Download M.Sc. (Part II) Inorganic Chemistry Revised Syllabus From June

NORTH MAHARASHTRA UNIVERSITY,
JALGAON
M.Sc. (Part II)
Inorganic Chemistry
SEMESTER – III AND IV
PROPOSED SYLLABUS
Revised Syllabus
From June- 2011
NORTH MAHARASHTRA UNIVERSITY, JALGAON
M.Sc. (Part II) SEMESTER – III AND IV
Inorganic Chemistry Revised Syllabus From June 2011
PROPOSED SYLLABUS
COURSE STRUCTURE
SEMESTER III
CH-330:-Co-ordination Chemistry (I)
CH-331:-Inorganic Polymer Chemistry
CH-332:-Solid State Chemistry
CH-333:-Some Selected Topics In Inorganic
SEMESTER - IV
CH-430: Co-ordination Chemistry (II)
CH-431:-Physical Methods In Inorganic Chemistry
CH432:-Organometalic metallic Chemistry and catalysis.
Practical Courses
CH-I-2:-Inorganic Chemistry Practical Annual
CH-I-3:-Inorganic Chemistry Practical Annual
CH-I-4:- A Short Research Project
Note:
1. There are in all four theory courses for Third Semester And three theory
courses for fourth semester and Three annual practical courses including one
short research project.
2. Each theory course should be covered in 6 periods each of 6o minutesper
week. 4 periods for lectures and two periods for tutorials,seminars etc.to be
completed in 60 lectures of 60 min duration each.
3. The marks for each paper (theory and practical) are distributed as external (80
marks) and internal (20 marks) examinations. For internal assessment of each
theory course 3 written test /tutorial will be taken in which best of two will be
considered for internal marks.
4. Each practical course and a requires 6 hours of laboratory work per week and
curse will be extended over two semesters and the candidate the candidate will
be examined at the end of the year.
5. There should not be more than 10 students in a batch of a practical course.Each
practical course is having weightage Six Hours per week.
6. Student have to submit a journal certified by the Head of the Department /Head
of the Institution.And student will not be permitted to appear at the practical
examination unless he /she produce a certified journal. If the journal is lost ,the
student should produce a certificate from Head of the department / Head of the
Institution stating that he /she has satisfactorily completed the practical work.
SEMESTER III
COURSE STRUCTURE
CH-330:-Co-ordination Chemistry (I)
Sr. Name of the chapter/topic
No.
No.of
periods
Weightage Weightage
without
with
option(80) option(120)
40
60
1
Inorganic Reaction Mechanism
30
2
Biological Inorganic Chemistry
05
07
11
3
Biological role of 'S' block elements
06
08
12
Biological role of transition elements
12
16
24
Metals in Medicine
07
09
13
4
5
CH-331:-Inorganic Polymer Chemistry
Sr. Name of the chapter/topic
No.
1 Zeolites
2
3
4
5
Supramolecular
Chemisrty
Metal Clusters
Isopoly and heteropoly
acids and salts.
Macrocyclic complexes
No.of periods
24
Weightage
without option
32
Weightage
with option
48
08
11
16
18
04
24
05
36
08
06
08
12
CH-332:-Solid State Chemistry
Sr.
No.
Name of the chapter/topic
No.of periods
1
2
Defects of solids
Mechanical properties of
material
Amorphous solids
Ceramic material
Composite material
Semiconductor devices
Electrical conductivity of
solid
Magnetic
Behavior
of
material
3
4
5
6
7
8
08
06
Weightage
without option
(80)
11
08
Weightage
with option
(120)
16
12
06
03
03
08
12
08
04
04
11
16
12
06
06
16
24
14
18
28
CH-333:-Some Selected Topics In Inorganic Chemistry
Sr. Name of the chapter/topic
No.
1
2
3
4
5
6
7
Group Theory
Group Theory
Group Theory
The chloroalkali industry
Noble gases
Nano Particles
Metal – ligand equillibria
in solution
No.of periods
08
10
12
06
06
10
08
Weightage
without option
(80)
10
14
16
08
08
14
10
Weightage
with option
(120)
15
21
24
12
12
21
15
M.Sc. (Part II) Inorganic Chemistry
SEMESTER – III – SYLLABUS
CH 330 Coordination chemistry I
Inorganic Reaction Mechanism
(30L)
• Type of Mechanisms: Basic concepts as stability and lability, stability
constants; HSAB principle, chelate effect, Macrocyclic effect.
• Substitution Reaction of Octahedral Complexes: The nature of Substitution
Reaction, Theoretical approach to Substitution mechanism, Nucleophilic
reactivity, Nature of central atom, Kinetic application of crystal field theory,
Substitution reaction of Co(III) complexes, Replacement of co-ordinated water,
Acid catalysis. Substitution in octahedral complexes: SN1, SN2 SN1CB
mechanisms,
• Stereochemical changes in Octahedral Complexes: Molecular rearrangement
of complexes, Reaction of geometrical and optical isomers, Isomerisation and
recemisation of octahedral complex, Ligand stereo specificity.
• Substitution Reaction of Square-Planer Complexes: Trans effect and its
theories, Mechanism of substitution reaction of Platinum (II) complexes
Oxidation-Reduction Reaction: Outer sphere mechanism, Inner sphere
mechanism, one and two electron transfer reactions.
Bioinorganic Chemistry
Chapter -1 Biological Inorganic Chemistry
Defination,
(5L)
functional role of biological inorganic elements, some
important biological ligands, crown ethers.
Chapter – 2 Biological role of 'S' block elements
(6L)
As electrolytes, Channels & Pumps, Charge carriers, chlorophyll, energy
production, Activation of enzymes, blood coagulation, endo & exo
skeletons.
Chapter- 3 Biological role of transition elements
(12L)
Biological role of – Fe
Biological role of – Cu
Biological role of – Zn
Biological role of – Co
Biological role of – Mn
Chapter – 4 Metals in Medicine
(7L)
Deficiency & over dose of metal disease, source of metal content, metal in
drug.
References:th
1) 1. F. A. Cotton and G. Wilkinson, Advanced Inorganic Chemistry, 5
Edn., John-Wiley & Sons, New York.
th
2) James E. Huheey, Inorganic Chemistry, 4
Edn., (1993), Addison
Wesley Pub. Co., New York
3) R.H. Crabtree, The Organometallic Chemistry of the Transition Metals,
st
1 Edn.(1988), John-Wiley & Sons, New York.
4) Comprehensive Coordination Chemistry”, Pergamon G. Wilkinson, R. D.
Gillard and J. A. McCleverty, , Vol. 1, pp 281-322, 331- 379, 385-411,
415-458 (Chapt. 7.4) and
463-471, (1987).
5) Inorganic Reaction Mechanism, J.O. Edwards, Benjamin.
6) Mechanism Of Inorganic Reactions, F.Basolo & R.G.Pearson, Wiley
New York.
7) Biological inorganic chemistry by Robert R. Crichton.
8) Bioinorganic Chemistry by Harry B. Gray & Steephen J. Lippard
9) Trace elements emerging As important in Human nutrition by Forrest H.
Nielsen & Janet R. Hunt.
10)
Inorganic Chemistry by Shriver, Atkins.
11)
Bioinorganic Chemistry by R.M. Hay.
CH-331- Selected Topics In Inorganic Polymers
1.Zeolites:
(24L)
A.Basic concept of Zeolites:Introduction, definition, natural and synthetic Zeolites or
aluminosilicates,the primary and secondary building blocks,final framework
structures, Lowenstein’s rule,sodalite and other structures.Nomenclature:atlas of
Zeolites,structural distinctions,novel Zeolites,examples of small,medium,large and
extralarge pore Zeolites,general properties and applications of Zeolites.
B.Synthesis of Zeolites:Methods of synthesis,hydrothermal Zeolites synthesis,factores
affecting
Zeolite
formation,Oswald’s
rules
of
successive
transformation,crystallization
and
identification,factors
affecting
crystallization,template theory,organic additives,crystallizing zeolite, ZSM-5 from an
organic free solvent system,synthesis in non aqueous solvents.
C.Characterization of Zeolites:XRD,SEM and other techniques,FTIR and solid state
NMR,sorption capacity,surface area by BET method,pore volume and pore structure.
D.Applications of Zeolites: Softening of water,agriculture.Applications in organic
synthesis with at least five reactions.
2.Supramolecular Chemisrty:
(8L)
Concept
of
supramolecular
Chemistry
chemistry,molecular
recognition,nomenclature,design of supramolecule through non covalent interactions
and their applications in transport processes.
3.Metal Clusters:
(18L)
Higher boranes,carboranes,metallocarboranes.Metal carbonyl and halide clusters,low
nuclearity clusters,isoelectronic and isolobal relationship.High nuclearity carbonyl
clusters-synthesis
and
structural
pattern.Heteroatomes
in
clusterscarbides,nitrides.Electron counting in high nuclear carbonyl clusters.
High nuclearcarbonyl clusters of Ge,Ru,Os,Co,Rh,Ir,Ni,Pd and Pt.Halide and
chalcogenide clusters.Cheveral phases,triangular clusters.Solid state extended arrays.
4.Isopoly and heteropoly acids and salts.
(4L)
5.Macrocyclic complexes:
(6L)
Types of macrocyclic ligands,design and synthesis by co-ordination template effect,di
and polynuclear macrocyclc complexes,applications of macrocyclc complexes.
• Suggested Bookes:
1. Introduction
to
Zeolite
Science
and
Practice,H.Van
Bekkum,
E.M.Flanigen,P.A.Jacobs and J.C.Jansen(Elsevier pub. Amsterdam,2001)
2. Verified Synthesis of Zeolite material, (Elsevier science pub,2001)
3. Atlas of Zeolite framework types 5th edn.,Ch.Bbaerlocher,W.M.Meier and
D.H.Olson.
4. Jean-Marie Lehn ,Supramolecular Chemistry, (1995) VCH, Weinheim.
5. F.A.Cotten
andG.Wilkinson
Advanced
Inorganic
Chemistry
6th
Edn.
(1999),John-Wiley &Sons,New York.
CH-332 Solid State Chemistry
1. Defects of solids
(08)
Defects of solids, classification of imperfections, Electronic defects,
atomic defects, Lattice imperfections, thermodynamics of schettkey defect and
frenkel defect, problems
2. Mechanical properties of material
(06)
Mechanical behaviours,mechanical properties,fractures of metal,ductile
fracture,brittle fracture,toughness and impact testing.
3. Amorphous solids
Amorphous
(06)
solid,
glass
transition
temperature,
oxide
glasses,
chalcogenide glassess,amorphous carbon,graphite,diamond,alkaline graphite
compounds
4. Ceramic material
(03)
Defination,types,polarization,polarizibility,electric
properties
ceramics,dielectric properties,piezoelectric,pyroelectric and ferroelectric
effect.
5. Composite material
(03)
Defination,fiber,concrete,asphalt,wood,several other types of composite
material.
6. Semiconductor devices
(08)
Diodes, p-n junction, transistor, some other state materials, interstitial
compound,cheveral compound, superconductivity compound, properties of
superconductivity compound, storage battery material.
7. Electrical conductivity of solid
(12)
Electrical conductivity, origin of valence and conduction band in solids,
classification of material, types of semiconductor, time dependent of
conductivity, mobility of charge carriers, metal-metal junction, metal–
semiconductor junction, optical properties of material, refractive index,
inorganic colored solid,LASER,photolumnisences.
8. Magnetic Behavior of material
(14)
Magnetic properties of material,atomic magnetism in solid,the exchange
interaction,classifation
of
magnetic
material,dimagnetics,langevin
paramagnetic,pauli
paramagnetic,ferromagnetism,antiferromagnetism,ferrimagnetism,sperparam
agnetism,ferromagnetic domain, hysteresis loop, types of hysteresis
loop,problem,ferrities,hard and soft ferrities,application of magnetic
material.
Reference Books :
1.
A. F. Wells, Structural Inorganic Chemistry – 5th edition (1984)
2.
J H Huheey, Inorganic Chemisry - Principles, structure and reactivity, Harper
and Row Publisher, Inc. New York (1972)
3.
J. D. Lee, Concise Inorganic Chemistry, Elbs with Chapman and Hall, London
4.
A. R. West, Plenum, Solid State Chemistry and its applications
5.
N. B. Hanney, Solid State Physics
6.
H. V. Keer, Principles of Solid State
7.
S. O. Pillai, Solid State Physics
8.
W. D. Callister, Wiley, Material Science and Engineering: An Introduction
9.
R. Raghwan, First Course in Material Science
10.
R. W. Cahan, The coming of Material Science
11.
A. R. West, Basic Solid State Chemistry, 2nd edition
12.
U. Schubest and N. Husing, Synthesis of Inorganic Materials, Wiley VCH
(2000)
13.
M. C. Day and J. Selbin, Theoretical Inorganic Chemistry, Reinhold, EWAP
14.
A. H. Hanney, Solid State Chemistry, A. H. Publications
15.
O. A. Phiops, Metals and Metabolism
16.
Cullen Dolphin and James, Biological aspects of Inorganic Chemistry
17.
Williams, An Introduction to Bioinorganic Chemistry
18.
M. N. Hughes, Inorganic Chemistry of Biological Processes
19.
Ochi, Bioinorganic Chemistry
20.
John Wulff, The structure an properties of materials
21.
L. V. Azoroff, J. J. Brophy, Electronic processes in materials, Mc Craw Hill
22.
F. A. Cotton, R. G. Wilkinson. Advanced Inorganic chemistry
23.
Willam L. Jooly, Modern Inorganic Chemistry
24.
Manas Chanda, Atomic Structure and Chemical bonding
25.
N. N. Greenwood and A. Earnshaw, Chemistry of elements,. Pergamon
26.
Chakraburty, Soild State Chemistry, New Age International
CH- 333 : Some selected Topics in Inorganic Chemistry
(A) - Group Theory :
1)
Products of symmetry operations, Group multiplication table : C2V, C2h, C3V,
C4V, D2h point groups. Matrics notations for geometric transformations,
properties of a group, law of reciprocal proportion, classes for C2V, C2h, C3V,
C4V and D2h point groups
(8 L)
REF : 1,2,3
2)
Reducible and irreducible representations, The Great orthogonality theorm and
its rules, construction of character table; Mulikan’s symbolism for irreducible
representations, Molecular term symbols, character tables for C2V, C2h, C3V,
C4V, D2h,D3h and D2d point groups
(10 L)
REF : 1,2,3,10.
3) Reduction of reducible representation into its irreducible representation on the
basis of character table, Sigma bond scheme : Hybrid orbitals with 6 bonding
for tetrahydral (Td), D3h,D4h,C4V point groups. Hybrid orbitals with Pi ( ∏ )
boinding for D3h,D4h point groups, constructing symmetry adapted for linear
combination (SALC) for C2V and C3V point groups. Molecular orbital approach
to analyse bonding in H2O, NH3 and BF3 molecules, Transformation properties
of atomic orbitals.
REF : 1,2,3.
(12 L)
B) Basic & applied Chemistry :
1) The chloroalkali industry :
(6L)
Introduction, LeBlanc process, Weldon and decon processes, electrolytic
process, diaphragm cell, Mecury cathode cell, solvay (ammonia soda) process
REF :
7
2) Noble gases :
(6L)
Introduction, electronic structure, clatherate compounds, structure and bonding
in XeF2, XeF4 and XeF6 compounds
REF : 7
3) Nano Particles :
(10L)
General Introduction and objectives study, synthesis of nano material by
physical, Chemical and Biological methods,
Chemical thethods : Coprecipitation method – Theory and Thermodynamic of
co-precipitation, Synthesis of metal from aqueous solution, Precipitation of
metal by reduction from non aqueous solution, precipitation of metal by
electrochemical method, precipitation of metal by radiation assisted reduction
method, precipitation of metal by decomposition of metalloorganic precursor
REF : 4,5,6
4) Metal – ligand equillibria in solution.
(8L)
Stepwise and overall formation constants and their interaction, trends in
stepwise constants, Factors affecting the stability of metal complexes with
reference to nature of metal ion and ligand,chelate effect and its thermodynamic
origin, determination of formation constants by PH- Metry, spectrophotometric
method
REF : 8,9,10,11
Reference Books:
1. Chemical applications of Group theory by F-Albert cotton second edition, wiley
Eastern limited New Delhi.
2. Group theory and its chemical applications by P.K. Bhattacharya Himalaya
publishing House.
3. Concept and application of Group theory by Kishor Arrora Anmol publications
Pvt.Ltd., New Delhi
4. Nanotechnology : Principles and particles – Sulabha K. Kulkarni (Capital
Publication Co.)
5. Recent Advances in the liquid phase synthesis of Inorganic Nano particles B.L.
Cushing, V.L. Kolesnichenko and C.J.O” connor chemical Review 104, 38933946 (2004)
6. Nano – The text revolution – Mohan sundara Rajan (National book trust India)
7. Concise Inorganic Chemistry fifth edition, J.D.Lee
8. Inorganic Chemistry by A.G. Sharpe third edition.
9. Advanced Inorganic Chemistry Fifth edition by F.A. Cotton and Wilkinson.
10. Inorganic Chemistry by J.E. Huhey
11. Electrons & Chemicals bonding by H.B. Gray.
*****************
M.Sc. (Part II) Inorganic Chemistry
COURSE STRUCTURE
SEMESTER – IV
CH-430: Co-ordination Chemistry (II)
Sr.
No.
Name of the chapter/topic
No.of periods
1
Molecular orbital theory of
Metal Complexes
Electronic Spectroscopy of
metal complexes
Infra-red and Raman
Spectroscopy
Magneto Chemistry
Structural and thermodynamic
consequences of partly filled
shells
2
3
4
5
Weightage with
option(120)
10
Weightage
without
option(80)
14
14
17
27
10
14
20
16
10
21
14
32
21
20
CH-431:-Physical Methods In Inorganic Chemistry
Sr.
No.
Name of the chapter/topic
No.of
periods
1
Nuclear Magnetic Resonance
Spectroscopy (NMR)
2
Nuclear Quadruple
Resonance
Spectroscopy(NQR)
Electron Spin Resonance
Spectroscopy (EPR/ESR)
Mossbaur Spectroscopy
Mass Spectrometry
3
4
5
14
Weightage
without
option(80)
18
Weightage
with
option(120)
27
04
06
09
12
16
24
05
07
07
09
10
14
6
Thermal Methods
18
24
36
CH432:-Organometalic metallic Chemistry and catalysis.
Sr.
No.
Name of the chapter/topic
No.of
periods
1
Transition metal compounds
with bonds to hydrogen
Compounds of transition
metals with single, double and
triple bonds to carbon
Compounds of transition
metals with alkenes, alkynes
and delocalize hydrogen
system
Oxidative addition and
migration (insertion) reactions
Heterogeneous catalysis
Inorganic photochemistry and
reactions
2
3
4
5
6
10
Weightage
without
option(80)
14
Weightage
with
option(120)
20
10
14
20
10
13
20
10
13
20
10
10
13
13
20
20
M.Sc. (Part II) Inorganic Chemistry
Syllabus
SEMESTER – IV
CH- 430
Co-ordination Chemistry and Spectroscopy
(10L)
1) Molecular orbital theory of Metal Complexes :
Classification of metal, ligand orbitals in cubic and non cubic environment,
octahedral, tetrahedral, square planer, square pyramidal, trigonal bipyramidal
geometries – concept of ligand group orbitals – construction of molecular energy level
diagrams for octahedral, tetrahedral and square planer metal complexes with sigma
(6) and Pi ( ∏) bonding contribution from the ligands
REF : 1,2,3
2) Electronic Spectroscopy of metal complexes :
(14L)
Strong ligand field configurations : The method of descending symmetry, splitting
pattern of co-ordination no. 2 to 9 metal complexes, Tanabe sugano diagrams for d2
and d8 configurations. Classification of electronic spectra for metal complexes :
Electric dipole transitions, Magnetic dipole transitions, relaxation in selection
rules- Nature of electronic spectral bands : Band widths, Band intensities and
factors influencing Band Shapes – Jahn Teller effect – Spectrochemical Series –
Naphelauxetic effect – crystal Field Spectra of ‘Oh’ and ‘Td’ complexes of 3d
metals – calculation of 10 Dq values, Racah parameters (B) and nephelauxetic
Tatio (β) – charge transfer spectra
REF : 1,2,3
3) Infra-red and Raman Spectroscopy :
(10 L)
Conditions for Infrared and Raman Spectroscopies, symmetry Based selection
rules of infrared and Raman, complementary Nature of infra-red and Raman
spectroscopies, symmetry requirement for overtone binary and ternary combination
bands – Fermi Resonance- Prediction of Diagnostic Fundametals in isomers of Metal
complexes, structure fitting : Determination of co-ordination sites and linkage isomers,
Assigning denticity of ligands and distinguishing isomers of metal complexes – effect
of co-ordination on ligand vibrations : Examples involving mono, bi or Polydentate
ligands of oxygen, sulphur, nitrogen, Phosphorus, Arsenic, carbon and halogen
donors. Application of Resonance Raman Spectroscopy to structural elucidation of the
active sites of Heme and non heme oxygen carriers .
REF : 4,5
4) Magneto Chemistry :
(16L)
Diamagnetic correction, single and multielectron system, types of magnetic
behaviour, diamagnetism, paramagnetism ferromagnetism, Ferri, antiferro and
magnetic interaction, the origin of para magnetism, magnetic behaviour of
complexes, simplification of van velck equation magnitude of magnetic moments,
determination of magnetic susceptibility of Gouy and Faraday method. )
Magnetic properties of complexes, paramagnetism, 1st and 2nd orderd Zeeman
effect, quenching of orbital angular momentum by ligand fields, Magnetic
properties of A,E,T ground terms in complexes, spin free – spin paired equillibria
REF : 6,7,8,11,12,13,14,15.
5) Structural and thermodynamic consequences of partly filled shells : (10L)
Ionic radii,origin of magnetic behaviour , thermodynamic effects of d- orbital
splitting, magnetic properties of chemical compounds, large multiplet separation
small multiplet separation, spin only, heavy atoms, high spin-low spin cross overs.
REF : 7,9,10
Reference Books :
1. Symmetry and Spectroscopy of molecules K.Veera Reddy, second edition, New
Age international P Limited publishers (2009)
2. Electronic Spectroscopy by A.B.P Lever
3. Intoduction to ligand fields by B .N.Figgis..
4. Infrared and Raman Spectroscopy of Inorganic and co-ordination compounds,
K. Nakamoto.
5. Infrared Spectroscopy of Inorganic Compound Bellamy.
6. Ligand Field theory and its application by B.N.Figgis and M.A.Hitchman Wiely
VCH publication (2000)
7. Inorganic Chemistry D.F.Shriver and P.W.Atkins Oxford (1999)
8. Inorganic Electronic Spectroscopy : A.B.P Lever 2nd Edition Elsevier science
publishers, New York (1984)
9. Advanced Inorganic Chemistry by Cotton and Wilkinson (3rd, 4th ,5th edition)
10. Theoretic al Inorganic Chemistry by Day and Selbin.
11. Introduction to Magneto Chemistry by Earnshow.
12. Mabbs and Machin Magnetism and transition metal complexes chamman Hall.
13. Calvin, Magnetic properties of transition metal complexes.
14. Magneto Chemistry by L.N. Maley.
15. Elements of Magneto Chemistry by Datta and Shymal.
CH-431
Physical methods in Inorganic Chemistry
1.Nuclear Magnetic Resonance Spectroscopy (NMR)
(14L)
Principal of NMR spectroscopy.Chemical shift,mechanism of electron shilding and
factors affecting the magnitude of chemical shift.Volume diamagnetic susceptibility,
Chemical shifts for which the local diamagnetic term does not predominate,spin-spin
spilitting, spin-spin coupling mechanism for transmitting nuclear spins,applications of
spin-spin coupling to structure determination,applications involving magnitude of
coupling constants,complex spectra,chemical exchange and the factors affecting line
width,effect of chemical exchange on spectra and the evaluation of reaction rates for
fast ractions,study od exchange reactions between ligands and metal ions.the double
resonance technique,NMR of paramagnetic complexes –contact shift.applcations of
NMR to Inorganic problems.
2.Nuclear Quadruple Resonance Spectroscopy(NQR)
(4L)
Introduction,effect of magnetic field on the spectra,relationship between the electric
field gradient q.and molecular structure,applications involving –the interpretation of
eQq data,the effects of crystal lattice on the magnitude of eQq,Structural information
from NQR spectra.
3.Electron Spin Resonance Spectroscopy (EPR/ESR)
(12L)
Introduction,Presentation of the spectrum,hyperfine splitting in some simple systems,
hyperfine splitting in various structures,factors affecting the magnitude of the g
values,intractions affecting the energies of unpaired electrons in transition metal
complexes ,zero-field splitting and Kramer’s degeneracy,anisotropy in hyperfine
coupling constant,the nuclear quadruple intraction,the spin Hamiltonian,line widths in
solid state ESR,electron delocalization,at least five different applications.
4.Mossbaur Spectroscopy
(5L)
Principle,Doppler broadening,resonance line shift from change in electron
environment,quadruple and magnetic interactions,
applications.
5.Mass Spectrometry
(7L)
Principle,presentation of spectra,process occuring due to combination of a molecule
and a high energy electron,applications-fingerprint application and the interpretation
of mass spectra,effect of isotops on the appearance of a mass spectrum,molecular
weight determinations exact masses of nuclides, molecular ions, isotope ions,
fragment ions of odd and even electron types, rearrangement ions.Factors affecting
cleavage, cleavage patterns,simple cleavage, cleavages at a heteroatom, multicentre
fragmentation rearrangements, Diels – Alder fragmentation..
6.Thermal Methods
(18L)
A.Thermogravimetry(TGA):Defination,types of
TGA, Instrumentation,
information from TGA curve, factors affecting TGA curves (instrumental as well as
characteristics of sample factors);applications TGA,calculation of percent
decomposition and percent composition of compounds,limitations and adventages of
TGA.
B.Dervative Thermogravimetry(DTG) and its adventages.
C.Differential Thermal Analysis(DTA): Definition, therotical basis of
DTA,
instrumentation of DTA apparatus, factors affecting DTA curves, applications of
DTA, adventages and disadventages of DTA,applications of DTA
D.Differential Sanning Calorimetry(DSC): Defination,comparison of DTA and
DSC technique,instrumentation of DSC,factors affecting DSC curves,applications of
DSC.
Suggested Reference Books:
1. Physical methods in Inorganic Chemistry, R.S.Drago, Renhold Puublishing
CorporationR.S.Drago
2. Instrumental Methods of Analysis,6th edition,Willard,Merit,Dean.
3. Instrumental Methods of Chemical Analysis,5th edition,Golden W.Ewing
4. Principals of Instrumental Analysis,3rd edition,Douglas A.Skoog
5. Instrumental Methods of Chemical Analysis,Anand,hatwal
6. Quantative Inorganic Analysis,A.I.Vogel
CH-432 Organ metallic Chemistry and Catalysis
1. Transition metal compounds with bonds to hydrogen
[10L]
2. Compounds of transition metals with single, double and triple bonds to carbon.
[10L]
3. Compounds of transition metals with alkenes, alkynes and delocalize hydrogen
system.
[10L]
4. Oxidative addition and migration (insertion) reactions
[10L]
5. Heterogeneous catalysis
[10L]
6. Inorganic photochemistry and reactions
[10L]
Reference Books
1. Advance inorganic chemistry by Cotton and Wilkinson (5th edition)
2. Inorganic chemistry principles and applications by Butler and Harrod
3. Organo transition metal chemistry-Applications to organic synthesis by
S.G.Davies(Pergamon)
M.Sc.(Part II) Inorganic Chemistry
Practical Courses
Practical Course - CH-I-2
1.Analysis ore/alloy
(any three)
i)Analysis of Cement
Ii)Analysis of Eleminite
iii)Analysis of Haematite
iv)Analysis of Steel Fe,Cr – alloy.
v)Analysis of Bronze – alloy.
2. Vitamin ‘C’ from Lamon juice.
3.Estimation of Fe from Soap Bar.
4.Analysis of pigment.(Zn & Cr)
5.Analysis of Plaster of Paris
6. Preparation and photochemical analysis of Fe(III) oxalate complex.
7.To study the kinetics & hydrolysis of Co(III) complex
By (a) conductance
measurement (b) Spectrophotometrically.
8 .Complexometric of bismuth titration.
9. To study rate of aquation of
spectrophotometry.
1,10 Phenanthroline Fe(II) in acid solution by
10To study the rate of aqation of complex trans-dichloro bis-ethylene diamine Co (II)
chloride
10 Determination of Cd+2 ion conc in a given sol n polarographically following (I)
calibration (II) std. addition (III) the pilot-Iron procedures.
11 Determination of Zn+2 ions present at the ppm level in the sol
n
employing
conventional D.C.& pulse polarographic techniques.
12. Amperometric determination of Zn with std. EDTA soln .
13. To study the current –potential character.ristics of Cd+2 ions using DC
polarography, sampled DC, cyclic voltammetry & pulse polarographic techniques.
14.Flame photometry
Practical Course : CH-I-3
1.Synthesis, purification & analysis of co-ordination complexes of simple &
chelating ligands. (Any-4)
i)Bis (acetylacetonato complex of Cu (II), Co(II) & VO (IV) (any – one)
ii)[ Cr(NH3 )6] Cl3
III)[Ti (urea)6] I3
iv)Ni-8 – hydroxy quinoline.
v)Salicyladoxime (Fe or Cu)
vi)Prussion – blue Fe4 [Fe(CN)6 ]3
2.Magneto Chemistry :
Magnetic susceptibility measurements of the following complexes.
i)Ni(II) -8 hydroxy quinoline.
ii)Salicylladoxime (Fe of Cu)
iii)Ti [(urea)6 ] I3
3.Turbidity determination- Determination of chloride in tap water by turbidity.
4.Phase diagram : Study of phase diagram of Sn-Sb alloy system.
5.Electronic spectra. : Analysis of electronic spectra of Ni(II),Co(II),Cu(II) & Cr
(III) complexes.
6.TGA (Thermogravimetric analysis ) two samples.
7.Determination of no. of water molecules from the given hydrated compound.
8.Stability constant of metal complex by Bjerrum (potentiometry) method/
pH metry.
9.Kinetic masking.: 1) Determination of Cr(III) & Fe(III) in a mixture.
10.Estimation of dissolved NO3⎯ /F⎯ /Cl⎯ in the given sample by colorimetry.
11.Ion exchange method. : Separation & estimation of Zn & Cd mixture or Zn &
Mg mixture.
12Preparation and characterization of cadmium sulphide nanoparticles using
thioglycerol as a capping agent and calculate particle size using UV spectra..
13Preparation of nickel nanoparticles using hydrazine hydrate as a reducing agent
and determine λmax using UV spectra.
Practical Course : CH-I-4
A short Reasearch Project
The course includes :
Literature survey, Research methodology and Industrial tour.
Practical AND/ OR Oral Presentation.
Desertation Report – 10 marks.
I)Presentation – 30 marks.
Practical
– 30 marks
OR
II)Oral Presentation -60 marks
Industrial Visit and Report – 10 marks.
Reference Books:
1.Advanced Practical Inorganic Chemistry , Goel Publishing House,Unit of
Krishna Praskashan Media (P) Ltd.
2.Post Graduate Practical Chemistry Part I,Himalaya Publishing House.
3.Advanced Physical Chemistry Experiments ,A Publication of Pragati
Prakashan,Meerut.
4
Nano technology: Principles and Practices-Sulbha K. Kulkarni
5. A Text book of Quantitative Inorganic Analysis; A. I. Vogel
6. Practical inorganic chemistry; Pass Geoffrey and haydn Sutcliffe.
7. Advanced Practical inorganic chemistry; Gurudeep Raj.
8. Vogel’s Qualitative Inorganic Analysis, D. Svehla, VII Edn. Orient Longman
Ltd..)
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