Survey
* Your assessment is very important for improving the workof artificial intelligence, which forms the content of this project
* Your assessment is very important for improving the workof artificial intelligence, which forms the content of this project
Waternet M.Sc in Integrated Water Resources Management: Introduction To Hydrogeology, Chapter 1 CHAPTER 1 Preliminary concepts and Overview Ron Chaoka Department of Geology, University of Botswana. Gabarone. Botswana. 1.1 Hydrogeology Hydrogeology is the study of groundwater. It is concerned with, but is not limited to, the distribution, occurrence, and movement of groundwater; physical and chemical interactions between groundwater and geologic formations; groundwater contamination; transport of chemical constituents by groundwater. Hydrogeology is one of the main branches of hydrology, and is sometimes referred to as groundwater hydrology. Hydrogeology is an interdisciplinary field. It requires a good understanding of chemistry, physics, geology, and mathematics. A basic understanding of hydrogeology is useful to engineers, soil physicists, planners, and others. Historically, the study of groundwater was almost entirely motivated by its importance as a resource. Thus groundwater exploration, evaluation, and exploitation were given a great deal of attention. Considerable effort was also devoted to understanding the principles governing groundwater flow. These are critical to the development of water supplies and the sustainable management of groundwater resources. While water supply aspects are still important, the emphasis in groundwater studies, particularly in developed countries, has shifted over the past several decades from water supply problems to other aspects. These include geochemical aspects, groundwater contamination and transport processes, the role of groundwater in environmental and geotechnical engineering problems as well as in geological processes. Geotechnical, mining, and civil engineers invariably have to take into consideration the impact of groundwater on their engineering designs. Massive inflows of groundwater into a tunnel, excavation, or mine can delay tunnel driving and mining operations for a considerable length of time. Increased groundwater pressures beneath a dam can lead to dam failure. Excessive groundwater Waternet M.Sc in Integrated Water Resources Management: Introduction To Hydrogeology, Chapter 1 withdrawals can lead to land subsidence and severe problems for engineering design. While the role of groundwater in geological processes such as crustal deformation, earthquake generation, ore deposit formation, migration and accumulation of petroleum is recognized, it is not very well understood. 1.2 Groundwater occurrence Groundwater may be found almost anywhere in the world and in almost all types of geologic formations. However, its distribution in terms of quantity and quality varies from one place to another and from one geologic formation to another. One of the greatest challenges to a hydrogeologist and /or a geophysicist, therefore, is to locate geological formations with sufficient water of reasonable good quality for a particular use. There are at least three factors that influence groundwater occurrence: hydraulic properties of geological formations, geological framework, and climate. Hydraulic properties of geological formations are those properties that govern groundwater storage and transmission. These include pores, vesicles, lava tubes (and tunnels), solution cavities, bedding planes, foliation, faults, shear zones, unconformities, and intrusive contacts. Some of these structures are primary; that is, they were formed at the same time as the formation. Others were formed after the formation was formed and are referred to as secondary. The generic term for the relative volume of a geologic formation in which water can be stored is porosity regardless of whether that volume consists of pores or other types of openings. Geological formations with interconnected openings are said to be permeable. The ability of a geological formation to transmit water and yield it in usable quantities to wells depends on its permeability. Geological formations differ considerably in their ability to store and transmit water. Knowledge of typical values of porosity and permeability of different geological formations is a prerequisite for successful groundwater exploration. Virtually all groundwater originates as surface water. In order to reach the saturated zone, water must not only be available at the surface; it must also be able to infiltrate to the saturated zone. The availability of water at the surface depends on climate, while the infiltration rate depends on the thickness and 1-2 Waternet M.Sc in Integrated Water Resources Management: Introduction To Hydrogeology, Chapter 1 permeability of the unsaturated zone as well as topography. Geological framework includes topography, type of geologic formation, physical and chemical characteristics of surficial or unconsolidated deposits overlying bedrock. 1.2.1 Hydraulic properties of geological formations Hydraulic properties of geological formations were defined in the preceding section as those properties that govern groundwater storage and transmission. The definitions of some of the most important hydraulic properties are provided below. Porosity ( n ) Porosity is the ratio of the volume of the voids or interstices in a given volume of geologic material to the total volume of material n Uv U (1.1) Where U v is the volume of the voids and U is the total volume of material. It may be expressed as a decimal fraction or as a percentage. Porosity ranges from 1 percent to as much as 80 percent in some recently deposited clays, but in most granular materials it falls between about 5 and 40 percent (Table 1.1). There are two types of porosity: primary and secondary. The former is developed during the formation of geological materials, while the latter is formed after. Specific yield (Sy) Specific yield is the ratio of the volume of water that drains from a saturated volume of geologic material under gravity ( U d ) to the total volume of the material: Sy Ud U (1.2) Table 1.1. Range of values of porosity (Kresic, 1997; Freeze and Cherry, 1979) __________________________________________________ n (%) __________________________________________________ Unconsolidated deposits Gravel 25-40 Sand 25-50 1-3 Waternet M.Sc in Integrated Water Resources Management: Introduction To Hydrogeology, Chapter 1 Silt Clay 35-50 40-80 Rocks Fractured basalt Vesicular Tuff Pumice Weathered volcanic rocks Sandstone Limestone, dolomite Shale Fractured crystalline rocks Dense crystalline rocks 5-50 10-50 15-40 60-90 15-60 5-30 <1-20 <1-10 <1-10 <1-5 In general the term specific yield is used to describe the storage capacity of an unconfined aquifer (see section 1.2.2). Values of specific yield typically range from 0.1 to 0.3, and are always less than the porosity of the geologic material. Specific Retention (Sr) Specific retention is the ratio of the volume of water a saturated volume of geological material retains against gravity ( U r ) drainage to the total volume of the material Sr Ur U (1.3) The sum of the specific yield and the specific retention is equal to porosity. Figure 1.1 (Bear, p. 485) shows the relationship between median grain sizes of various granular materials and the hydraulic properties defined above. Figure 1.1: Relationship between specific yield, specific retention, porosity and grain size (Bear, 1972) 1-4 Waternet M.Sc in Integrated Water Resources Management: Introduction To Hydrogeology, Chapter 1 Permeability (k) This is a measure of the ability of a formation to transmit water. It depends only on properties of the geological formation. Permeability is measured in units of length squared or in darcy units. Table 2.2 shows the range of values of permeability. Table 2.2 Range of values of permeability (Freeze and Cherry, 1979) Rocks Unconsolidated deposits k (darcy) 5 10 10 4 10 103 10 2 10 Gravel 10 Unfractured metamorphic and igneous rocks Shale Unweathered marine clay Glacial till Silt, loess Silty sand Clean sand Karst limestone Permeable basalt Fractured igneous and metarmorphic rocks Limestone and dolomite Sandstone K 2 (cm ) 10 -3 -4 -5 -6 10 -8 1 10 -1 -9 10 10 10-2 10-10 -3 10 -4 10 -5 10 -6 10 10 -7 10 10-8 10-16 10 10 10 10 -11 -12 -13 -14 -15 1.2.2 Hydrological classification of geological formations Saturated geological formations can be divided into three types depending on their ability to transmit water: aquifer, aquitard, and aquiclude. 1. An aquifer is a saturated geological formation that is sufficiently permeable to transmit water and yield it in usable quantities to a well or spring. 2. An aquitard is a saturated geological formation that is not permeable enough to yield water to a well or spring in usable quantities, but is permeable enough to allow an interchange of groundwater in between adjacent aquifers. 1-5 Waternet M.Sc in Integrated Water Resources Management: Introduction To Hydrogeology, Chapter 1 3. An aquiclude is a nearly impervious geological formation that is virtually incapable of transmitting groundwater. These definitions not withstanding, it must be pointed out that in nature there is no such thing as an impermeable geological formation. All geological formations have some permeability. However, it is difficult to provide definitions of aquifer and aquitard in terms of permeability because the difference between an aquifer and aquitard also depends on local conditions. Aquifers may be divided into three main types: confined, unconfined, and leaky (Figure 1.2). A confined aquifer is bounded above and below by an aquiclude (Figure 1.2a). Water-level elevations in wells tapping a confined aquifer are above the top of the aquifer; otherwise the aquifer is unconfined. The water in a well tapping a confined aquifer may rise above ground surface. Such a well is referred to as a flowing artesian well. An imaginary surface joining water-level elevations in a confined aquifer is known a potentiometric surface. water level aquiclude Confined aquifer aquiclude Figure 1.2a. Conceptual model of a confined aquifer. An unconfined aquifer, also known as a water table aquifer, is bounded below by an aquiclude and above by a water table, which is the surface joining water-level elevations in an unconfined aquifer (Figure 1.2b). There is a special type of unconfined aquifer known as a perched aquifer (Figure 1-6 Waternet M.Sc in Integrated Water Resources Management: Introduction To Hydrogeology, Chapter 1 1.2c). Perched aquifers are formed where lenses of low-permeability material occur within otherwise permeable material. The low-permeability material does not allow infiltrating water from the ground surface to pass through it. water level watertable Unconfined aquifer aquiclude Figure 1.2b: Conceptual model of an unconfined aquifer. A leaky aquifer is a type of confined aquifer in which one or both boundaries are aquitards (Figure 1.2c). As a result, water from overlying or underlying aquifers is free to move through the aquitard(s). As the preceding discussion implies, aquitards and aquiclude constitute the confining units. perched aquifer water-table Unconfined aquifer Aquitard Leaky aquifer Aquiclude Confined aquifer Aquiclude Figure 1.2c: Multilayered aquifer system showing a leaky and a perched aquifer. 1-7 Waternet M.Sc in Integrated Water Resources Management: Introduction To Hydrogeology, Chapter 1 1.3 Geological Processes and Formations The occurrence, distribution, movement, and composition of subsurface waters are intricately linked to the structure and nature of geological formations. One of the primary objectives of hydrogeological investigations is to identify geological formations and structures of importance for the occurrence of groundwater. A basic understanding of the different types of geological formations, as well as the events that produce them and their fundamental properties is required to achieve the objectives of such an investigation. The main objective of this section is to give a brief description of various geological processes that give rise to the different geological formations. Geological formations consist of rocks and their weathering products. A rock consists of an agregate of one or more minerals. A mineral on the other hand may be defined as a naturally occurring crystalline substance formed by inorganic or organic processes. There are three main groups of rocks: igneous, sedimentary and metamorphic. Once formed, rocks are susceptible to weathering, alteration, deformation, and transformation. Figure 1.3 is a schematic diagram of the rock cycle. It illustrates the role of various geological processes in the formation of the different types of rocks. It also shows how one rock is transformed into another by processes that act on and within the earth. 1.3.1 Igneous rocks As Figure 1.3 shows, igneous rocks form mainly from silicate melts (molten rock) by a process called crystallization. The melts or magmas from which igneous rocks form are produced by partial melting of pre-existing solid rock. Melting may be induced by changes in temperature, pressure, or an influx of water which depresses the melting point of the solid. Partial melting occurs at different levels within the earth’s crust and upper mantle and gives rise to a wide variety of magma compositions. However, most igneous rocks are composed mainly of silicon, oxygen with lesser amounts of aluminium, iron, magnesium, calcium, sodium, and potassium. 1-8 Waternet M.Sc in Integrated Water Resources Management: Introduction To Hydrogeology, Chapter 1 MAGMA Cooling and solidification (Crystallization) Melting Heat and pressure IGNEOUS METAMORPHIC ROCK ROCK W ea the ri ng , tr an sp or ta ion , Heat and pressure (Metamorphism) an dd ep osi t Weathering, transportation, and deposition ion Weathering, transportation, and deposition SEDIMENTARY ROCK Cementation and compaction (Lithification) SEDIMENT Figure 1.3: Schematic diagram of the rock cycle Crystallization of molten rock may occur within the earth to form intrusive igneous rocks or at the earth's surface following an eruption to form volcanic or extrusive igneous rocks. In general, extrusive rocks are fine-grained to glassy, while intrusive rocks are medium- to coarse-grained. Igneous rocks exhibit a wide variety of fabrics (textures) as well as chemical and mineralogical compositions. These characteristics have been used as a basis for classification schemes. Textural classifications are based on the degree of crystallinity (i.e. proportion 1-9 Waternet M.Sc in Integrated Water Resources Management: Introduction To Hydrogeology, Chapter 1 crystalline material to glass), grain size and shape, and the mutual arrangement of mineral grains within an igneous rock. Mineralogical classification schemes are based on modal composition; that is, the volumetric proportions of essential minerals in a rock. In contrast, chemical classification schemes are based on the bulk or whole rock chemical composition expressed in terms of weight concentrations on a percentage basis of major elements. 1.3.2 Sedimentary Rocks Sedimentary rocks are those rocks formed at or near the earth's surface at relatively low temperatures and pressures. They can be divided into clastic (detrital) and chemical sedimentary rocks. The main constituents of clastic sedimentary rocks are rock fragments and minerals. They are produced by weathering and erosion of pre-existing rocks. The products of weathering and erosion are transported and deposited by water, wind or ice. Clay minerals and quartz are the most abundant constituents of detrital sedimentary rocks, followed by rock fragments. Chemical sediments are derived from soluble material produced largely by chemical weathering. Chemical sediments are formed by precipitation of dissolved constituents. Precipitation occurs a result of inorganic processes such as evaporation or changes in the saturation status of the solution due to changes in temperature, pressure, and chemical activity. Some chemical sediments are produced by the action of living organisms. These are referred to as biogenic sediments. One rock type that is neither clastic nor chemiclal is coal. Coal is formed from accumulations of carbonaceous material derived from vegetation. The transformation from carbonaceous material to coal involves burial, compaction, and slight heating. Sedimentary rocks may be classified on the basis of various criteria such as (a) composition; (b) grain size; (c) grain shape; (d) orientations of the grains; and (e) the packing of the grains. For example, detrital sedimentary rocks may be divided into three groups on the basis of grain size of the detrital fragments and minerals (Table 1.1). As Table 1.1 shows, however, it may be difficult to distinguish among 1-10 Waternet M.Sc in Integrated Water Resources Management: Introduction To Hydrogeology, Chapter 1 different rock types on basis of one criterion or even two criteria. For example, both conglomerate and breccia consist of rock fragments and minerals within the same grain-size range but have different names because their constituent materials have different shapes. Therefore, additional modifiers and subdivisions are required to make classification systems more useful. Table 1.1: Classification of Clastic Sedimentary Rocks Sediment Name and Rock Name Particle Size Gravel (>2 mm) Conglomerate Breccia Sand (1/16 - 2 mm) Sandstone Silt and clay (<1/16 mm) Siltstone Shale Mudstone Three stages are involved in the transformation of sediments into sedimentary rocks: compaction, cementation and lithification (Figure 1.3). Cementation refers to the binding together of constituents of sedimentary rocks. Cements are formed by precipitation of chemical constituents dissolved in pore fluids. 1.3.3 Metamorphic rocks Metamorphic rocks form from other rocks by essentially solid-state changes in mineralogy and/or texture as a result of changes in temperature (T), pressure (P), and prevailing stress condition. Apart from possible losses or gains of minor amounts of volatile constituents (e.g. H2O, CO2, O2, and S), most metamorphic rocks have chemical compositions close to their precursors. However, in the type of metamorphism called metasomatism, significant changes to the chemical composition of the original rock body may occur due to the introduction of chemical constituents from an external source by metasomatic fluids. 1-11 Waternet M.Sc in Integrated Water Resources Management: Introduction To Hydrogeology, Chapter 1 The response of a solid rock body to changing P, T, and X (chemical composition) conditions depends on (1) the nature of the original rock; (2) the grade of metamorphism, that is, the relative temperature of metamorphism; and (3) presence or absence of a fluid phase. Various types of metamorphism are recognized. These include thermal (contact), dynamic, regional, burial, and retrograde metamorphism as well as metasomatism. Thermal metamorphism is associated with magmatic intrusions at shallow crustal levels. It is essentially isochemical. Dynamic metamorphism occurs in rocks subjected to intense localized stresses such as those due to meteorite impacts. Rocks produced by this type of metamorphism are rare. Regional metamorphism, as the name implies, occurs on a large scale under a wide range of pressure and temperature conditions. It is associated with mountain building and magmatism and is characterised by penetrative deformation. In contrast to regional metamorphism, burial metamorphism is not related orogeny or magmatism. It is due to pressure and temperature changes associated with thick sequences of volcanic and sedimentary rocks. The transformation of high-grade metamorphic mineral assemblages to low grade mineral assemblages is referred to retrograde metamorphism. Metamorphic rocks can be classified on the basis of fabric, field relations, mineralogical and chemical composition as well as the inferred pressuretemperature conditions of metamorphism. The inferred P-T conditions are based on characteristic mineral assemblages. The classification most commonly used is that based on foliation. Foliated texture is characterized by parallel alignment of minerals and structural features of metamorphic rocks. On the basis of these characteristics, metamorphic rocks can be divided into strongly foliated, weakly foliated, and nonfoliated. Strongly foliated rocks possess strong planar fabric and have a strong parallelism of prismatic minerals. They break easily along foliation planes. In contrast, weakly foliated rocks have a weak parallelism of prismatic minerals and/or diffuse planar fabric. Nonfoliated rocks are typically massive. 1.3.4 Rock deformation Most rocks are deformed. The most common manifestations of rock deformation are folds and fractures. Folding involves bending or warping of rocks in response 1-12 Waternet M.Sc in Integrated Water Resources Management: Introduction To Hydrogeology, Chapter 1 to compressive stresses. It is best observed in rocks containing planar structures such as rock strata, bedding planes, foliation or cleavage. The most common types of folds are anticlines and synclines (Figure 1.4a). Folds are often associated with extension fractures and normal faults on the convex side and thrust faults on the concave side of anticlines (Figure 1.4b). A n tic lin e S y n c lin e A n tic lin e Y o u n g e s tro c k O ld e s tro c k Figure 1.4a. Types of folds A B Ex t. t. Ex C N m Co p. Co m p. A - Tensile fracture B - Normal fault C - Thrust fault (rare) N - Neutral surface Figure 1.4b. Types of fractures associated with folds. The term fracture without qualification refers to any break in a material. Many different types of fractures are found in rocks. These may be divided into two types: (1) fractures along which displacement has occurred parallel to the fracture surfaces and (2) fractures along which no movement has occurred. The former 1-13 Waternet M.Sc in Integrated Water Resources Management: Introduction To Hydrogeology, Chapter 1 includes faults and shear fractures (shear zones), while the latter includes joints, gashes, fissures, and veins. Displacements in shear zones and along faults range from a few meters to hundreds of kilometers. Folds and faults affect groundwater regimes in many different ways. In general folding can lead to a complicated distribution of recharge and discharge zones, aquifers as well as local and regional flow systems. Fractures may facilitate groundwater storage and transmission or act as barriers to groundwater flow. They may also affect the distribution and occurrence of aquifers. Due to their importance in hydrogeology, fractures constitute important targets for groundwater exploration. 1.4 Soil moisture and groundwater Subsurface waters can be divided into vadose water and groundwater. Vadose water occurs in the vadose (unsaturated) zone, which comprises the soil moisture zone, the intermediate zone, and the capillary zone. Below the vadose zone is the saturated zone (Figure 1.5). Groundwater only refers to water in the saturated zone. The boundary between the vadose zone and the saturated zone is defined as the surface on which the fluid pressure in the pores of the porous medium is exactly atmospheric. It is referred to as the water table. Above the water table, fluid pressure is less than atmospheric, whereas below it the pressure is greater than atmospheric. The vadose zone typically extends from land surface to the saturated zone and its thickness varies from place to place depending on climatic conditions. For example, in wetlands, the thickness of the vadose zone may fluctuate seasonally or may even be non-existent. By contrast, in arid environments the vadose zone may not contain water for considerable depths. The interstitial spaces within the soil moisture zone are partly filled with water and partly filled with air. Soil moisture refers to all the subsurface water in the unsaturated zone. It occurs as films around soil particles and is held by surface tension forces. There are two types of surface tension forces: adhesive and cohesive forces. Adhesive forces are due to attraction between molecules of dissimilar substances (e.g., water and 1-14 Waternet M.Sc in Integrated Water Resources Management: Introduction To Hydrogeology, Chapter 1 soil particles or water and air). They are strong, but very short-range forces. Cohesive forces are due to attractions between molecules in like substances. Ground surface 0 +ve +ve -ve 0 +ve Unsaturated or Vadose zone Soil water zone Saturated zone Capillary fringe Water table depth Intermediate zone Groundwater = (a) (b) (c) Figure 1.5: (a) Zones of subsurface water, (b) profile of moisture content , and (c) profile of pressure head versus depth. As a result of surface tension (capillarity), water molecules at the water table are subject to an upward attraction. An expression for the height of capillary rise in unsaturated soils is usually arrived at by utilising an approach similar to that used in classical physics for the analysis of the binding of water in a glass capillary. The phenomenon of capillarity may be illustrated by inserting one end of a fine glass tube of radius r into water as shown in Figure (1.6). As a result of capillarity, water will rise in the tube to a height hc. The rise of the water in contact with the tube is attributed to the attraction between the sides of the tube and the water molecules (adhesive forces). In contrast, the rise of the water not directly in contact with the walls of the tube is due to cohesive forces between water molecules. Water will eventually stop rising when the downward pull of gravity exactly equals the sum of the adhesive and cohesive forces (Figure 1.7). 1-15 Waternet M.Sc in Integrated Water Resources Management: Introduction To Hydrogeology, Chapter 1 cos r hc Water Adhesion Cohesion Gravity Adhesion Figure 1.6: Illustration of capillary rise using a glass tube b a Figure 1.7: Diagram showing the forces acting on a column of water in a glass tube An equation for the height of capillary rise hc may be written by considering the forces acting on the column of water in the glass tube. The force acting downward Fd is the weight of the column of water and is given by Fd hc r 2 w g (1.4) Where w is the density of water and g is the acceleration due to gravity. The force acting upward Fu is the vertical component of the surface tension which acts around the circumference of the tube Fu 2 r cos (1.5) Where is the angle of wetting between the liquid and the glass. At the point of maximum capillary rise Fd must be equal to Fu. Thus 1-16 Waternet M.Sc in Integrated Water Resources Management: Introduction To Hydrogeology, Chapter 1 hc 2 cos w gr (1.6) Fluid pressures in the unsaturated zone are measured with a device known as a tensiometer. A tensiometer consists of a tube, which is fitted at one end with a liquid-filled porous ceramic cup, and at another end with a vacuum gauge (Figure 1.5). When a tensiometer is inserted into an unsaturated soil, water will flow out of the tensiometer through the pores in the ceramic cup. This creates a partial vacuum in the tube, which can be read from the vacuum gauge (Figure 1.8). Soil moisture is an important source of water for plant growth. It is also important for mineral weathering, which provides nutrients for plant growth. Vaccum gauge Connecting tube Ground level Porous cup Figure 1.8: Tensiometer with vacuum gauge, porous cup, and connecting tube. 1.5 Groundwater and geologic processes Groundwater plays an important role in many geological processes. Examples include faulting, earthquake generation, ore deposit formation, diagenesis, metamorphism as well as the migration and accumulation of hydrocarbons. Until the role of fluids in faulting was understood, it was very difficult to explain the movement of large slices of continental crust (thrust blocks) over large distances. The main problem was that the horizontal forces required to move the thrust 1-17 Waternet M.Sc in Integrated Water Resources Management: Introduction To Hydrogeology, Chapter 1 blocks thousands of metres thick tens of kilometres would create stresses that greatly exceeded the strength of any known rock. The paradox was eventually resolved when it was realised that pore water pressures in faults at depth greatly reduced the normal component of the intergranular stress in the fault plane and hence reduced the critical value of the shear stress required to produce sliding. As a result, horizontal forces that exceeded the strength of the rock were not needed to produce sliding. There is also a strong correlation between earthquake generation and elevated fluid pressures in the earth's crust. Earthquakes are generally associated with rupturing of the earth's crust and movements along faults in the earth's crust. The movement occurs when a rock that has been subjected to stress suddenly ruptures or whenever the frictional forces on the fault surfaces are overcome. It is now generally accepted that elevated pore water pressures in faults at depth contribute to the generation of earthquakes by reducing the frictional resistance at which the rock should fail. The origin of some (many) ore deposits is also attributed to mechanisms involving groundwater flow. These include the so-called Mississippi Valley-type (MVT) leadzinc deposits that are commonly found in porous carbonate rocks; sedimenthosted uranium deposits; and evaporites. In the case of MVT ore deposits there is a lot of evidence to suggest that they were deposited from deeply circulating heated saline connate waters at moderately high temperatures (80 to 1500C and at relatively shallow levels in the earth's crust. Evaporites as the name implies were formed by precipitation during the evaporation of brines. They can be divided into marine and nonmarine evaporites. The former precipitated from seawater, while the source of the latter is believed to be groundwater. Virtually all rocks undergo some physical and chemical changes after deposition and/or crystallization from magmas. The main changes in which groundwater plays a significant role are diagenesis and metamorphism. Diagenesis refers to all the changes undergone by sediments after initial deposition and during and after lithification. Most sediments contain pore fluids at the time of deposition. The increase in temperature and pressure that accompanies burial of a sediment 1-18 Waternet M.Sc in Integrated Water Resources Management: Introduction To Hydrogeology, Chapter 1 affects the solubility of substances and may lead to precipitation or dissolution of some minerals. Although metamorphism occurs at temperatures and pressures higher than those for diagenesis, there is no agreement on exactly where metamorphism begins and diagenesis ends. Metamorphism involves changes in the texture and mineralogy of a rock as a result of changes in temperature and pressure and the action of chemically active fluids. Geologists and geochemists have used oxygen and hydrogen isotopes to show that meteoric fluids (water) are abundant in many metamorphic environments. 1.6 Groundwater in the hydrologic cycle Water on earth resides in the atmosphere, on the surface of the earth, and below the surface of the earth. However, water does not remain in anyone of these environments indefinitely. It is constantly moving among them. This unending circulation of the earth's water is called the hydrologic cycle. The cycle has no beginning or end. Figure 1.9 shows a box model of the hydrologic cycle. Atmosphere ET Vegetation E P E P P-In Land Surface Ro I Soil Rg Rivers and Lakes Q Qs Qg Qg Ground Water Ocean Figure 1.9: Box model of the hydrologic cycle (ET = evapotranspiration, I n = interception, Rg = recharge, Qs = interflow, P = precipitation, E = evaporation, Ro = overland flow, Q = Runoff, and Qg = subsurface flow to streams and oceans). 1-19 Waternet M.Sc in Integrated Water Resources Management: Introduction To Hydrogeology, Chapter 1 Various estimates of the quantity of water in different components of the hydrologic cycle have been made. All of them show that groundwater constitutes an insignificant proportion of the earth's total water balance. As far as the world's freshwater resources are concerned, however, groundwater accounts for almost 97% of the utilizable freshwater resources (excluding icecaps and glaciers). Figure 1.10 shows near-surface hydrologic processes, some of which contribute to groundwater storage. As Figure 1.10 shows, precipitation that falls on land may be intercepted by vegetation, pond on the land surface, flow overland to streams and rivers and eventually end up in the oceans, infiltrate into the ground, flow through the unsaturated zone, and discharge into streams, percolate through the unsaturated zone to recharge groundwater, evaporate from the oceans and the land surface. Some of the infiltrated water is returned to the atmosphere by evapotranspiration. Transpiration Precipitation Precipitation Evaporation Uptake by roots Infiltration Ov er lan df low Int er f lo w Water table Stream Aquifer Figure 1.10: Near surface hydrologic processes 1-20 Waternet M.Sc in Integrated Water Resources Management: Introduction To Hydrogeology, Chapter 1 1.7 Utilization of groundwater in the Southern African Development Community (SADC) The Southern African Development Community is a regional grouping of 14 sovereign states with the main objective of fostering co-operation and mutual benefit from the resources of this region. The SADC member states are shown in Table 1.2. Several SADC member states have limited water resources. Furthermore, some of the available groundwater and surface water resources are shared by two or more states, some of whom belong to the SADC and others are not. Due to the transboundary nature of some of the water resources in the region, SADC member states have long recognized the critical importance of water to regional integration and economic development. As a result, in 1996, SADC established a Water Sector Co-ordination Unit. The SADC Water Sector Co-ordination Unit, among others, collects, analyses, and archives information on water use in each member state. Table 1.2 shows statistics on water use established by the SADC Water Sector Co-ordination Unit from country situation reports for the years 1996 to 1998 (Molapo et al., 2000). Although these figures are slightly outdated and some are rough estimates, they nevertheless show that groundwater is an important component of water use in the SADC region, particularly in Botswana, Namibia, Mauritius, and South Africa to some extent. 1.8 References Bear, J. (1972) Dynamics of Fluids in Porous Media. Dover Publications, New York. Freeze, R. A., and J. A. Cherry. (1979) Groundwater. Prentice Hall, New York. Hornberger, G. M., J. P. Raffensperger, and P. L. Wiberg. (1998) Elements of Physical Hydrology. The Johns Hopkins University Press. Kresic, N. (1997) Quantitative Solutions in Hydrogeology and Groundwater Modelling. Lewis Publishers, New York. Molapo, P., S. K. Pandey, and S. Puyoo (2000) Groundwater Resources Management in the SADC Region: A Field of Future Regional Co-operation. In Sililo et al. (eds) Proceedings of a Conference on Groundwater: Past Achievements and Future Challenges, Balkema, The Netherlands, pp.981-986 1-21 Waternet M.Sc in Integrated Water Resources Management: Introduction To Hydrogeology, Chapter 1 Tarbuck, E. D., and F. K. Lutgens. (1999) Earth: An Introduction to Physical Geology. Prentice Hall, New York. Tindall, J.A., J. R. Kunkel. (1999) Unsaturated Zone Hydrology of Scientists and Engineers. Prentice Hall, New York. Table 1.2. Water use and part of groundwater in the SADC countries (Molapo et al., 2000) SADC Domestic water supply Part of Total water use Part of Member Surface & Groundwater groundwater Surface & Groundwater ground- states ground- only in domestic ground only water in water 106 m3/s water supply water 106 m3/s total water % 106 m3/s 106 m3/s use Angola 130 28 22 2,474 35 1 Botswana 36 15 41 119 76 64 D.R. Congo - - - - - - Lesotho 19 11 58 37 15 41 Malawi 120 35 29 1,161 35 3 Mauritius 170 80 47 620 101 16 que 107 36 34 630 36 6 Namibia 144 53 37 278 140 50 Seychelles - - - - - - South Africa 2,128 319 15 18,965 2,844 15 Swaziland 24 8 33 1,716 40 2 Tanzania 263 66 25 2,423 108 4 Zambia 271 75 28 2,221 189 9 Zimbabwe 410 40 10 3,930 390 10 SADC 3,823 766 20 34,574 4,009 11.6 Mozambi- Figures in bold italics are rough estimates 1-22