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Transcript
Indo German Winter Academy 06
Future Memory Devices
By
Pratik Kotkar
Dept. Of Electronics and Communication Engg.
IIT Guwahati
under the guidance of Prof. Heiner Ryssel, University of
Erlangen-Nuremberg
1
The Topic
Indian Institute of Technology,
Guwahati
Indo German Winter Academy 06
ƒ What are memory devices?
ƒ Development cycle
1.
Past and present memory devices
2.
Comparison of the trends in development
ƒ Requirements of future devices
ƒ Some materials that can be used in the future
1.
Analysis of each material
2.
Advantages and disadvantages
3.
Comparative study
ƒ Summary
2
An Overview
Indian Institute of Technology,
Guwahati
Indo German Winter Academy 06
ƒ What are memory devices ?
ƒ Development cycle
ƒ Requirements of future devices.
ƒ Some materials that can be used in the future
ƒ Summary
3
An Overview
Indian Institute of Technology,
Guwahati
Indo German Winter Academy 06
ƒ Memory
ƒ Memory is the retention of, and ability to recall, information, personal
experiences, and procedures
ƒ Data storage for any processor
ƒ Physical memory vs. virtual memory
ƒ RAM vs. ROM:
RAM
4
ROM
• Memory can be accessed in any
order
• Class of storage that cannot be
written to
• Read and write allowed
• Contents close to hardware
• Primary data storage
• Programmable types
• SRAM, DRAM etc.
• PROM, EPROM, EEPROM etc.
What are Memory Devices?
Indian Institute of Technology,
Guwahati
Indo German Winter Academy 06
ƒ What are memory devices ?
ƒ Development cycle
ƒ Requirements of future devices
ƒ Some materials that can be used in the future
ƒ Summary
5
An Overview
Indian Institute of Technology,
Guwahati
Indo German Winter Academy 06
Development of Memory Devices :
ƒ Vacuum Tubes
ƒ A device generally used to amplify, or otherwise
modify, a signal by controlling the movement of
electrons in an evacuated space
ƒ Based on Thermionic Emission (Edison Effect)
ƒ Diode and Triode types
ƒ Transistors
ƒ A semiconductor device that uses a small amount
of voltage or electrical current to control a larger
change in voltage or current
ƒ BJT and FET
ƒ Uses: Switching, Amplification
ƒ Using in memory
6
Evolution of Memory (Past)
Indian Institute of Technology,
Guwahati
Indo German Winter Academy 06
Current IC Technology:
ƒ Miniaturized electronic circuit consisting mainly of semiconductor devices, as
well as passive components manufactured into the surface of a thin substrate
of a semiconductor
ƒ SRAMS
ƒ Type of memory that stores data till
power is applied to it
ƒ It uses a “6- transistor” per bit type
storage facility
ƒ Advantages: High speed & no
refresh needed
ƒ Disadvantages: Power needs & low
density
7
ƒ DRAMS
ƒ Type of memory that stores data till
power is applied to it but leaks out fast
ƒ It uses a capacitor to store each data
bit
ƒ Advantages: Simplicity & high density
ƒ Disadvantages: Low speed & refresh
required frequently
Evolution of Memory Devices
Indian Institute of Technology,
Guwahati
Indo German Winter Academy 06
ƒ What are memory devices?
ƒ Development cycle
ƒ Requirements of future devices
ƒ Some materials that can be used in the future
ƒ Summary
8
An Overview
Indian Institute of Technology,
Guwahati
Indo German Winter Academy 06
ƒ Current Devices:
ƒ
ƒ
DDR , DDR 2 & SDRAM’s
1. SDRAMs wait for clock pulse before responding
2. Rated as per maximum clock rate allowed for a chip
3. SDRAM transfers data only positive edge
DDR 2 Module
4. DDR 2 doubles bus frequency for more speed
Flash Memory
1. Works on floating gate principal. MOSFET with two gates where
one is for control and other is insulated
2. Non volatile and more shock absorbing
3. Faster access times
ƒ Factors for improvement:
ƒ
ƒ
ƒ
9
Memory density
Volatility
High speed
Direction for Future Development
USB Flash Drive
Indian Institute of Technology,
Guwahati
Indo German Winter Academy 06
ƒ What are memory devices?
ƒ Development cycle
ƒ Requirements of future devices
ƒ Some materials that can be used in the future
ƒ Fe RAM
ƒ M-RAM
ƒ Phase change memory
ƒ Programmable metallization cell
ƒ Bi stable organic devices
ƒ Molecular memory
ƒ Summary
10
An Overview
Indian Institute of Technology,
Guwahati
Indo German Winter Academy 06
ƒ What is it?
Similar in construction to DRAM, which is currently used in the majority of a
computer‘s main memory, but uses a ferroelectric layer to achieve nonvolatility.
Ferroelectric capacitors possess the two characteristics required for a
nonvolatile memory cell, that is they have two stable states corresponding to
the two binary levels in a digital memory, and they retain their states without
electrical power.
ƒ Ferroelectricity:
ƒ Phenomenon which can be observed in a relatively
small class of dielectrics called ferroelectric materials
ƒ In a ferroelectric material, on the other hand, there is
a spontaneous polarization - a displacement which is
inherent to the crystal structure of the material
ƒ Does not disappear in the absence of the electric field
ƒ The direction of this polarization can be reversed or
reoriented by applying an appropriate electric field
11
Ferroelectric RAM
A FeRAM chip
Indian Institute of Technology,
Guwahati
Indo German Winter Academy 06
Binary state 0
Positive electric field
Positive polarization
Binary state 1
Negative electric field
Negative polarization
ƒ Working & principle:
ƒ Can be permanently programmed in two different states by simply applying an
electrical bias to the films
ƒ Electric field causes mobile ions to align along the applied field
ƒ The individual unit cells of the crystal interact with their neighboring cells to
form ferroelectric domains in the material
12
Ferroelectric RAM
Indian Institute of Technology,
Guwahati
Indo German Winter Academy 06
ƒ Materials used:
ƒ PbZrxTi1-xO3 (PZT)
ƒ SrBi2Ta2O9 (SBT)
ƒ (BiLa)4Ti3O12 (BLT)
ƒ 1 T - 1 C type cell:
ƒ
13
Read
- WL: addressed
- DL: addressed with positive
voltage +Vcc
- BL: capacitor divider between
Cfe and Cbl, sense amplifier
compares voltage with Vref
- V < Vref: Binary state 0
- V > Vref: Binary state 1
Ferroelectric RAM
ƒ
Write
- WL: addressed
- DL: pulse +VCC (half
length)
- BL:
+VCC: “1”, ground: ”0”
Indian Institute of Technology,
Guwahati
Indo German Winter Academy 06
Problems faced and disadvantages:
ƒ A decrease of the remanent polarization reduces the
difference between switching- and non-switching charge
ƒ Polarization fatigue (after repeated read-write cycles)
Fatigue
ƒ Retention loss (with time)
ƒ Imprint
ƒ shift of the hysteresis loop leads to preference of one
polarization state (write failure; only critical at low voltage)
or loss of polarization (read failure)
Loss
ƒ Increase of temperature leads to worse material properties
(i.e. defect distribution)
ƒ Reading operation is “destructive”
ƒ High quality semiconductor/ferroelectric material
14
Ferroelectric RAM
Imprint
Indian Institute of Technology,
Guwahati
Indo German Winter Academy 06
ƒ What is it?
ƒ Combines a magnetic device with standard silicon-based microelectronics to
obtain the combined attributes of non-volatility, high-speed operation and
unlimited read and write endurance not found in any other existing memory
technology
ƒ Magneto-resistivity:
ƒ Two ferromagnetic plates separated by a thin insulating
material
ƒ Each memory element uses a magnetic tunnel junction
(MTJ) device for data storage
ƒ Composed of a fixed magnetic layer, a thin dielectric tunnel
barrier, and a free magnetic layer
ƒ When a bias is applied to the MTJ, electrons that are spin
polarized by the magnetic layers traverse the dielectric
barrier through a process known as tunneling
ƒ The MTJ device has a low resistance when the magnetic
moment of the free layer is parallel to the fixed layer and a
high resistance when the free layer moment is oriented antiparallel to the fixed layer moment
15
Magneto-Resistive RAM
M-RAM
Indian Institute of Technology,
Guwahati
Indo German Winter Academy 06
ƒ Principle & Working:
ƒ Data is stored as a magnetic state, rather than charge
ƒ Sensed by measuring the resistance without disturbing
the magnetic state
ƒ Digit Lines and bit lines:
ƒ Used for cross point writing
ƒ ”Single line disturb” phenomena
ƒ Sense Transistor
ƒ Write:
Single Bit storage MRAM
ƒ During the write operation, current pulses are
passed through a digit line and a bit line, writing
only the bit at the cross point of those two lines
ƒ Read:
ƒ The isolation transistor of the target bit is turned
on to bias the MTJ and the resulting current is
compared to a reference to determine if the
resistance state is low are high
16
Magneto-Resistive RAM
MRAM array with bit and
digit lines
Indian Institute of Technology,
Guwahati
Indo German Winter Academy 06
ƒ Toggle M-RAM:
ƒ Through the use of a new free layer structure (SAF),
bit orientation and current pulse sequence, the MRAM
bit state can be programmed via a “toggle" mode
ƒ “toggle” means that exactly the same pulse sequence
is used to write from the “0” state to the “1” state and
for “1” to “0;”
ƒ Each time the sequence is executed the device toggles
ƒ Working:
Synthetic Anti
Ferromagnet(SAF)
ƒ Unique behavior of a synthetic anti ferromagnet (SAF)
free layer that is formed from two ferromagnetic layers
separated by a non-magnetic coupling spacer layer
ƒ Rather than following an applied magnetic field, the
two anti parallel layer magnetizations will rotate to be
approximately orthogonal to the applied field
ƒ A current pulse sequence is used to generate a rotating
magnetic field that moves the free-layer moments
through the 180° switch from one state to the other
17
Magneto-Resistive RAM
Indian Institute of Technology,
Guwahati
Indo German Winter Academy 06
ƒ Advantages:
ƒ Disadvantages:
ƒ the magnetic polarization does not leak
away with time like charge does, so
information is stored even when the
power is turned off
ƒ switching the magnetic polarization
between the two states does not involve
actual movement of electrons or atoms
and thus has no known wear-out
mechanism
ƒ Induced Field Overlap Issues
ƒ Power Needs in “read cycle”
are much higher for the high
voltage tunneling
ƒ The “toggle mode” gives
slower speeds due to its
“multi step” write process
ƒ Non volatile
ƒ Density and speed comparable to
DRAMs
ƒ When compared to FLASH drives it has
greater endurance and lower power
requirement in “write cycle” where
high voltage tunneling is not needed
18
Magneto-Resistive RAM
Indian Institute of Technology,
Guwahati
Indo German Winter Academy 06
ƒ What is it?
ƒ Resistor based approach
ƒ Relies on phase transitions induced by nanosecond-scale heating and cooling
of small volumes of chalcogenide films within the memory cell
ƒ 650 MB PD and CD-RW disks and 5.2 GB DVD-R optical memory disks using
a laser-induced structural phase change in a chalcogenide alloy are now in
production
ƒ Chalcogenides:
ƒ Collective name for group VI
elements in the periodic table
ƒ Property of stability at room
temperature in two forms
ƒ Example:
Alloys of GeSbTe in “pseudo
binary composition”
Group VI in the periodic table
19
Phase Change Memory
Indian Institute of Technology,
Guwahati
Indo German Winter Academy 06
ƒ Amorphous state (Reset state):
ƒ High resistivity
ƒ High current and fast quenching
ƒ Crystalline state (Set state)
ƒ Low resistivity
ƒ Medium current for longer pulse time
20
Phase Change Memory
Indian Institute of Technology,
Guwahati
Indo German Winter Academy 06
ƒ Principle and Working:
ƒ The phase conversion is accomplished by
heating and cooling the material
ƒ When melted it loses all crystalline structure,
and rapid cooling below glass transition
temperature causes the material to be locked
into its amorphous phase
ƒ To switch the memory element back to its
conductive state, the material is heated to a
temperature between the glass transition
temperature and the melting temperature
ƒ Set - reset transition:
ƒ No change for lower currents
ƒ Rapid change for I > 450 µA
ƒ The amorphous form is
established by rapid cooling on
the falling edge of pulse
21
I-R characteristics of PCM
ƒ Reset - set transition:
ƒ Resistance steeply decreases for
I >100 µA
ƒ Crystallization of GST
ƒ Very large currents lead it to
amorphous form again hence
medium currents are used
Phase Change Memory
Indian Institute of Technology,
Guwahati
Indo German Winter Academy 06
ƒ Use in memory Arrays:
ƒ An array of access transistors must each be
capable of providing sufficient power to a memory
element to melt a portion of the chalcogenide alloy
ƒ Thermal isolation of the memory element itself
from the heat-sinking substrate and metallization
is crucial
ƒ Three modes of operation:
VA
RC
D e v ic e
VA
RC
D e v ic e
Cn
VA
RC
D e v ic e
VA
RC
D e v ic e
C n+1
Row n
Row n+1
Memory Array using PCM’s
ƒ Read: The electric field is limited by applying a low voltage. A small current will
pass if the material is in the amorphous state; in the crystalline phase, the applied
voltage and the resistance of the contact will limit the current through the device
ƒ Set:
The voltage must be high enough to ensure that the alloy will switch into a
low impedance state. An intermediate current level will heat the material but not
melt it
ƒ Reset: The voltage must be high enough to ensure that the alloy will switch into a
low impedance state with sufficient current to heat a portion of the material above
its melting temperature. When the current is removed, the small volume of
material that has melted will rapidly quench into the amorphous state
22
Phase Change Memory
Indian Institute of Technology,
Guwahati
Indo German Winter Academy 06
ƒ Schematic configuration:
SiO2
Chalcogenide
SiO2
via
Thin
Contact
SiO2
Si
ƒ The bottom electrode contacts the chalcogenide alloy material, forming a ringshaped contact area
ƒ The chalcogenide alloy is deposited in the highly conductive crystalline phase
ƒ The region where phase transition occurs is limited to the chalcogenide material
immediately adjacent to the lower electrode
ƒ This reduction in the volume of material being melted reduces the power
requirement sufficiently to allow a minimum-feature-size MOS transistor to easily
control the device
23
Phase Change Memory
Indian Institute of Technology,
Guwahati
Indo German Winter Academy 06
ƒ Scaling of devices:
ƒ Main scaling limitation of a memory device based on a phase change alloy is
the minimum amount of material that can reliably undergo a phase transition
ƒ Power needed to operate the memory goes down dramatically as the device size
is decreased
ƒ Quenching time is roughly proportional to the device size as well
ƒ Advantages:
ƒ Non volatile memory . Since
crystallization energy is > 3.4 eV
it cant be provided at room
temperature
ƒ Disadvantages:
ƒ Proximity Disturbances
ƒ Stuck Cells:
ƒ Fast read and write cycles
ƒ Low voltage and moderate energy
consumption.
24
Phase Change Memory
- Over heating of cells reduces
cycling capability as cells are
“stuck in Set- State”
- High cycle failure leading to cell
“stuck in reset state” because of
open circuit at contact region
Indian Institute of Technology,
Guwahati
Indo German Winter Academy 06
ƒ What is it?
ƒ Programmable Metallization Cell (PMC) memory is based on the
electrochemical growth and removal of nanoscale metallic pathways in thin
films of solid electrolyte
ƒ Use a little-known feature of some amorphous materials that they can
incorporate relatively large amounts of metal and behave as solid electrolytes
ƒ Electrochemistry:
ƒ Oxidation as the losing of electrons and reduction as the gaining of
electrons
ƒ Accompany each other in redox reaction
ƒ Example:
- Reduction
Cu2+ + 2e− → Cu (E = +0.34 V)
- Oxidation
Zn → Zn2+ + 2e− (E = −0.76 V)
25
Programmable Metallization Cell
Indian Institute of Technology,
Guwahati
Indo German Winter Academy 06
ƒ Schematic configuration:
ƒ The electrodes are separated by a dielectric and a via in this layer defines the
electrolyte area that contacts the bottom electrode
ƒ Good solid electrolytes contain large numbers of highly mobile positively
charged metal ions
ƒ The backbone material separating these conducting regions is a good dielectric
so the resistivity of the electrolyte is high
ƒ As the high resistivity provides a high off resistance and the abundance of
mobile ions is critical for rapid and stable resistance lowering
ƒ Charge neutrality
ƒ Using Ag or Cu deposits for ease of oxidation
26
Programmable Metallization Cell
Indian Institute of Technology,
Guwahati
Indo German Winter Academy 06
ƒ Working & principle:
ƒ An oxidizable metal layer and an inert electrode formed in contact with the
electrolyte film creates a device in which information is stored via electrical
changes caused by the oxidation of the metal electrode and reduction of metal
ions in the electrolyte
ƒ Change of state (set and reset states):
ƒ Aapplied bias as low as a few hundred mV and can result in a resistance
change of many orders of magnitude within a few tens of nanoseconds even
for currents in the μA range
ƒ Reverse bias of the same magnitude will reverse the process until the
electrodeposited metal has been removed, thereby erasing the device
ƒ Information is retained via metal atom electrodeposition rather than charge
storage
27
Programmable Metallization Cell
Indian Institute of Technology,
Guwahati
Indo German Winter Academy 06
ƒ Characteristics:
ƒ Applied voltage of a few hundred mV will reduce ions
to form an electro deposit of metal atoms at the
cathode and inject ions into the electrolyte via
oxidation at the anode
ƒ The apparent rise in resistance following switching is
caused by the current limit (compliance) control in
the measurement instrument
V-R characteristics
ƒ Hysterisis
ƒ Reduced Threshold on the I-V characteristics:
Once electro deposition is initiated, the threshold for
further electro deposition is decreased. This is
evident by the presence of a lower voltage, in this
case 220 mV, at which the current drops below
compliance on the negative-going sweep
V-I characteristics of PMC
28
Programmable Metallization Cell
Indian Institute of Technology,
Guwahati
Indo German Winter Academy 06
ƒ Advantages:
ƒ Information is retained via metal atom
electro deposition rather than charge
storage, PMC memory has excellent
retention characteristics.
ƒ Do not readily tolerate
ƒ Non volatile
ƒ Electro deposition of metal in
the electrolyte cannot be
sustained if the voltage across
the structure drops below that
necessary to overcome the
electrochemical potential or if
the supply of oxidizable metal
becomes exhausted
ƒ Excellent switching characteristics
ƒ The write threshold decreases with
increasing temperature
ƒ Switching may be achieved using low
voltage 50 ns pulses
ƒ Ag-doped materials will survive backend-of-line processing to 430 °C
29
ƒ Disadvantages:
processing conditions much
beyond 200 Celsius for selenide
type. Higher for sulphides
Programmable Metallization Cell
Indian Institute of Technology,
Guwahati
Indo German Winter Academy 06
ƒ What is it?
ƒ The resistive switching phenomenon observed in organic semiconductor layers
containing granular metal particles conforms to a charge storage mechanism. The
space-charge field due to the stored charge inhibits further charge injection from
the electrodes
ƒ The equilibrium current-voltage curve is N shaped and the low and high resistance
states are obtained by applying voltage close to the local maximum and minimum
ƒ Schematic configuration:
ƒ Device proposed is a sandwich structure consisting of
three layers between top and bottom metal electrodes
ƒ 3 layers are, respectively, the organic semiconductor, the
metal, and the organic semiconductor, specifically
AIDCN/Al/AIDCN
ƒ Metal layer actually consists of discrete particles, and is
therefore electrically discontinuous
ƒ Specifically, here we use aluminum tris~8hydroxyquinoline (Alq3) as the semiconducting medium
and granular aluminum for the charge-trapping sites
ƒ The electrodes are also aluminum
30
Bi-stable Organic Memory Devices
Indian Institute of Technology,
Guwahati
Indo German Winter Academy 06
ƒ Working & principle:
ƒ When the device is in the low resistance ON
state, and the voltage is ramped up from
zero, an ‘‘N-shaped’’ I-V curve is obtained
ƒ If a voltage near Vmin is applied and then
rapidly set back to 0 V, the device is left in
its high-resistance OFF state
ƒ When the device is in the OFF state, and the voltage is ramped up from zero, the
current remains low until a threshold is reached, at which the high-current ON
state is established
ƒ The threshold voltage (Vth) is comparable to, but slightly less than, Vmax
31
Bi-stable Organic Memory Devices
Indian Institute of Technology,
Guwahati
Indo German Winter Academy 06
ƒ
ƒ
ƒ
ƒ
ƒ
32
The ON state is obtained by setting the voltage close to Vmax and above Vth , then
reducing it to zero
Intermediate states, i.e., those between the ON and OFF resistance values, can be
obtained by setting the voltage between Vmax and Vmin in the NDR(negative differential
resistance) region
The region of bistability is obtained for voltages below
the threshold (Vth +2.7 V)
Set State:
- Voltage is ramped from zero in the OFF state the
current increases rapidly at the threshold voltage,
and then follows an N shape. By sweeping the
voltage back towards zero, the current follows the
upper curve and the device is set in its ON state and
it will stay in that state unless voltage between Vmin
and Vmax is applied
Reset state:
- Set the device at a certain voltage in the NDR
region and returning rapidly to zero
Bi-stable Organic Memory Devices
Indian Institute of Technology,
Guwahati
Indo German Winter Academy 06
ƒ Principle:
ƒ Variety of different materials and concepts all of which using individual molecules as
building blocks for memory cells storing bit information in the space of an atom or a
molecule
ƒ Create a monolayer (ML) film consisting of a large number of functional molecules
and thereafter contacting these films by depositing an electrode layer on top of it
ƒ Techniques used:
ƒ Rapid reversible conductance switching of molecules
ƒ Self assembled monolayers of these molecules and embedding them into an
Au/molecular ML/Au electrode structure a fast and reversible resistance switching
ƒ Single time programmability
ƒ Problems faced:
ƒ Finding of adequate deposition methods
ƒ Thermodynamic stability of the different molecular states and the reaction kinetics
have to be studied
ƒ Formation of a well defined metallic contact to the molecules or molecular
arrangements in order allow a reliable reading and writing
33
The Ultimate : Molecular Memory
Indian Institute of Technology,
Guwahati
Indo German Winter Academy 06
ƒ “Punch card”:
ƒ Storing a terabit of data on a chip no bigger than a
postage stamp has been developed by researchers at
IBM
ƒ ”Millipede” chip, created by a team in Zurich,
Switzerland, stores single bits of data in the form of
tiny indentations
ƒ The indentations are made in the surface of the chip
using tiny "spikes" or tips on the end of pivoting arms.
These same spikes are used to write, read and erase
data on the chip
ƒ Atomic memory:
ƒ Scattering gold atoms on a silicon wafer caused the silicon
atoms to assemble into tracks exactly five atoms wide
ƒ Works well at very low temperatures with loosely-bound
atoms, but not at room temperature
ƒ Writing and Reading from each atom is very slow at present
34
“Punch Card” and Atomic Memory
Indian Institute of Technology,
Guwahati
Indo German Winter Academy 06
ƒ What are memory devices?
ƒ Development cycle
ƒ Requirements of future devices
ƒ Some materials that can be used in the future
ƒ Summary
35
An Overview
Indian Institute of Technology,
Guwahati
Indo German Winter Academy 06
ƒ Summary:
¾ The present:
ƒ
ƒ
Nonvolatile memories are based on charge storage
Aim is to either realize a memory that can be operated like a DRAM or
SRAM and additionally exhibits non volatility, or to realize a considerably
higher density of nonvolatile memories than the currently available ones
¾ The future devices:
ƒ
ƒ
ƒ
36
Inorganic materials are simplest to integrate into an existing CMOS
process. (FeRAM already available in market till 256 Kb and MRAM of
1Mb is in the making)
On the other hand the phase change memory concept has a number of open
questions with respect to the stability of the electrode/chalcogenide
interface as well as the thermal isolation between neighboring bits
For molecular memory fundamental fabrication and integration issues will
have to be solved before we can expect first products
Conclusion
Indian Institute of Technology,
Guwahati
Indo German Winter Academy 06
Indian Institute of Technology,
Guwahati
37