Download Exercise in Physical Chemistry

AY2015 NIT Ibaraki College
Yoshiharu MIYASHITA
Exercise in Physical Chemistry
Email: [email protected]
Basic Information
Course
Regular Course
Compulsory / Elective
Elective
Grade
4th
Number of Credits
1
Semester
Full year
Credit Type
Normal
Class Type
Technical Subject
Course Objectives
This subject is designed to learn chemical thermodynamics. The course objective is to understand
chemical thermodynamics through doing exercises and calculation of thermodynamic parameters such as
heat, work, internal energy, enthalpy, entropy, and free energy.
Topic Outline / Schedule
Week
1
2
3
Topic
Systems
First Law of Thermodynamics
Isothermal Process for Ideal Gas 1
Outline
Exercises in Types of Thermodynamic Systems
Exercises in the First Law of Thermodynamics
Exercises in Expansion and Compression of Ideal Gas in
Isothermal Irreversible Process
4
Isothermal Process for Ideal Gas 2
5
6
7
8
9
10
Internal Energy for Ideal Gas
Enthalpy
Mid-term Review on 1st semester
Heat Capacity
Equipartition of Energy
Adiabatic Process for Ideal Gas 1
Exercises in Expansion and Compression of Ideal Gas in
Isothermal Reversible Process
Exercises in Joule's Law
Exercises in an Enthalpy
11
Adiabatic Process for Ideal Gas 2
12
13
Heat of Reaction
Enthalpy of Formation
14
15
16
17
18
19
Temperature Dependence of Heat of
Reaction
Review on 1st semester
Second Law of Thermodynamics 1
Second Law of Thermodynamics 2
Entropy
Entropy Change
20
Third Law of Thermodynamics
Exercises in Heat Capacity and Mayer's Relation
Exercises in Law of Equipartition of Energy
Exercises in Poisson's Equation
Exercises in Expansion and Compression of Ideal Gas in
Adiabatic Process
Exercises in Hess's Law
Exercises in Calculation of Heat of Reaction by Using
Standard Enthalpy of Formation
Exercises in Calculation of Heat of Reaction at Various
Temperature
Exercises in the Second Law of Thermodynamics
Exercises in Carnot Cycle and Efficiency of Heat Engine
Exercises in an Entropy?
Exercises in Calculation of Entropy Changes in Some
Basic Processes
Exercises in Boltzman's entropy Equation and the Third
Law of Thermodynamics?
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AY2015 NIT Ibaraki College
21
22
23
Law of Increasing Entropy
Mid-term Review on 2nd semester
Free Energy
Exercises in Clausius Inequality
24
Gibbs Free Energy Change
25
26
Clausius-Clapeyron Equation 1
Clausius-Clapeyron Equation 2
Exercises in Calculation of Gibbs Free Energy Changes
in Some Basic Processes
Exercises in Derivation of Clausius-Clapeyron Equation
27
Chemical Equilibrium 1
28
Chemical Equilibrium 2
29
Electromotive Force
30
Review on 2nd semester
Exercises in a Free Energy?
Exercises in Use and Application of Clausius-Clapeyron
Equation
Exercises in Relationship between Equilibrium Constant
and Free Energy
Exercises in Temperature Dependence of Equilibrium
Constant
Exercises in Relationship between Electromotive Force
and Free Energy
Textbooks and Other Readings
There is no required textbook for this subject. Relevant books will be introduced whenever necessary.
Relevant books:
G. Sugihara, T. Inoue, H. Akisada, Physical Chemistry Centering around Chemical Thermodynamics (3rd
Edition), Gakujutsu Tosho Shuppan-sha, 2011 (in Japanese)
P. Atkins, Atkins' Physical Chemistry (10th Edition), Oxford University Press, 2014*
* available in our library
Relevant Online Resources
First Law of Thermodynamics / Internal Energy (YouTube)
https://www.youtube.com/watch?v=Xb05CaG7TsQ
The Second Law of Thermodynamics (YouTube)
https://www.youtube.com/watch?v=4nPGS8xgzKw
The Third Law of Thermodynamics (YouTube)
https://www.youtube.com/watch?v=hBqcGWzHQbY
Using Free Energy (YouYube)
https://www.youtube.com/watch?v=MALZTPsHSoo
Grading Policy
Grading will be based on tests given in every week. To get credit, you need to get 60 or more points in total.
Course Description
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AY2015 NIT Ibaraki College
This subject is for studying physical chemistry mainly concerning chemical thermodynamics. To prepare
and review each lecture, you need to check the books, papers or websites introduced in class.
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