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Chemistry SOL Review Packet CH.1 The student will investigate and understand that experiments in which variables are measured, analyzed, and evaluated produce observations and verifiable data. a) designated laboratory techniques; b) safe use of chemicals and equipment; c) proper response to emergency situations; d) manipulation of multiple variables, using repeated trials; e) accurate recording, organization, and analysis of data through repeated trials; f) mathematical and procedural error analysis; g) mathematical manipulations (SI units, scientific notation, linear equations, graphing, ratio and proportion, significant digits, dimensional analysis); h) use of appropriate technology including computers, graphing calculators, and probeware, for gathering data and communicating results; and i) construction and defense of a scientific viewpoint (the nature of science). design and perform controlled experiments to test predictions, including the following key components: hypotheses, independent and dependent variables, constants, controls, and repeated trials. predict outcome(s) when a variable is changed. read measurements and record data, reporting the significant digits of the measuring equipment. demonstrate precision (reproducibility) in measurement. recognize accuracy in terms of closeness to the true value of a measurement. determine the mean of a set of measurements. use data collected to calculate percent error and discover and eliminate procedural errors. use common SI prefixes and their values (milli-, centi-, kilo-) in measurements and calculations. demonstrate the use of scientific notation, using the correct number of significant digits with powers of ten notation for the decimal place. graph data utilizing the following: independent variable (horizontal axis), dependent variable (vertical axis) scale and units of a graph, regression line (best fit curve). calculate mole ratios, percent composition, conversions, and average atomic mass. perform calculations according to significant digits rules. convert measurements using dimensional analysis. use graphing calculators to solve chemistry problems. read a measurement from a graduated scale, stating measured digits plus the estimated digit. use appropriate technology for data collection and analysis, including probeware interfaced to a graphing calculator and/or computer and computer simulations. summarize knowledge gained through gathering and appropriate processing of data in a report that documents background, objective(s), data collection, data analysis and conclusions. explain the emergence of modern theories based on historical development. For example, students should be able to explain the origin of the atomic theory beginning with the Greek atomists and continuing through the most modern quantum models. In order to meet this standard, it is expected that students will make connections between components of the nature of science and their investigations and the greater body of scientific knowledge and research. demonstrate safe laboratory practices, procedures, and techniques. demonstrate the following basic lab techniques: filtering, using chromatography, and lighting a gas burner. understand Material Safety Data Sheet (MSDS) warnings, including handling chemicals, lethal dose (LD), hazards, disposal, and chemical spill cleanup. identify the following basic lab equipment: beaker, Erlenmeyer flask, graduated cylinder, test tube, test tube rack, test tube holder, ring stand, wire gauze, clay triangle, crucible with lid, evaporating dish, watch glass, wash bottle, and dropping pipette. make the following measurements, using the specified equipment: volume: graduated cylinder, volumetric flask, buret mass: triple beam and electronic balances temperature: thermometer and/or temperature probe pressure: barometer and/or pressure probe. identify, locate, and know how to use laboratory safety equipment, including aprons, goggles, gloves, fire extinguishers, fire blanket, safety shower, eye wash, broken glass container, and fume hood. Chemistry SOL Review Packet CH 1 Problems: 1. Review safety contract. Write precautions 27, 29, 33,39,40, and 42 5. Sue found several samples of the same substance in a riverbed. She wanted to find the density of the substance to help identify it. She gathered the following data: 2. Define: filtering, decanting, chromatography, and distillation. Indicate which can be used to separate heterogeneous mixtures and which can be used to separate homogeneous mixtures. Mass (g) 3. Identify laboratory safety equipment in the classroom and their locations. Be sure you understand how to use each one. 4. John performed an experiment in which he was concerned with the effects of changing temperature on the volume of a gas. In his experiment, he changed the temperature of a sealed balloon and found the volume. The following table shows the data he collected: Temperature Temperature Volume Vol/Temp (°C) (K) (mL) (mL/K) 1 -73.0 403 2 -1.0 546 3 0.0 546 4 1.0 545 5 10.0 601 6 100.0 748 a) Complete the above table. b) If you wanted to graph this data which variable would go on the x-axis? the y-axis? c) In which trial is it likely that experimental error has been made? Explain. a) b) Trial # c) d) e) f) g) Volume Density (cm3) (g/cm3) Sample A 5.86 0.31 Sample B 6.24 0.36 Sample C 3.57 0.18 Sample D 1.19 0.06 Sample E 12.27 0.64 Sample F 8.49 0.44 Find the mean (average) value for the density of the unknown substance. According to the following density values, what is the substance Sue has found? a. Silver – 10.49 g/mL d. Gold - 19.32 g/mL b. Titanium – 4.5 g/mL e. Lead – 11.3 g/mL c. Copper – 8.92 g/mL Which sample is it likely that a procedural error has been made? Explain. Discuss the precision and accuracy of Sue’s data. Convert the mass of Sample E to kilograms. Express the answer in scientific notation. Convert the mass of Sample E to milligrams. Express the answer in scientific notation. Calculate the % error of Sue’s data. Chemistry SOL Review Packet CH 2 The student will investigate and understand that the placement of elements on the periodic table is a function of their atomic structure. The periodic table is a tool used for the investigations of a) average atomic mass, mass number, and atomic number; b) isotopes, half lives, and radioactive decay; c) mass and charge characteristics of subatomic particles; d) families or groups; e) periods; f) trends including atomic radii, electronegativity, shielding effect, and ionization energy; g) electron configurations, valence electrons, and oxidation numbers; h) chemical and physical properties; and i) historical and quantum models. In order to meet this standard, it is expected that students will determine the atomic number, atomic mass, the number of protons, and the number of electrons of any atom of a particular element using a periodic table. determine the number of neutrons in an isotope given its mass number. perform calculations to determine the “weighted” average atomic mass. perform calculations involving the half-life of a radioactive substance. differentiate between alpha, beta, and gamma radiation with respect to penetrating power, shielding, and composition. differentiate between the major atom components (proton, neutron and electron) in terms of location, size, and charge. distinguish between a group and a period. identify key groups, periods, and regions of elements on the periodic table. identify and explain trends in the periodic table as they relate to ionization energy, electronegativity, shielding effect, and relative sizes. compare an element’s reactivity to the reactivity of other elements in the table. relate the position of an element on the periodic table to its electron configuration. determine the number of valence electrons and possible oxidation numbers from an element’s electron configuration. write the electron configuration for the first 20 elements of the periodic table. distinguish between physical and chemical properties of metals and nonmetals. differentiate between pure substances and mixtures and between homogeneous and heterogeneous mixtures. identify key contributions of principal scientists including: atomos, initial idea of atom – Democritus first atomic theory of matter, solid sphere model – John Dalton discovery of the electron using the cathode ray tube experiment, plum pudding model – J. J. Thomson discovery of the nucleus using the gold foil experiment, nuclear model – Ernest Rutherford discovery of charge of electron using the oil drop experiment – Robert Millikan energy levels, planetary model – Niels Bohr periodic table arranged by atomic mass – Dmitri Mendeleev periodic table arranged by atomic number – Henry Moseley quantum nature of energy – Max Planck uncertainty principle, quantum mechanical model – Werner Heisenberg wave theory, quantum mechanical model – Louis de Broglie. differentiate between the historical and quantum models of the atom. Chemistry SOL Review Packet 8. Write electron configurations for the following: a. chlorine b. magnesium c. oxygen CH 2 Problems: 1. Electrons have little mass and a __________ charge. They are located in _____________, __________ the nucleus. Protons have a ___________ charge. Neutrons have a ____________ charge. Protons and neutrons are located in the center or ________________ of the atom and comprise most its mass. 9. Define the periodic law. 2. An _____________ is an atom that has the same number of protons as another atom, but has a different number of __________. Some isotopes are radioactive; many are not. 10. Vertical columns are called _____________ and have similar properties because _________________________________. Horizontal rows are called ___________ and have predictable properties based on an increasing number of electrons in the outer orbitals. 3. The __________________ of an element is the same as the number of protons. In a neutral atom the number of _______ are always equal to the number of ______________. All atoms of the same element have the same number of _______. 11. Electronegativity ____________ from left to right and _________ from top to bottom within a group. Atomic radius _____________ from left to right and __________ from top to bottom within a group. Ionization energies generally __________ from left to right and ___________ from top to bottom within a group. Shielding effect is _____________ within a given period and ____________ within given groups from top to bottom. 4. The periodic table is arranged by increasing ______________. 5. Name the following elements: Group 2, Period 5 Group 14, Period 2 6. Using the periodic table, determine the atomic #, mass #, # protons, # electrons, and # neutrons of the following: Element Atomic Mass # # p+ # e# n0 # C I Ca Mn 7. Determine the # protons, neutrons, electrons and mass # of the following: 137 60 +3 31 -3 Ba+2 Ni P Protons Neutrons Electrons Mass # . 12. Name groups 1, 2, 3-12, 17, and 18 on the periodic table. 13. Name the metalloids. 14. Which of the following ahs the largest atomic radius? Ca Ga Li 15. Which of the following has the lowest ionization energy? Na K Rb 16. Which of the following has the greatest electronegativity? Li N F Chemistry SOL Review Packet 17. States the Pauli Exclusion Principle. 18. State Hund’s Rule. 24. Explain the periodic trend of reactivity. 19. Identify the groups that represent the following orbitals: s, p, d, f 25. Briefly describe the contributions to the modern atomic theory of the following scientists: a. Democritus 20. When an atom gains an electron, it becomes ________ charged and is called a(n) _______. When an atom loses and electron, it becomes _______ charged and is called a(n) ________. 21. Define physical and chemical properties. 22. Write the formulas for the seven (7) diatomic molecules. b. Dalton c. JJ Thomson d. Lord Rutherford e. Millikan f. 23. Classify the following as element (E), compound (C), heterogeneous mixture (het), or homogeneous mixture (hom) a. b. c. d. e. f. Water Carbon Salt water Air Tap water Salad dressing Bohr g. Mendeleev h. Plank i. Heisenberg j. de Broglie Chemistry SOL Review Packet CH 3 The student will investigate and understand how conservation of energy and matter is expressed in chemical formulas and balanced equations. Key concepts include a) nomenclature; b) balancing chemical equations; c) writing chemical formulas; d) bonding types; e) reaction types; and f) reaction rates, kinetics, and equilibrium. draw Lewis dot diagrams to represent valence electrons in elements and draw Lewis dot structures to show covalent bonding. use valence shell electron pair repulsion (VSEPR) model to draw and name molecular shapes (bent, linear, trigonal planar, tetrahedral, and trigonal pyramidal). recognize polar molecules and non-polar molecules. classify types of chemical reactions as synthesis, decomposition, single replacement, double replacement, neutralization, and/or combustion. recognize that there is a natural tendency for systems to move in a In order to meet this standard, it is expected that students will direction of randomness (entropy). name binary covalent/molecular compounds. recognize equations for redox reactions and neutralization reactions. name binary ionic compounds (using the Roman numeral system distinguish between an endothermic and exothermic process. where appropriate). predict, draw, and name molecular shapes (bent, linear, trigonal planar, tetrahedral, and trigonal pyramidal). transform word equations into chemical equations and balance chemical equations. write the chemical formulas for certain common substances, such as ammonia, water, carbon monoxide, carbon dioxide, sulfur dioxide, and carbon tetrafluoride. use polyatomic ions for naming and writing formulas of ionic compounds, including carbonate, sulfate, nitrate, hydroxide, phosphate, and ammonium. interpret reaction rate diagrams. identify and explain the effect the following factors have on the rate of a chemical reaction: catalyst, temperature, concentration, size of particles. distinguish between irreversible reactions and those at equilibrium. predict the shift in equilibrium when a system is subjected to a stress (Le Chatelier’s Principle) and identify the factors that can cause a shift in equilibrium (temperature, pressure, and concentration.) Chemistry SOL Review Packet CH 3 Problems: 1. State the law of definite proportions. e. Carbon dioxide f. Iron(III) sulfate g. Sulfur dioxide 2. Define empirical formulas, molecular formulas, and structural formulas. 3. What is the difference between an ionic bond and a covalent bond in terms of electrons. h. Carbon tetrachloride i. Methane j. Ammonia 4. Define ionization energy. 5. Define electronegativity. 9. Draw the lewis dot diagram for the following: S Br Ca 6. Define polarity. 7. Name the following compounds: a. PbCl2 b. Fe2O3 10. Draw examples of molecules with the following molecular shapes: Linear Trigonal Planar c. P2O5 d. Cu2CO3 Bent Tetrahedral e. BCl3 f. Au(NO3)3 Trigonal Pyramidal g. Pb(C2H3O2)4 8. Write chemical formulas for the following: a. Water b. Carbon monoxide c. Calcium carbonate d. Lithium nitride 11. Reaction Type ______Write general form a. Synthesis b. Decomposition c. Single replacement d. Double replacement e. Combustion Chemistry SOL Review Packet 12. Define oxidation-reduction reaction, oxidation, reduction, oxidizing agent, reducing agent. 13. Define exothermic and endothermic reactions. 14. State Le Chatelier’s Principle. Explain what stresses affect reactions. 15. Write balanced chemical equations for the following reactions and classify the reaction. a. Phosphorus reacts with oxygen to product c. Copper(II) hydroxide and potassium sulfate are produced when potassium hydroxide reacts with copper(II) sulfate. 16. In the following reactinos, tell which element is oxidized and which is reduced and identify the oxidizing and reducing agents: a. 2HgO 2Hg + O2 b. S + O2 SO2 c. Cu + 2AgNO3 Cu(NO3)2 + 2Ag d. Mg + Cl2 2MgCl2 diphosphorus pentoxide. b. Iron(II) oxide reacts with aluminum to produce aluminum oxide and iron. 17. Identify the following as an endothermic reaction or an exothermic reaction: a. C3H8 + 5O2 3CO2 + 4H2O + 2043kJ b. C + H2O + 113kJ CO + H2 Chemistry SOL Review Packet CH 4 The student will investigate and understand that chemical quantities are based on molar relationships. Key concepts include a) Avogadro’s principle and molar volume; b) stoichiometric relationships; c) solution concentrations; and d) acid/base theory; strong electrolytes, weak electrolytes, and nonelectrolytes; dissociation and ionization; pH and pOH; and the titration process. In order to meet this standard, it is expected that students will perform conversions between mass, volume, particles, and moles of a substance. perform stoichiometric calculations involving the following relationships: - mole-mole; - mass-mass; - mole-mass; - mass-volume; - mole-volume; - volume-volume; - mole-particle; - mass-particle; and - volume-particle. compare and contrast the differences between strong, weak, and non-electrolytes. relate the hydronium ion concentration to the pH scale. perform titrations in a laboratory setting using indicators. CH 5 The student will investigate and understand that the phases of matter are explained by kinetic theory and forces of attraction between particles. Key concepts include a) pressure, temperature, and volume; b) partial pressure and gas laws; c) vapor pressure; d) phase changes; e) molar heats of fusion and vaporization; f) specific heat capacity; and g) colligative properties. In order to meet this standard, it is expected that students will explain the behavior of gases and the relationship between pressure and volume (Boyle’s Law), and volume and temperature (Charles’ Law). identify the limiting reactant (reagent) in a reaction. solve problems and interpret graphs involving the gas laws. calculate percent yield of a reaction. identify how hydrogen bonding in water plays an important role in perform calculations involving the molarity of a solution, including dilutions. many physical, chemical, and biological phenomena. interpret vapor pressure graphs. interpret solubility curves. graph and interpret a heating curve (temperature vs. time). differentiate between the defining characteristics of the Arrhenius interpret a phase diagram of water. theory of acids and bases and the Bronsted-Lowry theory of acids and bases. identify common examples of acids and bases, including vinegar and ammonia. calculate energy changes, using molar heat of fusion and molar heat of vaporization. calculate energy changes, using specific heat capacity. examine the polarity of various solutes and solvents in solution formation. Chemistry SOL Review Packet CH 4 Problems 1. How many liters of carbon dioxide will be produced if 1.47 mol of oxygen is used in the following reaction? C3H8 + 5O2 3CO2 + 4H2O + 2043kJ 7. Aluminum reacts with sulfuric acid to produce aluminum sulfate and hydrogen. How many grams of aluminum sulfate will be produced from 0.58 mol of sulfuric acid? 8. List the postulates of the kinetic-molecular theory. 2. Methane (CH4) reacts with oxygen to produce carbon dioxide and water. If 5.28L of oxygen is used in the reaction at STP, what mass of water will be produced? 9. Write equations for Boyle’s Law, Charles’s Law, combined gas law, and Dalton’ Law. 3. Calcium carbonate and hydrochloric acid react to produce calcium chloride and carbonic acid. How much calcium chloride will be produced if 7.89g of hydrochloric acid are used? 4. How many moles of oxygen are produced from the decomposition of 19.55 moles of water? 5. How many atoms of iron are required to react with 8.2x1024 molecules of oxygen according to the following equation: 4Fe + 3O2 2Fe2O3 6. How many liters of N2 are needed to produce 6.84L of NH3 in the synthesis of ammonia? 10. The pressure and volume of a sample of gas at a constant temperature are _________ proportional to each other. (____________ Law) At constant pressure, the volume of a fixed amount of gas is _________ proportional to its temperature. (____________ Law) 11. If 75.3g of aluminum and 110.1g of oxygen react according to the following equation, which is the limiting reactant? 4Al + 3O2 2Al2O3 12. 125g of Al2O3 is recovered from the above reaction, What is the percent yield? 13. A gas occupies a volume of 60.0cm3 at 36°C. What will the same gas occupy at standard temperature if the pressure remains constant? Chemistry SOL Review Packet 14. A mixture of gas has a pressure of 725mmHg. The mixture contains hydrogen, nitrogen, and argon. The pressure of the hydrogen and argon are 378mmHg and 64mmHg, respectively. What is the pressure of the nitrogen in kPa? 19. What volume of 12M HCl is neeed to prepare 500mL of a 2M HCl solution? 20. List five properties of acids and five properties of bases. 15. If some oxygen gas at 101 kPa and 25°C is allowed to expand from 5.0dm3 to 10.0dm3 without changing the temperature, what pressure will the oxygen gas exert? 16. How many moles can be obtained in a 1.44L flask at 32°C and 93.5kPa? 21. Name the following and indicate whether it is an acid or base: a. KOH b. HCl c. H2SO4 d. NaOH e. HNO3 f. H2CO3 22. What is an acid/base titration? 2.50x102mL 17. What is the molarity of 9.46g cesium bromide? of solution containing 23. Explain the difference between a strong and a weak electrolyte. 18. What is the molarity of 5.23g of iron(II) nitrate dissolved in 100.0cm3 of solution? Chemistry SOL Review Packet CH 5 Problems Use the following heating curve for water to answer the questions. 6. An 18.7g sample of platinum metal increases in temperature by 2.3°C when 5.7J of heat are added. What is the specific heat of platinum? E 7. Define heat of fusion and heat of vaporization. D 8. Polar substance dissolve ___________ substances and nonpolar substances dissolve _____________ substances. C A B Heat Added 1. At which point on the heat curve is heat of fusion represented? Heat of vaporization? 2. At which point(s) on the curve is there no increase in average kinetic energy? 3. Label solid, liquid, gas, melting point, boiling point, freezing, condensation, melting, and vaporization. 4. Define sublimation and deposition. 9. Label the following on the above phase diagram for water: solid, liquid, gas, melting and boiling points at 1atm, critical point, and triple point. 5. A 21.0g sample of water is cooled from 34.0°C to 28.0°C. How many joules of heat were removed from the water? 10. Draw and label arrows that represent freezing, vaporization, and sublimation. Chemistry SOL Review Packet Heats of vaporization and heats of fusion of some substances Substance Heat of Heat of fusion vaporization Water 40.7 kJ/mol 6.00 kJ/mol Methane 9.2 kJ/mol 0.84 kJ/mol Mercury 59.4 kJ/mol 2.33 kJ/mol 11. How much energy is required to vaporize 22.5g of liquid mercury? d. NH3 e. Cl2 13. Distinguish between inter- and intra-molecular forces 12. Draw the following molecules and determine if they are polar or non-polar molecules. a. H2O 14. List the intramolecular forces in order of decreasing strength. b. CH4 15. List the intermolecular forces in order of decreasing strength. c. CO2 Chemistry SOL Review Packet CH.6 The student will investigate and understand how basic chemical properties relate to organic chemistry and biochemistry. Key concepts include a) unique properties of carbon that allow multi-carbon compounds; and b) uses in pharmaceuticals and genetics, petrochemicals, plastics, and food. In order to meet this standard, it is expected that students will 2. Which statement describes how plastics differ from nucleic acids? a. Plastics are synthetic polymers but nucleic acids are natural b. Plastics are formed from repeated subunits, but nucleic acids are not c. Plastics are formed from organic compounds, but nucleic acids are not d. Plastics are polymers, but nucleic acids are monomers 3. Draw Lewis structures for the following and determine molecular polarity: a. Methane describe how saturation affects shape and reactivity of carbon compounds. draw Lewis dot structures, identify geometries, and describe polarities of the following molecules: CH4, C2H6, C2H4, C2H2, CH3CH2OH, CH2O, C6H6, CH3COOH. b. Ethane recognize that organic compounds play a role in natural and synthetic pharmaceuticals. c. Ethene recognize that nucleic acids and proteins are important natural polymers. d. Ethyne recognize that plastics formed from petrochemicals are organic compounds that consist of long chains of carbons. e. Ethanol conduct a lab that exemplifies the versatility and importance of organic compounds (e.g., aspirin, an ester, a polymer). f. Formaldehyde g. Benzene CH 6 Problems 1. Which of the following polymers are naturally occurring? a. Nylon b. Protein c. Polyester d. Teflon e. DNA h. Acetic Acid