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Weathering • Weathering: physical and chemical breakdown of earth material (rocks and minerals) at or near the surface. • Includes disaggregation of parent materials, erosion and transportation of resulting clasts and sediments, and leads to deposition and lithification of these materials • Differential weathering: uneven weathering of heterogenous materials that leads to unique geologic structures such as hoodoos and arches Mechanical Weathering • Physical processes cause weathering several ways: • Frost action: freezing and thawing in cracks and pores in rocks; high altitudes and latitudes • Pressure release: expansion of uplifted and exposed intrusive rocks; exfoliation domes such as Stone Mountain, GA, rock bursts in mines • Thermal expansion/contraction: differential reaction by rocks and minerals to daily or seasonal temperature changes • Salt crystal growth: occurs primarily in hot, arid regions • Biological actions: burrowing, root wedging Chemical Weathering • Processes that chemically alter parent material: • Solution/dissolution: occurs when ions separate in water due to the solvent properties of H20, example: dissolution of calcite in limestones by groundwater • Oxidation: occurs when oxides are formed by mineral ions combining with oxygen, example: Fe + O = hematite (rust) • Hydrolysis: free ions of H+ and OH- in water can replace ions in minerals, which are liberated to undergo oxidation, example: orthoclase weathers to kaolinite by loss of Al ions Chemical Weathering • Chemical weathering operates on the surface of rocks and minerals, and can be observed in the difference between old and fresh surfaces of broken rock, controlled by: • Fractures: produce increased surface area in equal volume of rock • Climate: presence of water greatly accelerates weathering. Humid, warm climates have high weathering rates • Composition: stable minerals are resistant to weathering, example: Quartz; less stable minerals rapidly weather (Bowen’s reaction series) • One unique form of weathering is spheroidal weathering: rocks often weather into spherioids due to uneven weathering. 3X at points compared to flats Soil • Regolith: sediments that cover the Earth’s land surface • Soil: regolith composed of weathered minerals, air, water, and organic material; supports vegetation • all land-dwelling organisms dependent on soil • good farming soil composed of sediments (sand, silt, and clay), air, water, and humus. • Humus: carbon derived by bacterial decay of organic material Soil profile • Soil forms in characteristic layers: • Horizon O: thin subaerial layer, predominately organic material, including humus • Horizon A: weathered unstable minerals that provide nutrients, remnants of stable minerals such as quartz grains, a zone of biological activity. • Horizon B: where minerals leached from above accumulate (zone of accumulation) • Horizon C: unaltered to altered parent material Sedimentary Rocks • Composed of sediments from weathering, chemical precipitation, and clastic material including fossil fragments • Sediments are produced by erosion or chemical means, then transported by physical processed such as wind, water, and gravity, and deposited as loose aggregates of particles. • Sedimentary particles are classified according to size: > 2 mm = gravel, 1/16-2 mm = sand, 1/256-1/16 mm = silt, < 1/256 = clay Sedimentary Rocks • Depositional environment: describes the basin in which sediments are deposited, including: stream beds, lake bottoms, river deltas, coastal beaches, continental shelves, and sand dunes • Variations in transport duration and conditions produce characteristic sedimentary particles; abrasion reduces particle size, rounding wears away sharp angles, and sorting occurs during deposition • After deposition, sediments can be lithified by compaction and cementation to produce sedimentary rocks Depositional Environments Rounding of Sediments Sedimentary Rocks • The most common cements in sedimentary rocks are the minerals calcite and silica, which are derived from weathering of rocks and transported by water • There are two major types of sedimentary rocks: • 1) DETRITAL SEDIMENTARY ROCKS-composed of solid particles (detritus) derived from weathered parent rocks, classified according to size and include: • conglomerate: composed of gravel-sized particles, breccia refers to a conglomerate with angular clasts • sandstone: composed of sand-sized clasts of any composition, most common clast is quartz • mudrock: general term for sedimentary rocks with silt to clay sized clasts, varieties include: siltstones, mudstones, claystones, fissile = shale Sedimentary Rocks • 2) CHEMICAL SEDIMENTARY ROCKS: have a chemical origin and include: • limestone: the most common carbonate rock, composed of carbonate mud usually precipitated from shallow, warm marine waters, and often containing fossil fragments • coquina: type of limestone composed of fragmented seashells • oolitic limestone: contains small, spherical grains (ooids), concentric rings of calcite precipitated around a nucleus Chemical sedimentary rocks • Other chemical sedimentary rocks are: • evaporites: composed of dissolved substances precipitated from evaporated water, examples: halite (NaCl) and gypsum (CaSO4.2H2O) • chert: microcrystalline quartz deposited as beds of microfossils (radiolarians and diatoms), often re-crystallized, includes flint and jasper Sedimentary Rocks • Coal: derived from compressed, altered land plant remains: • peat: barely altered plant material • lignite: more fully altered, low grade coal (~70% carbon) • bitumin: or bituminous coal, higher grade (~80%), with little remaining evidence of plant material • anthracite: high grade, high carbon coal (up to 98% carbon) Sedimentary structures • These are textural features formed by variation in deposition, and include: • bedding/strata: horizontal layers • graded bedding: vertical grain size change • cross bedding: bedding at angles to depositional surface • ripple marks: small dunes preserved on sand deposits, formed by moving fluids (air, water) • mud cracks: indicative of subaerial drying Fossils • remains of ancient life, found in sedimentary rocks • trace fossils: tracks, prints • body fossils: altered or unaltered remains of body parts such as bones, teeth or shells • microfossils: microscopic body fossils • biostratigraphy: correlation of sedimentary rocks using fossils Resources in Sedimentary Rocks • • • • • • clay, sand, and gravel evaporite minerals: salt, gypsum, fertilizers placer deposits: gold, silver, uranium coal petroleum/natural gas iron (b.i.f.s)