallest possible piece • The smallest piece would be called atomis • The eminent philosophers of the time, Aristotle and Plato, had a more respected, (and ultimately wrong) theory. Why? Aristotle and Plato favored the earth, fire, air and water approach to the nature of matter. Their ideas held sway because of their eminence as philosophers. The atomos idea was buried for approximately 2000 years. Dalton 1803 • Father of the atomic theory • Resurrected Democritus's idea of atoms • He thought the atom looked like a billard ball! How do the ideas compare? The big question…. • If it wasn’t Dalton’s idea to begin with…. Why is he called the father of the atomic theory? Dalton’s Atomic Theory • 1) All elements are composed of atoms, which are indivisible and indestructible particles. • 2) All atoms of the same element are exactly alike; in particular, they all have the same mass. • 3) All atoms of different elements are different; in particular, they have different masses. • 4) Compounds are formed by the joining of atoms of two or more elements. In any compound , the atoms of the different elements in the compound are joined in a definite whole-number ratio, such as 1 to 1, 2 to 1, 3 to 2, etc. What does it mean? • Each element is made of a different kind of atom • Atoms combine to form compounds. • When they form compounds they combine in specific ratios- such as water is always 2 hydrogens and 1 oxygen! Thomson- 1897-1898 Thomson agreed with Dalton that everything was made of atoms He discovered the electron He proved that the atom was not indestructible and was not indivisible- instead it could be broken down into smaller parts. It was a great idea but….. • Thomson faced two major problems: • 1. How could he account for the mass of the atom when the electron was only about 1/1000 the mass of the hydrogen atom (the more modern figure is 1/1836) • 2. How could he create a neutral atom when the only particle he knew about was negatively charged (the electron). The plum pudding model • He predicted that something else would be discovered to account for the mass of the atom • He predicted that the atom would have a positive part. Rutherford-1908-1911 • Ernst Rutherford proved that the atom did have a positive part (Thomson's idea) • He discovered the positive nucleus of the atom • He discovered the proton How did he make his discovery? • His experiment is now famous! • http://chemmovies.unl.edu/ChemAnime/RUT http://chemmovies.unl.edu/ChemAnime/R HERFD/RUTHERFD.html UTHERFD/RUTHERFD.html What else did Rutherford discover? • Rutherford proved that the majority of the atom is empty space! Bohr-1913 • Neils Bohr discovered that the electrons move in energy levels The Bohr Model • The Bohr Model of the atom is still used today in science classes! Heisenburg- 1927 • Thomson was correct- the electrons move in energy levels but they move so quickly that you can’t be certain where they are… • Heisenburg discovered that electrons move so quickly they form an electron cloud! What does his model look like? Chadwick-1932 Even though both protons and electrons had been discovered, scientists still couldn’t determine why the atom had such a large mass. Chadwick discovered the answer when he discovered the neutron Scientists through time discovered the atom has three main subatomic particles • The proton is positive and has an atomic mass of 1 amu (and is in the nucleus) • The electron is negative and has relatively no mass at all (and orbits the nucleus) • The neutron is neutral and has a mass of 1 amu (and is in the nucleus) It didn’t end there… • Kendall- Friedman and Taylor • 1968-1969 • Discovered that protons and neutrons were made of smaller particles • The particles are called quarks The proton The neutron What do we now know? Atoms are the building block of all matter • An Atom is the smallest part of an element which can take part in a chemical reaction. • The atom consists of three fundamental particles- the proton, the neutron and the electron The main subatomic particles • The Proton has mass of approximately 1 atomic mass unit and a positive charge, • The Neutron has a mass of approximately 1 atomic mass unit and no charge • The Electron has a mass 1/1840 of the proton and a negative charge. Atoms make up elements • Each element is made up of one kind of atom only. Just over one hundred different kinds of atoms are known. • Ninety of these elements are naturally occurring (i.e. they are found on the earth), and the remainder have been made artificially in nuclear reactors. There is still more to be discovered…. What will the model we know change with the new discoveries?