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SNC1DChemistryUnit Date:_______________________________________ ThePeriodicTable:MetalsandNon-MetalsComparison Asageneralrule,theperiodictableisarrangedwith______________towardtheleftside. ____________________aregenerallyfoundontherightsideofthetable.Theoneexceptionis ____________________whichisfoundinthetopleftcornerofthetable. Ontheperiodictablebelow,colourinthedifferentareasforeachofthefollowing: Metals,Nonmetals,Metalloids Metals Nonmetals Metalloids Ds Rg Ce Pr Nd Pm Sm Eu Tb Dy Ho Er Tm Yb Lu Th Pa U Np Am Cm Bk Cf Es Fm Md No Lr Pu Gd ComparisonofMetalsandNonmetals Property Metals Nonmetals Lustre Malleability Conductivity ReactivitywithAcid StateatRoomTemperature Note:therearesomeelementsthatdonotfitthecategoriesabove.Theyareconsidered ______________________.Theseareelementsthathavepropertiesthataresimilartoboth _________________and_______________________.Theyarelocatednearthe“staircase”. SNC1DChemistryUnit Date:________________________________________ InferringSymbolsofElements Unlikethenamingoftheelements,thesystemfordeterminingthesymbolsfollowsasetofrules.In1817,thesystemof chemicalsymbolsthatweusetodaywasfirstproposedbytheSwedishchemistJonsJakobBerzelius(1779-1848). Eventuallythissystemwasacceptedallaroundtheworld.Itwasacceptednotonlybecauseitprovidedsymbolsforall theknownelements,butalsobecauseitshowedhowtocreatesymbolsforanynewelementsthatmightbediscovered later.Inthisactivity,youwillfindoutwhattheserulesarebyexaminingthesymbolsforcertainelements. 1. Kal’sbodymassis50kg.Mostofit(48kg)ismadeupofjustfourelements:hydrogen(H),oxygen(O), carbon(C)andnitrogen(N).Thesymbolsfortheseelementsareinparentheses. (a) WhatruledoyouthinkBerzeliususedtocreatethesesymbols?Write“Rule1”downinthespacebelow. Rule#1:__________________________________________________________________________ (b) Kai’sbodycontainslessthan1goftheelementiodine.Userule1toinferthechemicalsymbolfor iodine.Useyourperiodictabletocheckyourinference. Symbolforiodine:____________ 2. About1kgofcalciumisdistributedthroughoutKal’sbones,teethandblood. (a) IfyouusedRule1toworkoutasymbolforcalcium,whatwouldthesymbolbe?______________ (b) Whatelementalreadyhasthissymbol?______________________ (c) Refertoyourperiodictable.Whatistheactualsymbolforcalcium?____________ (d) Infertherulethatwasusedtocreatethesymbolforcalcium.Writeitdownas“Rule2”. Rule#2:__________________________________________________________________________ 3. Severalelementnamesbeginwith“b”. (a) Theelementboroncanbeusedtomakesiliconcomputerchipsconductmoreelectricity.Boron’s symbolisB.IsthissymbolbasedonRule1orRule2?________________ (b) Inferlikelysymbolsfor(i)barium___________ (ii)beryllium___________ (iii)bismuth___________ (iv)bromine___________ Whichruledidyouuse?Explainwhy?__________________________________________________ _________________________________________________________________________________ (c) In1947chemistsinBerkeley,Californiamanufacturedanewelementandnameditberkelium.Referto yourperiodictable.Whatisthesymbolforberkelium?______________ (d) Infertherulethatwasusedtocreatethesymbolforberkelium.Writeitdownas“Rule3”. Rule#3:__________________________________________________________________________ 4. ThesevenmetalsknowntotheancientswerecalledbytheirLatinnamesforcenturies:argentumforsilver, aurumforgold,cuprumforcopper,ferrumforiron,hydragyrumformercury,plumbumforlead,and stannumfortin. (a) Infersymbolsforthesemetals.Useyourperiodictabletocheckforyourinferences. silver___________ gold___________ copper___________ mercury___________ lead___________ tin___________ iron___________ (b) Inferwhichmetalwasprobablyusedforwaterpipesinancienttimes.Explainhowitsnamehelpedyou makeyourinference. ____________________________________________________________________________________________________________ Date:________________________________________ TheoriesofAnAtom AnIndivisibleParticle–TheAtom Around400BCE,Democritusproposed(withoutexperimentalevidence)thatatomsare: • • • Earth,Water,AirandFire:Aristotle Aristotlerejectedtheideaofthe__________.Hesupportedanearliertheorythatallmatterismadeup offourbasicsubstances:_________________,_______________,________________and _________________. Aristotle’stheoryofthestructureofmatterwasacceptedforalmost___________________________. TheBilliardBallModel Proposedby_________________________________in__________.Heproposedthat: • • • • Dalton’smodelwasunabletoexplain:____________________________________________________ ____________________________________________________________________________________ Thomson’sExperiments–TheElectron In1897Thomsondiscoveredthat:________________________________________________________ ____________________________________________________________________________________ Theseparticleswereeventuallycalled_______________.Thomsontheorizedthat: • • • TheGoldFoilExperiment–TheNucleusandtheProton AsummaryofRutherford’s1909goldfoilexperiment:________________________________________ _____________________________________________________________________________________ _____________________________________________________________________________________ Rutherford’srevisedmodeloftheatom: • • • Rutherforddiscoveredthe_____________________in____________.Whatisaproton?___________ _____________________________________________________________________________________ Practice - Development of the Atomic Theory Readpp.228-233inyourtextbook.Matcheachnamewiththeappropriatedescriptionbelow.Eachname maybeusedmorethanonce. (A)Aristotle (B)JohnDalton (C)ErnestRutherford (D)Democritus (E)J.J.Thomson (F)DmitriMendeleev 1. Discoveryoftheelectron 2. Discoveryoftheproton 3. Theorythatanatomismostlyemptyspace 4. Gold-foilexperimentprovidingevidenceofthenucleusinanatom 5. Hypothesis(inthe1800s)thatallmatterismadeupofindivisibleatoms 6. Organizationofelementsintheperiodictableaccordingtotheirpropertiesand atomicnumbers 7. Predictionofthepropertiesofelementsunknownatthattime 8. Hypothesisthatallatomsofanelementareidentical 9. Ideathatanatomispositivelychargedsphere,withelectronsevenlydistributed throughoutit,liketheraisinsinaplumpudding 10. Hypothesisthatatomsofdifferentelementsaredifferent 11. Demonstratedthatthenucleusofanatomcontainsmostofitsmassandispositively charged 12. Theoryofan“indivisible”atom 13. Claimthatallmatterismadefromearth,water,airandfire SNC1D Date: IntheyearsafterJohnDalton’smodelwasaccepted,twodiscoveriesaboutatomswere: a.Therearesmallerpiecesthatmakeupatomscalled________________________________________. b.Thereare________________________________withinatoms Themodelhadtoberevised.EventuallyNielsBohrandErnestRutherfordproposedtheirownmodel. BOHR-RUTHERFORDMODELOFTHEATOM ü Anatomisthoughttoconsistofthreetypesofsubatomicparticles: ________________________,_________________________and___________________________. ü Mostofthemassofanatomisconcentratedinaverydensecorecalledthe__________________, whichcontains_______________________and__________________________. SUMMARYOFSUBATOMICPARTICLES: subatomicparticlesð PROTON NEUTRON ELECTRON RELATIVEMASS almostzero RELATIVECHARGE ü _________________________arethoughttomoverapidlyaroundthenucleusinorbits(likeplanets aroundtheSun) ü____________________and________________________haveequal(insize)butopposite(insign) charges. CHARGEDATOMS Ifanatomiselectricallyneutralithasequalnumbersof__________________and_________________ Sometimesatomsgainorlose_______________. WhenthenumberofprotonsandthenumberofelectronsareNOTequaltheatomischargedandis calledan________. Forexample: numberofprotons numberofelectrons netcharge 3 3 25 23 33 36 ATOMICSYMBOLS mass number ⎯⎯→ A q (charge) X atomic number ⎯⎯→ Z For example : 25 2+ 12 Mg F Theatomicnumber,(Z),tellsthenumberof___________________inanatomandalwaysidentifies theelement.(Intheexampleabove,theatomicnumber=________=numberof_______________) F Themassnumber,(A),revealsthetotalnumberof__________________+__________________. (Intheexampleabove,thenumberofneutrons=___________ ) Intheexampleabove,thecharge,+2,meanstheatomofMghastwomore_________________thanit has_________________. Example#2: massnumber=____________,atomicnumber=___________,netcharge=___________ numberofprotons=_______,numberofneutrons=_______,numberofelectrons=_______ ISOTOPES F Sometimesatomsofthesameelementhavedifferent_________________.Thesearecalledisotopes. Forexample: FthesetwoatomsofMghavethesamenumberof___________________butdifferentnumberof ________________. PRACTICE: nameof element symbol atomic number mass number numberof protons numberof neutrons numberof electrons netcharge oxygen 15 0 21 18 +2 35 80 36 Practice: Atomic Structure SNC1D Name of element a beryllium b oxygen nuclear symbol A z X Atomic Mass Number Number Number Number Number of of of protons 10 4 Be 17 −2 Si d 16 33 18 e 30 f 66 manganese 29 nickel +4 45 −1 36 0 30 +3 Hg 0 l 200 m 15 potassium 17 46 116 50 p 79 0 26 0 14 silver 104 +2 ? q ? +1 18 40 o 0 +2 198 k r 30 35 i n 26 53 h j Charge 30 14 c g neutrons electrons Net 12 0 +1 Note:thetopnumberistheatomic numberforeachelement. SNC1D Date: Bohr-Rutherford Diagrams H Helium has two electrons paired up. ThePeriodicTable(firsteighteenelements) Instructions:DrawBohr-RutherfordDiagramsbyusingtheperiodictableto determinethenumberofprotonsinthenucleusofeachatom (writenumberofprotonsinthenucleusanddrawelectronshellsaroundit) 1p+ He 2p+ Li Be B C N O F Ne Na Mg Al Si P S Cl Ar Group 1 Group 2 Alkali metals Alkaline earth metals Group 13 Group 14 Group 15 Group 16 Group 17 Group 18 Halogens Noble gases Bohr-Rutherford Diagram Questions: 1. a.Inwhichgrouparesodium,lithiumandpotassiumlocated?Givethegroup#andchemicalfamilyname. b.Howmanyelectronsareintheouter(valence)shellofsodium,lithiumandpotassium? 2. a.Inwhichgrouparefluorineandchlorinelocated?Givethegroup#andchemicalfamilyname. b.Howmanyelectronsareintheouter(valence)shelloffluorineandchlorine? 3.a.Whichelementshavecompleteouter(valence)shells?Givethenameandsymbolforeach: b.Whatchemicalfamilydotheseelementsbelongto? 4.Examinetheothergroups,whatgeneralstatementcanbemadewithregardstothegroupnumberandthe numberofelectronsintheouter(valence)shell? 5.a.Inwhichperiodarehydrogenandheliumlocated? b.Howmanyshellsofelectronsareintheatomsofhydrogenandhelium? 6.a.Inwhichperiodarelithium,beryllium,boron,carbon,nitrogen,oxygen,fluorineandneonlocated? b.HowmanyshellsofelectronsdotheaboveatomshaveintheirBohr-Rutherforddiagram? 7.Ingeneral,whatistherelationshipbetweentheperiodnumberandthenumberofshellsofelectrons? 8.Predictthenumberofvalenceelectronsforeachelementbasedontheinformationgivenbelow: a.potassiumisfoundingroup1 #ofvalenceelectrons:______ b.bromineisahalogen #ofvalenceelectrons:______ c.bariumisanalkalineearthmetal #ofvalenceelectrons:______ Date:________________________________________ ProducingandTestingGases Purpose:Touseasetofstandardteststhatwillpositivelyidentifydifferentgases Materials:testtubes,woodensplints,candle,limewater,avarietyofchemicals TESTFOROXYGEN ResultofSplintTest: ChemicalReaction:thebreakdownofhydrogenperoxide Observations: Apparatustotestforoxygen(drawing&description): TESTFORHYDROGEN ResultofSplintTest: ChemicalReaction:reactionofzinc+sulfuricacid Observation: Apparatustotestforhydrogen(drawing&description): TESTFORCARBONDIOXIDE Resultoflimewatertest: ChemicalReaction:carbondioxide+limewater(asolutionofcalciumhydroxide) Apparatustotestforcarbondioxide(drawing&description): Questions: 1.Whatphysicalpropertiesdothethreegases(O2,H2,CO2)share? 2.Howcanyoutellbychemicalpropertiesthatthethreegases(O2,H2,CO2)arenotthesame? Application: 3. Oneofthegasescanbeusedinfireextinguishers.Whichoneandwhy? 4. Anothergaswasusedformanyyearstoaidinthefloatingoftransportationballoons.Whichone?Whyisthisgasnot usedtoday? 5. Anothergasisusedtoassistthebreathingofmanypatientsinhospitals.Whichone? SNC1DChemistryUnit Date:___________________________________ C he m icalForm ula Recall:eachelementhasitsownchemicalsymbol. Eachcompoundhasitsownchemicalformula.Aformulatellsustwoveryimportantthingsabouta compound: 1.the________________thecompoundismadeof 2.thenumberof_____________ofeachelementofthecompound Example#1:TheformulafortablesaltisNaCl. • Naisthesymbolfor_________________. • Clisthesymbolfor________________. OneunitofNaClhasatotalof_____atoms.Oneoftheatomsissodium(Na).Theotheratomischlorine (Cl). Sometimesasymbolhasasmallnumberwrittennexttoit.Thisnumber,calledthe_______________, tellsusthenumberofatomsthereareofthatelement. Example#2:TheformulaforwaterisH2O. • H2meanstwoatomsof_________________. • Oisthesymbolfor________________. OnemoleculeofH2O,then,hasatotalof_____atoms.Twooftheatomsarehydrogen.Oneatomis oxygen. Note:Theformulaforacompoundisalwaysthesame.Achangeintheformulameansthatanew substancewasformed. Practice: Formula KCl Picture Fe2O3 H2SO4 Name Numberof Elements Namesofthe elements Numberof Atomsof EachElement TotalNumber ofAtoms potassium chloride ironoxide (rust) sulfuricacid sodium hydrogen carbonateor sodium bicarbonate (bakingsoda) NaHCO3 Exercise: Completethechartbyfillinginthemissinginformation.Thefirstonehasbeendoneforyou. Formula Name Numberof Elements Namesofthe elements NumberofAtoms ofEachElement TotalNumberof Atoms 1.MgO magnesiumoxide 2 magnesium oxygen 1 1 2 2.CO carbonmonoxide 3.CO2 carbondioxide 4.NH3 ammonia 5.H2CO3 hydrogen carbonate (carbonicacid) 6.C6H12O6 glucose 7.MgSO4 magnesiumsulfate (Epsomsalt) 8.NaOH sodiumhydroxide 9.H2O2 hydrogenperoxide 10.C12H22O11 sucrose (tablesugar) SNC1DChemistryUnit Date:_______________________________ Investigation:ChemicalFormulae Inthisactivityyouwillfindoutmoreaboutdifferentchemicalformulaeandwhattheycantellus aboutdifferentsubstances. Part1:FormulasforMolecularCompounds ThinkAboutIt Manycompoundsaremadeofmolecules.Examplesincludewater,carbondioxide,propane,and glucose(sugar).Interprettheformulasforthesecompoundsbyusingthefirstlineofthistableasa guide. Nameof Formulaof ElementsPresent HowManyAtomsofEach? Compound Molecule 2atomsofH water H2O hydrogen,oxygen 1atomofO carbondioxide CO2 propane C 3 H8 glucose C6H1206 WhattoDo Basedinthetableabove,howmanyatoms,intotalarepresentinthefollowingmolecules? a)onewatermolecule b)onecarbondioxidemolecule c)onepropanemolecule d)oneglucosemolecule Part2:FormulasforNonmolecularCompounds(example:saltcrystals) ThinkAboutIt Notallcompoundsaremadeofmolecules.Forexample,sodiumchloride(tablesalt)doesnotcontain independentsaltmolecules.Thefollowingrepresentativemodel(seenextpage)showsapartofasalt crystal.Itshowsthepositionoftheatomsinthesaltcrystal,butitdoesnotshowwhatthecrystal actuallylookslike.Examinethemodelcarefullytoseehowthetwoelementsarearranged. Pleaseturnover. ThesymbolforsodiumisNa.Thesodiumatomsare blackinthismodel. ThesymbolforchlorineisCl.Thechlorineatomsare white. WhattoDo 1)Countthetotalnumberofatomsofeachelement thatarerepresentedinthemodel. a)Intotal,howmanysodiumatomsarerepresented?______ b)Intotal,howmanychlorineatomsarerepresented?______ 2)Completethefollowingstatements. a)Themodelhas1Naatomforevery_____Cl.(Choose1,2,3,or6.) b)Themodelhas1Clatomforevery_____Na.(Choose1,2,3,or6.) c)TheratioofNatoClinthemodelis_______.(Choose1:1,1:2,1:3,1:6) 3)Thecompoundrepresentedinthemodelissodiumchloride. a)WriteaformulathatshowseveryNaandClinthemodel. b)TheformulaforsodiumchlorideisnormallywrittenasNaCl.Isthisanaccuratedescriptionofthe compound?Explain. Part3:FormulasforMolecularElements(example:hydrogen) Thinkaboutit Someelementsexistasmolecules(twoatomsbondedtogether)underordinaryconditions.For example,theairyouinhalewitheverybreathismostlyamixtureoftwocompoundsandtwoelements. Thesearelistedinthetablebelow.Fillinthemissingboxesinthetable.Thefirstoneisdoneforyou. NameofGas Compoundor Madeof Formula? NumberofAtoms Element? Molecules? perMolecule watervapour compound yes H2O 3 carbondioxide oxygen yes yes CO2 O2 nitrogen element yes 2 Oxygenandnitrogenexistasdiatomicmoleculesintheair.Diatomicmoleculesaremoleculesmade upoftwoatomsofthesameelement.Otherexamplesinclude:hydrogen,fluorine,chlorine,bromine andiodine. SNC1D Date: Chemistry Test Review ____________________________ TestDate: Bringtothetest:apencil,eraser,penandawell-restedbrain.NOTE:Onlythesymbolsandatomicnumberswill beprovidedontheperiodictablegiventoyouonthetest. AstudentinMr.Masri’sGrade9Scienceclassshouldbefamiliarwith: 1. Distinguishbetweenandidentify:homogenousvsheterogenousmatter;physicalvschemicalchange;physical vschemicalproperties.(pg.179–185) 2. Describethedifferencebetween:amixtureandapuresubstance;amechanicalmixtureandasolution.(pg.176) 3. Identifythepartsofasolution:soluteandsolvent. 4. DistinguishbetweenthePureSubstances:elementsandcompounds(pp.175) 5. ThePeriodicTable(pg.211-214) a)knowwhatgroupshaveelementsthatarethemostreactiveandunreactive b)differentiatebetweenperiodsandgroups c)thechemicalsymbolsandnamesfortheselectedelements(seehandout) d)differentiatebetweenmetals,metalloidsandnon-metals(i.e.theircharacteristics) 6.Identifythemajorcontributionstotheunderstandingoftheatombythefollowingscientists/philosophers: Democritus,Aristotle,Dalton,ThomsonandRutherford(Note:youarenotresponsiblefordatesofexperiments) 7.AtomicStructure(pg.234-235) a)knowhowprotons,neutronsandelectronscompareastocharge,massandlocationintheatom b)knowwhatatomicnumbertellsyou c)knowwhatmassnumbertellsyou 25 d)obtaininformationaboutatomsfromsymbolslike: 12 Mg aboutthenumberofprotons,neutronsandelectrons e)beabletodescribethemeaningofaneutralatom,anionandanisotopeofanatom 8.Determineinformationfromchemicalformulaeofcompounds(i.e.numberofatomsofeachelement) 9.Bohr-Rutherforddiagrams(pg.236)–knowhowtodrawdiagramsforthefirsteighteen(18)elements 10.DescribetheStandardGasTestsforHydrogen,OxygenandCarbonDioxide Studytips:Readthroughyourclassnotesandtextreferences.Trymakingpointformnotestosummarize thetopics. Suggestedreviewquestionsintextbook(multiplechoice,T/F,shortanswer): p.205#1–5,11,14 p.248Q#1,2,4,5 p.250Q#1,4,7–10,14 p.282Q#1,3 p.288Q#3,6–10,14,19,20,21 Completeextrareviewquestionsonthebackofthesheet. Extrareviewquestions: 1.Groupsontheperiodictable: a. wherearethenoblegasesfoundontheperiodictable: Group#: b. giveanexampleofanoblegas __________________________ c. wherearethealkalimetalsfoundontheperiodictable: Group#: d. giveanexampleofanalkalimetal __________________________ e. wherearethehalogensfoundontheperiodictable: Group#: f. giveanexampleofanhalogen g. describethereactivityofthefollowinggroupsofelements: i) noblegases (reactiveorunreactive)? ii) alkalimetals(reactiveorunreactive)? iii) halogens (reactiveorunreactive)? 2.Sucroseisacompound.ThechemicalformulaforsucroseisC12H22O11. Nameofelementspresent Numberofatomsofeachelement 3.Theatomismadeupofthreesmallparticles,completethechartbelow: Partsoftheatom RelativeLocation Electriccharge 4.Fillintheinformationaboutatomsinthetablebelow: ELEMENT NAME SYMBOL ATOMIC NUMBER MASS NUMBER numberof PROTONS numberof NEUTRONS numberof ELECTRONS Netcharge fluorine 9 10 0 phosphorus 31 18 23 11 Na + 5.Manyscientistshavefurtheredourknowledgeofthestructureoftheatom.Summarizethecontributionsof thefollowingscientistsorphilosophersonaseparatesheetofpaper: a)Democritus b)Aristotle c)Dalton d)J.J.Thomson e)Rutherford 6.DrawtheBohr-Rutherforddiagramofargon.