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Environmental Physics Chapter 4: Solids, Liquids and Gases Copyright © 2007 by DBS Concepts • The physical states of matter – solids, liquids, gases and plasma - are determined by intermolecular forces, dependent upon temperature and pressure • To change state involves exchange of energy and may also need ‘seeding’ • Strength and elastcity are important characteristics of solids, which may be applied to rocks • In a gas, pressure, temperature and volume are closely related, giving rise to the ‘gas laws’ which are important in describing energy flows in the atmosphere • Fluid dynamics, the study of movements of fluids, is applicable to a wide range of environmental systems States of Matter The physical characteristics of matter contained in environmental systems determine many of the key processes and flows within that system States of Matter States of Matter fluids Solids • little thermal energy • rigidly bonded together • regular pattern • may be plastic or rigid Temp. Liquids • particles flow • held close together • no regular arrangement Plasma • similar to a gas but higher energy, composed of isolated e- and nuclei rather than discrete atoms or molecules http://www.chem.purdue.edu/gchelp/atoms/states.html Gases • individual molecules • well separated • move at high speeds Water Question vapor What are the common names for the three states of water? Spot the mistake! Question Complete the following: following State Shape Volume Solid Definite Definite Liquid Indefinite Definite Gas Indefinite Indefinite 106 K Source: http://ds9.ssl.berkeley.edu/themis/mission_sunearth.html States of Matter • Aurora borealis – plasma – interaction of the solar wind (plasma) with the Earth’s atmosphere and magnetic field http://www.om3rkp.cq.sk/articles.php?lng=en&pg=220 States of Matter The Structure of the Earth Not a solid! P On cooling lighter elements moved to surface • • • • • Lithosphere – rigid Asthenosphere – plastic/molten Lower mantle – solid Outer core – liquid Inner core – solid (under pressure) Core Mantle Crust Question Label the diagram below. 1. 2. 3. 4. 5. 6. 7. Outer core Crust Mantle Lithosphere Inner core Asthenosphere Lithosphere States of Matter Solutions and Other Mixtures • Solution – • Suspension – – • – – Suspended mixture of insoluble liquids (e.g. oil and water) Brought about under specific chemical/physical conditions Settle out over time Aerosol – • Small solid particles are mixed in a liquid Can be separated by filtering or centrifuge Emulsion – • Molecules or ions of one material are evenly spread throughout a liquid Liquid water as tiny droplets too small to fall as rain Saturation point – – – Maximum amount of material that can be dissolved in another Solids - Increases with temperature e.g. sugar Gases in liquids - Decreases with temperature States of Matter Changes of State • Change of state – Due to changes in temperature and pressure – Intermolecular bonds • • • Ice is unusual as it expands when it freezes Water crystallizes into an open hexagonal form containing more space than the liquid state Compressing ice tends to melt the ice (mpt. decreases) States of Matter Changes of State 4° density maximum Balance between breakup of icelike clusters (> ρ) and thermal expansion (< ρ) ~ 1 kg L-1 Expansion Controlled by Hbonding ρ↓ contraction expansion 2.2 Matter Has States Deposition Add phase • States of matter change terms Melting Evaporation Freezing Condensation Sublimation Demo • Sublimation States of Matter Cloud Seeding and Condensation Nuclei • Condenstaion nuclei (CN) – Gases condense more readily – Liquids solidify more readily • Supersaturated – Cooling a vapor/gas mixture to below saturation point • Supercooled – Cooling a pure liquid to below freezing point contrail Demo: Smog in a Bottle • Large bottle, matches • • • • • Swirl hot water to coat inside walls of bottle Light a match and add to bottle Compress sides to increase the pressure Release As the temperature inside the bottle reduces water vapor condenses States of Matter Molecular Diffusion • • Random thermal motion In most cases turbulent mixing and pressure/convection currrents predominate • Diffusion is slow http://www.ap.stmarys.ca/demos/content/thermodynamics/brownian_motion/brownian_motion.html States of Matter Molecular Diffusion • Fick’s Law- Depends on concentration gradient Over short distances and for low C Q = kD ΔC / Δz ~ kD (C2-C1)/(z2-z1) Where Q = flux of material (kg m-2 s-1), ΔC / Δ z = concentration gradient, kD = diffusivity coefficient (m2 s-1) C(z) = C0exp[-1/2(z/σ)2] Where C0 = concentration at source, z = distance from source, σ = typical distance diffused after a certain time • Flux declines with distance exponentially Question Consider a local concentration of 106 mg per cm3 which drops by a factor of 10 over a distance of 1 cm. Assume the diffusivity is 0.1 m2 s-1. Calculate the flux. Q = kD ΔC / Δz Q = (0.1 m2 s-1)[-(106 mg cm-3)/10] / 1 cm Q = (0.1 m2 s-1)[-(1012 mg m-3)/10] / 0.01 m Q = (0.1 m2 s-1)(-1011 mg m-2) / 0.01 m = 1012 mg m-2 s-1 End • Review Properties of Solids • Solids are characterized by: – – – • Shape Strength – tensile, compressive, shear Resistance to external stress Properties determine material use Properties of Solids Elasicity, Stress and Strain • • Stress – internal forces reacting to applied load (= force/Area) – Compressive, tensile, shear Strain – geometrical expression of deformation caused by stress (= extension/length) Young’s Modulus (stiffness): E = stress / strain E = f/A e/l • • • Also known as modulus of elasticity For certain materials stress ~ strain Strain due to a given stress can be calculated Question What are the units of Young’s modulus? Kg m s-2 m2 N m-2 = Pascals Material E (GPa) Rubber 0.1 Polystyrene 3 Wood 11 Aluminum 69 Titanium 105 Steel 200 Diamond 1000 flexible stiff Questions (i) Is there a relationship between E and ρ? (ii) Why are ceramics, such as silicon carbide, used for machine tool tips? Properties of Solids Elasicity, Stress and Strain Bulk modulus, K = volumetric stress volumetric strain (resistance to compression) Extension of E to 3-D (should be low for solids) Shear modulus, μ = shear stress shear strain Deformation of shape at constant volume Properties of Solids Poisson’s Ratio • • When a solid is stretched in one direction it tends to flatten and broaden in the other direction Poisson’s ratio, σ = (ΔB/B) (Δ L/L) Material Good for wine bottles! σ Cork ~0 Steel 0.3 Rubber 0.5 Properties of Solids Elasicity, Stress and Strain • • Bulk modulus, K = bulk stress bulk strain K= E(1 – σ) 3(1 + σ)(1 - 2σ) Shear modulus, μ = shear stress shear strain Only applicable over elastic deformation range (material returns to original shape after stress is removed) μ = ½ E/(1 + σ) (=0 in fluids, no resistance to shape changes) Properties of Solids Elasicity, Stress and Strain • • Elasticity - ability of a material to return to it previous shape after stress is released Plasticity – opposite of elasticity -past the elastic limit plastic deformation occurs – Molecular bonds break – Energy is released as heat – Material reaches breaking point Slope = E Properties of Solids Strength • • Strength measures the resistance of a material to failure, given by the applied stress (or force per unit area) Depends on shape of curve Will vary with temperature and purity, e.g. C added to steel Failure due to metal fatique, exposure to UV or ionizing radiation Question Sketch stress-strain curves for rubber, silly putty and china. Rubber – elastic over a large range Silly putty – plastic over a large range China – Elastic then plastic over very short range (breaks) Properties of Solids Stress and Strain in Rocks If forces exceed plastic limit rock will break – fault line Over long timescales solid rock can bend and be uplifted leads to distorted strata with discontinuity Properties of Solids Seismic Waves • P and S waves End • Review Pressure • Pressure in a fluid is due to the weight of fluid above pressing down P = f /A Where f = force (N), A = area (m2) • Pressure on an area A at depth h is due to the weight of a column of fluid above it, volume = Ah mass = Ahρ Pressure = f / A = mg / A = Ahρg /A =hρg • Atmospheric pressure is due to the height of the column of air above us Pressure • Average atmospheric pressure = 1.013 x 105 Pa = 1 atmosphere (at sea level) Range: 0.9 x 105 Pa - 1.1 x 105 Pa • Decreases exponentially with height (air gets thinner) • Since density decreases the linear relationship p = hρg does not hold • Major difference - Air is compressible, unlike water Pressure Mercury Barometer • Since mercury is a fluid P = hρg • Where = density of mercury = 13600 kg m-3 h=p/ρg h = 1.013 x 105 Pa / (13600 x 9.8 m s-2) h = 0.76 m So 1 atm = 760 mm Hg Question What is the pressure (in atm.) at 10 m depth of water? What is the pressure at 20 and 30 m depth? (ρ = 1000 kg = m-3) P = hρg = 10 x 1000 x 10 = 1 x 105 Pa = 1 atm P = hρg = 20 x 1000 x 10 = 2 x 105 Pa = 2 atm P = hρg = 20 x 1000 x 10 = 3 x 105 Pa = 3 atm Every 10 m increase in depth increases P by 1 atm Pressure Archimedes’ Principle • • When a body is submerged in a fluid, there is an upward force equal to the weight of fluid displaced Archimedes' principle – The apparent weight of an object immersed in a fluid will be smaller than its “true” weight Wobject in water = Win air - W displaced water • Pressure at the lower surface is greater than up top – results in net upwards force • Bouyancy depends on density Question An object weighs 36 g in air and has a volume of 8.0 cm3. What will be its apparent weight when immersed in water? When immersed in water, the object is buoyed up by the mass of the water it displaces, the mass of 8 cm3 of water Taking the density of water as 1 g cm-3, the upward (buoyancy) force is 8 g The apparent weight = 36 g – 8 g = 28 g Pressure Flotation • Objects float if upthrust from fluid > objects weight • i.e. density < density of fluid • An iceberg has density 0.9 g cm-3 and is floating with V1 of its volume above and V2 of its volume below water • Sketch a diagram showing the iceberg Pressure Flotation V1 Volume of ice below water: V = V1 + V2 ρice V2 ρwater Weight of ice: W = mg = Vρiceg By Archimedes principle: W = mg = V2ρwaterg Balance forces (flotation): V2ρwaterg = Vρiceg V2 = V(ρice/ρwater) 9/10 of iceberg is below water = V (0.9 g cm-3/1 g cm-3) = 0.9V Pressure Flotation • What happens when the iceberg melts? • Meltwater has the same density as liquid water so the volume contracts (ρice < ρwater) After melting, Vmelt = W / (ρwaterg) Substituting for W, the upwards bouyant force: W = V2ρwaterg Vmelt = V2ρwaterg / (ρwaterg) Vmelt = V2 Same volume as ice before melting, top vanishes, effect on water level is zero Pressure Flotation • Any melting of floating ice in the Artic (sea ice) due to global warming has no net effect on global sea levels • Only land ice has an effect (glaciers) – Is this true??? – Something has been overlooked! Pressure Flotation • Is the density of sea water 1 g cm-3 = 1000 kg m-3? No! It is actually 1026 kg m-3 Vmelt = V2ρsea waterg / (ρwaterg) Vmelt = V2(1026/1000) = 1.026 V2 Volume of meltwater is 2.6 % greater than the displaced seawater, water levels will rise Ice displaces its own weight of the underlying liquid, it does not displace the same volume as the meltwater End • Review Gases • • • Gases are compressible and have lower density than water Pressure (P), Temperature (T), and Volume (V) are more closely related than for solids or liquids Understanding gas behavior is important in climatology and air pollution studies Gases The Gas Laws • At constant T (Kelvin), V is halved when P is doubled Boyle’s Law: P ~ 1/V or PV = constant • At constant P, if T increases then V increases Charles’ Law: V ~ T or V/T = constant • Pressure increases, particles move closer together At constant V, if T increases then P increases Gay-Loussac’s Law: T ~ P or P / T = constant KE increases, particles spread out, increased V KE increases, particles collide with the container walls more rapidly, exerting increased P Gases The Gas Laws Question The temperature of a balloon at room temperature (27 ºC) is increased by 1 ºC. What is the new volume? V1/300 = k V2/301 = k V1/300 = V2/301 V2 = 301V1 / 300 V2 = (300/300 + 1/300)V1 V2 = (1 + 1/300)V1 = V1 + 1/300V1 Gases The Gas Laws • Three laws are combined to give the equation of state: PV = r where r = constant T Where V = volume (m3), P = pressure (Pa), T = temperature (K), r = 4.16 J kg-1 K-1 The ideal gas law is most accurate for monoatomic gases and is favored at high temperatures and low pressures. It does not factor in the size of each gas molecule or the effects of intermolecular attraction Gases The Gas Laws • Gases are often measured in terms of molar volume. One mole of any gas occupies the same volume Avogadro’s hypothesis: V ~ n or V / n = k Where n = no. moles and 1 mole = 6.022 x 1023 molecules • Equation of state now becomes: PV = nRT Where n = no. moles and R = molar gas constant = 8.31 J mol-1 K-1 • 1 mole of any gas occupies 22. 4 L at 1 atm. 273 K Gases Conversion to standard temperature and pressure • Since volume changes with T and P it is useful to state the volume occupied at STP (standard temperature and pressure) P1V1 = P2V2 = r T1 T2 Where subscripts 1 and 2 refer to values before and after Question An industrial plant emits 3000 m3 of gas per hour containing 0.5 % NO2 at T = 77 ºC and P = 1 atm. Find the volume of NO2 emitted. Convert to STP: V2 = P1V1T2 / T1P2 V2 = (1)V1T2 / T1(1) = V1T2 / T1 = 3000 x 273 / 350 = 2340 m3 in one hour = 2340 m3 h-1 Volume of NO2 emitted is 0.5% of 2340 = 11.7 m3 h-1 Gases Work Done • When a gas expands it does work using energy supplied by the change in temperature e.g. car engine – energy from gasoline heats cylinder and expands the gas inside: heat → movement E = P ΔV Where E = Energy (J), P = Pressure (N m-2) and V = Volume (m3) • Compressed gases can store energy and be used as a fuel E=fxd 1Nm=1J Gases Work Done • Force exerted on piston F=P.A • Piston moves Δx, what is work done on the gas, W? W = P . A . Δx • What is ΔV? ΔV = A . Δx • Express work done: W = PΔV Question A cylinder is at pressure of 6000 Pa and a piston has an area of 0.1m2. As heat is slowly added the piston is pushed up a distance of 5 cm. Calculate the work done on the surroundings assuming constant pressure. E = P ΔV E = 6000 Pa x (0.1 m2 x 0.05 m) E = 6000 Pa x 5 x 10-3 m3 = 30 N m-2 x m3 = 30 N m = 30 J Gases Heat Capacities of Gases • When a gas heats up the temperature rise depends on – Heat capacity (c) (similar to solids and liquids) But also: – Expansion (volume change) – Pressure • Not possible to define simple heat capacity for a gas, need two! Gases Heat Capacities of Gases • Specific heat capacity at constant volume, Cv (J mol-1 K-1) All heat applied goes into inc. T Q = nCv ΔT Energy required to raise the temperature of 1 mole of gas by 1 K in a closed container (constant V) • Specific heat capacity at constant pressure, Cp (J mol-1 K-1) Heat applied goes into inc. T and expanding Q = nCp ΔT Energy required to raise the temperature of 1 mole of gas by 1 K at constant pressure Gases Heat Capacities of Gases • According to first law of thermodynamics ΔU = Q – W • Where U = change in internal energy, Q = heat added to system, W = work done by the system (PΔV) ΔU + PΔV = nCp ΔT • From the ideal gas law (PV = nRT) under constant pressure conditions: PΔV = nRΔT ΔU + nR ΔT = nCp ΔT • Since Cv = ΔU/ nΔT (same as above but ΔV = 0) Cp = Cv + R Cp > Cv Takes more energy since energy is used in expansion Gases Adiabatic and Isothermal Expansion • Gas expands at constant T = isothermal PV = constant Work is being done in expanding the gas so to keep T constant heat (E = PΔV) must be supplied, e.g. squeezing a balloon • If no external energy input = adiabatic PVγ = constant Where γ = Cp/Cv e.g. release of gas from pressurized cylinder cools the cylinder Gases Adiabatic Cooling • A body of warm, less dense air rises in the atmosphere – Pressure decreases – Body expands – No source of external energy – Body cools as it does work to equilibrium point • Adiabatic lapse rate – temperatures decrease with height – For dry air DALR = - 9.8 ºC km-1 – For moist air MALR = - 6.5 ºC km-1 LH release from condensation decreases MALR Question Question End • Review Fluids and Fluid Flow • Applications – Groundwater flow – Sedimentation – Water supply – Air and water pollutant distribution – Design of wind turbines – Reduction of drag in vehicles – Flight of birds and aircraft Fluids and Fluid Flow Characterizing flow • Viscosity – Measure of how treacly a liquid is – ‘fluid friction’ – Newtonian fluid - viscosity increases linearly with rate of change of velocity • Compressibility – How much a fluid can be squashed – Common liquids are virtually incompressible – Gases are compressible Fluids and Fluid Flow Characterizing flow • Reynolds number – Ratio of inertial (ρv) to viscous forces (μ/l) ρvl μ Re used in modelling flow Where ρ = density, μ = viscosity, v = velocity, l = length – Useful in physical modeling, at the same Re two fluids behave in the same way Question A scale model has linear dimensions one quarter of full size, how should the flow velocity be increased to show the same behavior? Re = ρvl μ Re1 = Re2 ρv1l1 / μ = ρv2(l1/4) / μ v2 = 4v1 If l is reduced by a factor of 4 v must be increased by a factor of 4 Fluids and Fluid Flow Laminar and Turbulent Flow • Laminar flow – Uniform and orderly – Occurs at low Reynolds numbers, where viscous forces are dominant – Flow rate easy to calculate • Turbulent flow – Random eddies, vortices and other flow fluctuations – Occurs at high Reynolds numbers and is dominated by inertial forces – Flow rate difficult to calculate Fluids and Fluid Flow Laminar and Turbulent Flow The transition between laminar and turbulent flow is often indicated by a critical Reynolds number Flat surface Recritcial = 5 x 10-5 Pipe Recritcial = 2200 Atmosphere Re ~ 109-1012 http://www.ae.su.oz.au/aero/fprops/pipeflow/node7.html Rapid dispersal of pollutants Fluids and Fluid Flow Measuring Flow Rates • • • • Flow rate = amount of fluid passing one point at any time (m3 s-1) Flow velocity = speed of flow (m s-1) Flow rate for a small stream can be measured with a timed bucket fill, not practical for larger bodies – Requires conversion from flow velocity (easier to measure) to flow rate Volume passing a point in one second equals the area multiplied by the distance travelled downstream in one second Q=vA Where v = velocity (m s-1), Q = flow rate (m3 s-1) and A = crosssectional area (m2) Question How would you measure flow velocity? With a float and time or a current meter (looks like an anemometer) Fluids and Fluid Flow Measuring Flow Rates • At constant Q, decreasing cross-sectional area increases velocity decrease A v increases Principle of continuity of flow – the same amount of water passes each point in one second anywhere down its length Fluids and Fluid Flow Laminar Flow in a Pipe Fluids and Fluid Flow Laminar Flow in a Pipe • • One of the few types of flow that can be described by simple equation Flow is modelled assuming thin layer at wall does not move, water closer to center moves rapidly Flow rate = p1 – p2 = π pr 4 R 8ηL Poiseuille’s Law • Where r = radius of pipe, η = viscosity, p = pressure difference, L = length Not valid for turbulent flow or large velocity and pressures Question Suppose the flow rate is 100 cm3 s-1. What are the effects of doubling each of the parameters? Double length → 50 cm3 s-1 Double viscosity → 50 cm3 s-1 Double pressure → 200 cm3 s-1 Double radius → 1600 cm3 s-1 Fluids and Fluid Flow Bernoulli’s Principle • Derived from Law Conservation of Energy - Sum of all forms of energy in a fluid flowing along an enclosed path is always constant PV + ½ m v2 + mgh = constant PV + ½ m v2 + mgh = constant V V V P + ½ ρ v2 + ρgh = constant • • Where P = pressure, ρ = density, v = velocity, g = gravity and h = height Law conservation of energy – a reduction in energy due to a change in either p, KE or PE must be compensated by an increase in another Fluids and Fluid Flow Bernoulli’s Principle • Pressure decreases when velocity is increased http://www.wfu.edu/physics/demolabs/demos/avimov/bychptr/chptr4_matter.htm Fluids and Fluid Flow Venturi Effect • Reduction of pressure when velocity is increased Used to measure flow Fluids and Fluid Flow Aerodynamics and Aerofoils Newtonian explanation • Lift occurs when a moving flow of gas is turned by a solid object – Equal and opposite force acts from below Bernoulli explanation • As air travels at different velocities around a solid pressure changes, adding up the pressure changes x area of wing gives lifting force Cannot be based on shape of wing: Planes fly upside down Paper planes fly Fluids and Fluid Flow Atmospheric Transport • Dilute and disperse – high stacks • Temporal and spatial scales are large – Horizontal motion - wind – Vertical motion - convection and turbulence • Pollution that reaches the stratosphere may not be removed for 100’s of years Fluids and Fluid Flow Atmospheric Transport • • • Gaussian plume model Assumes pollution drifts with wind, spreading out at a rate dependent on turbulent diffusion and concentration Depends on height, wind speed, surface roughness and atmospheric effects Fluids and Fluid Flow Atmospheric Transport r H z A B Q = rate of emission (kg s-1), u = average wind speed, P = concentration (kg m-3) H P B = spread out, dec. P Fluids and Fluid Flow Atmospheric Transport • Amount of pollution passing point A = amount emitted Q = π r2 u P • Plume hits ground when r = H, when plume hits the ground: Pmax = • To minimize P – Reduce Q – Increase H (higher stack) – Increase u (windy sites) Q π u H2 More likely to have pollution in middle of plume Fluids and Fluid Flow Plumes • Emitted gas tempeature is higher than surroundings, initial movement is upwards Pmax = NQ u(H + h)2 Where N is typically 0.15 • • Higher stacks reach higher level winds (less turbulence) Pollutant may travel 100-1000s km before being washed out Fluids and Fluid Flow Plumes (a) inversion coning (b) weak lapse (c) weak lapse below, inversion aloft trapping (d) lapse below, inversion above (e) Inversion below, lapse aloft fummigation lofting Plume shape depends on stability of atmosphere fanning Fluids and Fluid Flow Surface Tension At the surface of the liquid, the molecules are pulled inwards but they are not attracted as intensely by the molecules in the air Therefore all of the molecules at the surface are subject to an net inward force Results in relatively strong surface of water Each molecule is pulled equally in all directions by neighboring molecules, resulting in a net force of zero Fluids and Fluid Flow Surface Tension • • Explains roundness of droplets (smallest surface area) Shapes meniscus Force circumference = gravity Force = 2 π r γ = mg 2 π r γ = π r2hρg 2 γ = rhρg h = 2 γ / rρg h ~ 15 / R End • Review Hydrology • h Hydrology and Hydrogeology Hydrological Processes • h Hydrology and Hydrogeology Darcy’s Law • h Hydrology and Hydrogeology Groundwater Flow • h Books • Jones, A.M. (1997) Environmental Biology. Routledge, London. p124. • Price, M. (1985) Introducing Groundwater. Chapman & Hall, London. • Seinfeld, J., and Pyros, S.N. (1998) Atmospheric Chemistry and Physics: From Air Pollution to Climate Change. John Wiley, New York. Further Reading • Eastlake, C.N. (2002) An Aerodynamicist's View of Lift, Bernoulli, and Newton. The Physics Teacher, Vol. 40, pp.166 . • Noerdlinger, P.D. and Brower, K.R. (200?) The Melting of Floating Ice Raises the Ocean Level. Unpublished article. • Rosenfeld, D. (2000) Supression of rain and snow by urban and industrial air pollution. Science, Vol. 287, pp. 1793.