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Recommended Procedures for Site Investigations of Waste Disposal Sites and Contaminated Sites in Thailand Funded by the Ministry of Education and Research (BMBF) of the Federal Republic of Germany (FKZ 0261218) Bangkok, Berlin, Hannover, Cottbus 2006 For the scientific content the authors are solely responsible. Authors: Prof. Dr. Hans-Juergen Voigt, Dr. Ursula Noell, Dr. Klaus Knoedel, Dipl.-Ing. Florian Jenn, Dipl.-Geol. Jens Radschinski, Dr. Christoph Grissemann, Dipl.-Geophys. Gerhard Lange With contributions of: Dr. Joachim Baumann, Dr. Manfred Birke, Peter W. Boochs, Dr. Gunter Doerhoefer, Dr. Dr. Matthias Dorn, Prof. Dr. Ulrich Foerstner, Dr. Joachim Gerth, Dr. Hagen Hilse, Dr. Kurt-Heiner Krieger, Dr. Thomas Lege, Dr. Jürgen Lietz, Prof. Dr. Rolf Mull, Dr.-Ing. Claus Nitsche, Dr. Matthias Schreiner, Dr. Andreas Schuck, Dipl.-Geophys. Knut Seidel, M. Sc. Worawoot Tantiwanit, Dr. Hildegard Wilken, Dr. Thomas Wonik Contact Address: Dr. Ursula Noell, Federal Institute for Geosciences and Natural Resources, Hannover, Germany, [email protected] 2 The “Recommendations for Site Investigations of Waste Disposal Sites and Contaminated Sites in Thailand” are a product of the Thai-German Research Project WADIS (Waste Disposal: Investigation of abandoned landfills and proposed areas for new waste disposal sites in Thailand). This project has been approved by the Thai Cabinet on 30th May 2000 and has been funded by the German Federal Ministry for Education and Research (BMBF). The research work has been carried out in Thailand in cooperation with the Department of Mineral Resources (DMR). The WADIS Project emphasizes the application of the “Multi-Barrier Concept” as a powerful approach to enhance the safety of waste disposal sites. This concept follows an integrated approach and requires not only the installation of a man-made barrier (technical barrier) to reduce the danger of pollution but also the integration of the natural subsoil of a waste site (geological barrier) as a safety component. This concise summary gives a brief overview on the recommended procedures for locating new waste disposal sites and the investigation of sites suspected to be hazardous. The main focus is the assessment of the lateral extent and sealing qualities of the geological barrier. For this assessment geophysical, geohydrological, geo- and hydrochemical studies are to be performed which are described briefly in this concise summary. The authors thank all colleagues in DMR, PCD, BGR, universities and companies in Thailand and Germany for their contributions and discussions. The full text of these recommendations is available from the Federal Institute for Geosciences and Natural Resources (BGR) in Germany. Table of Contents Waste Problem and Multi Barrier Safety Site Searching Process Part 1: Selection of New Waste Disposal Sites 1.1. Overview Investigation 1.2. Geological Assessment 1.3. Hydrogeological Investigation 1.4. Geophysical Investigation 1.5. Geochemical and Hydrochemical Investigation 1.6. Natural Attenuation Capability 1.7. Geotechnical Stability Part 2: Investigation of Sites Suspected to be Hazardous 3.1. Overview Investigation 3.2. Detailed Investigation 3.3. Geophysical Investigation 3.4. Hydrogeological Investigation References/Further Reading 4 6 8 8 10 12 14 16 18 19 20 20 22 23 24 26 3 Waste Problem and Multi Barrier Safety Initiatives to separate waste and to organize recycling have been set up but recycling is not for free, it can also cause contamination. Increasing population density and industrialization is creating a high strain on the natural environment and resources. Therefore, precautionary measures to protect the environment and remedial actions to repair the damages of the past have high priority. Resources to be protected are surface water, groundwater, soil and air. Hazards to these resources are landfills and industrial sites as well as mining facilities, including tailings, conditioning plants, and smelters, oil refineries, distribution facilities and pipelines, gas stations and other areas used by humans (e.g. military training sites). Waste Reduction Waste Avoidance Environmental protection has a high priority on the national agenda of the Kingdom of Thailand. The best way to avoid environmental damage due to landfill facilities is to avoid the waste generation. We have to train ourselves to become more aware about the waste generation by asking whether o a product will last, o it can be maintained, repaired or restored as it gets older, o there is a simpler, less wasteful alternative. 4 Incineration and other waste treatment reduce the waste volume; however, waste will still be generated. Landfill construction will be required to deal with the incineration ashes often containing high amounts of harmful substances. Efforts are made on all levels striving towards a Zero Emission Strategy (ZERI). Until this aim is fully achieved safe landfill construction will be necessary. The Multi Barrier Concept High-level standards are necessary for the disposal of waste in order to avoid environmental damages. State of the art is the Multi Barrier Concept (MBC) for landfills which was introduced in Germany in 1993 under the regulation “Technical Instructions on Wastes from Human Settlements” (TASi). The MBC comprises the phases of planning, construction, operation and follow-up care of a waste site and is based on the combined effects of several, from each other largely independent barriers systems. The three barriers are the landfill body, the landfill sealing and drainage system and the landfill site (geological barrier) as shown in Figure 1. Most importantly a landfill has to be constructed in such a way that the drainage water is collectable by free outflow from the waste site. It is therefore of utmost importance to construct a landfill as heap and not to fill existing pits. The Waste as Barrier The waste to be emplaced must comply with a number of characteristics in order to take on the function of a barrier. These include having the minimum possible eluation behaviour, in other words must strongly inhibit infiltration and leachate formation, having minimum possible toxicity as well as long-term chemical stability. Assessment values include not only threshold values for toxic constituents but in particular the specification of a low content of organic components expressed as the "ignition loss". For the most part inert wastes can only be guaranteed by way of suitable conditioning methods (e.g. incineration, pre-composting). In many cases the waste generated will not comply with these characteristics. They are, however, important to strive for. If they are fulfilled the waste itself acts as a barrier and the risk of environmental pollution by the landfill is greatly reduced. It is of utmost importance to avoid deposition of toxic material as well as fuel, batteries, and other long lived industrial objects in combination Figure 1: The Multi Barrier Concept with household waste as they will cause a lasting threat to the groundwater. Whenever possible waste should be separated and for the different types of waste (biodegradable, metallic, recyclable plastics, etc) an adequate treatment is to be organized. Technical Barrier In terms of technical barriers, based on today’s standard, combination systems made up of mineral seals together with plastic membranes promise the best infiltration inhibition as the base seal. Other elements of technical barriers comprise drainage systems offering long-term functionality (drainage beds) and also systems for gas collection (gas drainage). The base seal must be emplaced right at the start of the landfill construction. Even if the thorough study of the geological barrier has proven its very low hydraulic conductivity a technical base seal should always be emplaced. The technical barrier retains the leachate for the first years until it is chemically stabilized. The seal also enables a well defined access to the leachate for monitoring purposes. Only at the end of the deposition process the decision on surface seals must be taken. Dry cracking often results in adverse effects and is to be avoided. Particularly clay seals bear the risk of cracking once they dry out. New surface seals (e.g. bitumen, capillary barriers) get currently developed with improved characteristics. Geological Barrier The geological barrier holds a special position within the MBC. It in all cases comprises naturally arranged, slightly permeable, unconsolidated or consolidated rock of several meters thickness and exhibiting a high pollution retention capacity extending beyond the area of the dumping site. The existence of such a barrier is to be proven at sites suspected to be hazardous. The following chapters describe the procedures regarded necessary for investigation of the geological barrier. The combination of the three barriers will result in a landfill having the least detrimental effects for the resources water, soil and air. If the geological barrier is insufficient technical barriers must be constructed to fulfill its function which will increase the landfill’s construction costs. 5 Site Searching Process General Aspects It is important to understand the complexity of the process required to obtain reliable and reproducible results for site investigation and assessment. The steps of a scientific landfill site search and investigations of sites suspected to be hazardous are not a matter of personal judgment or individual or social preference, but are based on scientific principles. They can be repeated since they are generated according to well documented procedures, and new data can be integrated for broadening the insight. This is of prime importance for the search of a geological barrier, i.e. the evaluation of potential barrier properties of rocks. The scientific character of the procedure ensures that everyone involved can agree on the results. And if the objective is not consensus based on scientific results, nothing else has a chance of leading to a consensus. Acceptance of the results of a scientifically based landfill site search process by the public will be high and potential conflicts can be reduced. However, it is of utmost importance to involve all stakeholders in the site searching process. 6 Public Participation It is important that all the steps of the site searching process are open to the public. Transparency, mediation between disagreeing parties, and the right to participate as an equal partner in the discussion strengthen the site search process. Its design as a public process avoids the impression that a site will or can be selected without taking the public’s opinion into consideration. The primary aim of a site searching process is to minimize the environmental impact of a waste disposal site. A site is to be selected where the least detrimental effect can be ensured with minimum costs; geological barriers are for free, technical barriers must be paid for. And the population suffers from the burden of an improper site selection. The site searching process must take the regional aspects and problems, i.e. regional planning decisions, special geological features, and economic conditions (affecting, for example, the amount of waste produced) into consideration. Pragmatic Approach in Planning of New Landfills There are regions for which at present no geological and hydrogeological data bases, no “Potential Barrier Rock Maps (PBR maps)” and/or “Groundwater Vulnerability Map”, and in some cases no geological map 1 : 50 000 are available. In such cases a pragmatic approach in planning a new landfill can be used. Possible waste disposal sites are selected by political decision and/or applying non-geoscientific criteria (e.g. availability of public land, transport routes). In such cases the geoscientific site investigation and assessment must be carried out in order to make sure that inadequate sites are excluded and the most appropriate site in terms of the geological barrier is chosen. On account of the various complicated geoscientific issues to be considered when looking for a new landfill site or to investigate a site suspected to be hazardous professional contractors should be appointed for these tasks. These contractors should be selected by a transparent tender process as to reduce the risk of detrimental influence on siting decisions to a minimum. The necessary steps for the geoscientific investigation, although easily described in theory, become often very complicated due to various social and political aspects which have to be taken into account. The following describes in a flowchart a procedure to be followed: The local authority responsible (LAR) should appoint a general contractor for the site searching process or parts of this process. This general contractor should steer through the whole process, ensure the contracting of specialists for certain detailed investigations and should organise public participation as agreed with the local authority responsible. LAR: Definition of initial conditions kind of landfill (kind of waste), planning area (e.g. district), quantity of waste (for 25 years); size of landfill site. LAR in cooperation with ARP: Selection of sites for a suitability assessment. LAR and IR: First consultation with the IR • advice on the basic principles, • provision of available data. LAR: Commissioning of overview investigation Contractor: Conducts orientating site investigation and assessment (phase 1) • compilation of available data for the proposed sites, • exclusion of unfavorable sites, • orientating geoscientific investigations, • comparative site assessment If no selected site is suitable as a waste disposal site, LAR should select new sites with the support of IR LAR and IR: Second consultation with the IR • assessment of results LAR: Commissioning of the detailed site investigation Contractor: Detailed site investigation IR: Assessment of results, possibly approval of landfill planning. The institution responsible (IR) should be consulted at well defined steps of the process to give advice concerning the general principles of the site searching, to provide geoscientific data if available and to ensure that the whole process is performed according to rules and regulations set in the Kingdom of Thailand. It is of utmost importance that the procedures are coherent countrywide, by no ways is it acceptable that safety requirements are adhered to only by certain communities and not by others. The authority for regional planning (ARP) should be consulted at the very beginning. The Kingdom of Thailand is rapidly developing and plans for future settlements, industries and national parks or recreation facilities must be taken into account in the very early phases of the site searching. Planned roads, railways and other means of public transport, possibly having detrimental effects of the sites safety and long term stability, need to be considered. Landfills are long lasting facilities, the future use of the area, once the deposition is terminated, should be planned thoroughly already at the early phases of landfill planning. Abandoned landfills, without proper monitoring and organized future use, present an unacceptable hazard for future generations. Specification of further investigations if necessary 7 Part 1: Selection of a New Waste Disposal Site 1.1 Overview Investigation The first step to select a suitable site for landfill construction is the overview investigation. In this overview investigation firstly the excluding criteria for landfill construction are evaluated. In the Kingdom of Thailand excluding criteria are recommended by the Pollution Control Department (PCD) and published in the PCD booklet (1998/2000): “Regulation and Guideline of Municipal Solid Waste Management”. According to these recommendations no landfill is to be constructed 1) Within the watershed areas class 1 and class 2. 2) Within 1-kilometer distance from the property boundary of any ancient monuments. 3) Within the 5-Kilometer distance from any licensed and operating airport runways. 4) Within 700 meters of a potable water well or community water treatment plant. 5) Within 300 meters of any natural or manmade body of water, including wetlands. 8 6) In an area where the formation will not provide support for the solid waste. 7) In an area subject to frequent and periodic flooding unless flood protection measures are in place. 8) Unless in an area where the normal water table is sufficient low. In high water level area, unless special design is provided. Further Excluding Criteria In addition to these criteria others have to be taken into account, based on experience and aimed at finding a location with least detrimental effects the environment and at minimizing combating interests. It is strongly recommended never to construct a landfill within a particular hazard prone area. Hazards to be looked upon are floods, earthquakes, landslides, subsidence and tsunamis. In areas of seismic activity the greatest possible distance to faults and lineaments, active during holocene times, are to be kept. within an area of high soil quality in order to minimize combating interests. above an aquifer bearing potable water unless it is protected by an aquiclude of some meters thickness. within nature reserves, wildlife sanctuaries, areas of ecological importance and recreation areas. directly adjacent to quarries and mining areas in order to avoid combating interests. directly adjacent to main rivers and river tributaries. Within an area of particular high wind speed. Mapping A map should be produced to visualize all areas excluded by the criteria mentioned above. To construct this map the following characteristics of the investigation area are to be gathered: topography, land use and vegetation, settlements, industrial areas, roads and railways, other man made structures (landing strips, military areas, pipelines, power lines, …), precipitation, temperature, evapotranspiration, direction, velocity and intensity of wind, natural or man made bodies of water, wetlands, and flood plains, drainage (streams. rivers, any natural or man made drainage channel), flood-, land slide-, tsunami-, and earthquake prone areas, soil, stratigraphy and lithology, fault zones and lineaments, ecological aspects: e.g., nature reserves, protected geotopes, water protection areas. Information for this investigation phase can be drawn from archived material and available maps on the different topics. Remote sensing methods are of particular help for detecting fault zones and lineaments and the mapping of areas prone to flooding. Areas of former landslides can also be detected by remote sensing methods. Maps and data to be gathered and used comprise but are not limited to: The best way to compile a map on these characteristics is by using a Geographical Information System (GIS). If this is not available maps at a scale of 1:25000 are to be drawn, where all these characteristics are properly displayed. topographic maps, aerial photography, satellite images, geological maps, hydrological maps, maps on hazards and/or geological risks, reports and expertise as well as special literature. A reconnaissance survey in the field must be done in order to check the accuracy of maps and data. A historical review of anthropogenic sites or structures is recommended and can be achieved by interviews of time witnesses or evaluation of old aerial photographs. High Potential Barrier Rocks (acc. to boreholes/acc. to geological map)) Medium Potential Barrier Rocks (acc. To boreholes/acc. To geological map) ca.4 km Figure 2: Potential Barrier Rock Map of the Lamphun area (abbreviated after Dorn & Tantiwanit, 2002). 9 1.2 Geological Assessment First Assessment of the Potential Barrier Properties The most important characteristic of the geological barrier is it’s low to very low hydraulic conductivity. Only areas where the lithological information gives evidence for low hydraulic conductivity should be suggested as possible sites for detailed investigations. The geological map gives the first clue to the hydraulic conductivity, however, field surveys are necessary to prove this. A study on potential barrier properties of different lithologies has been performed in the Chiang Mai area and the following scheme has been developed (abbreviated from Dorn & Tantivanit). Unit Potential Barrier Property high 5 6 Lithological description Fluvial clay : clay, silty Natural levee silt, very fine Alluvial fan sand Alluvial sand and clay Low terrace gravel Colluvial formation 7 High terrace gravel none 8 9 Sandstone Shale and mudstone low high 1 2 3 4 10 medium to high none medium to high none high This scheme gives an idea in which way the potential barrier property might be attributed to the different lithologies, but for every geological setting an appropriate scheme must be developed. A map, termed Recommended Areas for Site Investigation Map (RASIM) should be compiled. In this map only areas with high to very high potential barrier characteristics and not excluded by the excluding criteria above are to be marked. This map should be compiled in a format readily comprehensible for the public and should be used to inform all stakeholders of the current status of the investigation. Detailed Investigation The one to three areas recommended for detailed investigations due to their supposedly high to very high potential barrier properties must now be investigated in detail. The detailed investigation aims at the assessment of the subsurface in terms of structure and composition (texture, grain size, mineral content, density, water content, possibly contamination), strength (compressibility, shear strength), porosity and water saturation, and hydraulic conductivity. The detailed investigation must not only focus on the planned landfill site but also on its surrounding. The groundwater system of a site might cover an area of several 10 km2, and information about this system must be collected. The local system to be investigated in detail usually covers an area between 0.1 and 1 km2. Relevant to site investigations is a depth range from surface to 50m depth. Deeper (up to 150m) investigations (possibly by reflection seismics) might be necessary to better understand the regional structures (stratigraphy and tectonics) as well as the groundwater system. Principle Approach The geological barrier must be as homogeneous and hydraulically impermeable as possible in order to minimize the risk of groundwater pollution. The principle aim of the study is to proof these characteristics of the planned landfills subsurface. Below the one to three sites recommended for detailed investigation the extension and thickness of the rock beds (lithological units) and their hydraulic conductivities are determined using geological methods (geological mapping, excavations, drilling, direct push sounding, geophysical borehole logging) in combination with geophysical methods, remote sensing, hydrogeological investigations, geo- and hydrochemical analysis, determination of the retention capacity and geotechnical assessment. These different methods are described in detail below. The Conceptual Model A conceptual hydrogeological model is the basis as well as the final result of the (hydro)-geological investigation of new landfill sites and contaminated sites. The initial conceptual model will continually change during the process of investigation. For every site two steps are necessary to develop a first conceptual hydrogeological model: 1. geological field survey and overview surveys. All boreholes and measurement points must be plotted into this map. The requested lateral accuracy is 1m and the precision for the elevation should be 0.01 m for boreholes to be used as groundwater observation wells, 0.03m for gravimetry, 0.1m for seismics and 0.5 m for geoelectrics and electromagnetics. It is strongly advisable to mark the geophysical profiles on the investigated site in a lasting way. on the refined model. Detailed geophysical measurements might be helpful to clarify the hydrogeological situation. Normally drilling should be done on the geophysical profiles in order to enable the best calibration of the geophysical measurements. It should be considered well in advance that drilling and geophysical profiling is performed in such a way as to enable the identification of the groundwater flow direction. The results of the geophysical surveys are to be used to refine the conceptual hydrogeological model. The position of the investigations wells will be decided upon based 2. analysis of existing well and borehole data. The geological field survey must include not only the site but must cover the surrounding area. The geology of the area is to be assessed in terms of lithology, stratigraphy and tectonics. Hand augering is to be performed and the samples are to be analyzed lithologically and stratigraphically. Water samples are to be taken and analyzed for the hydrochemical characteristics. A detailed geological and hydrogeological map of the site and its surrounding is to be compiled. This map serves as base map for positioning of the geophysical Figure 3: Cross section in North-South direction of the site Mae Hia in the Chiang Mai area. Groundwater flow towards south into the canal is evident by the water table of the wells and boreholes. The waste site is within a clay rich layer thus inhibiting leaking of contaminants into the deeper groundwater layers, as verified by hydrochemical measurements. 11 1.3 Hydrogeological Investigation These parameters have to be measured in the field or be obtained from nearby meteorological stations. Comprehensive knowledge of the groundwater conditions is necessary for the assessment of long-term safety of a planned landfill site as well as the planning of effective groundwater monitoring. It is necessary to investigate all major aquifers which could possibly provide a pathway for contaminant transport. Their hydraulic and hydrochemical parameters need to be assessed. Based on results of the investigation of groundwater conditions and geological information, a hydrogeological model of the site must be developed. Field Investigations Compilation of Climatic Data There are different reasons to study the local climatic and hydrological conditions. The climatic conditions define the water balance of the investigation site. The most important parameters are precipitation, temperature, humidity, runoff, evaporation and evapotranspiration. Precipitation not only recharges the groundwater, but also forms leachate in landfills and mobilizes solutes in contaminated sites. 12 Subsurface investigations, such as trenches, boreholes and direct push technology (DPT) soundings are necessary to get information about: • the geological structure, • the lithological and stratigraphical profile, • the spatial distribution of aquifers and aquicludes, • their hydraulic and geochemical properties, and • the groundwater table and the catchment area of the drainage basin. It is necessary to drill wells and to sample water, soil and rocks for laboratory analysis. Hydraulic well tests, pumping tests, groundwater tracer tests and continuous groundwater level measurements are used to investigate the hydrodynamic situation of a site. For these investigations groundwater monitoring wells are necessary. Therefore drilling and well construction is an essential part of the hydrogeological field work. Quality monitoring wells are furthermore the prerequisite for hydrochemical sampling. Apart from the requirements for hydrogeological site investigations, it should be considered to use the newly constructed wells as components of a groundwater monitoring system. Well Construction Drilling and installation of wells are the most important hydrogeological investigation methods. The construction of monitoring wells of high quality is of crucial importance for well tests and hydrochemical sampling. Important for the quality of wells are: • clean work and proper materials, • appropriate drilling technique, • correct placement and length of the filter, • sufficient clay seals, and • suitable well dimensions for all following investigation (sampling, hydraulic tests, etc.). Hydrogeological Conditions The hydrogeological conditions of a site can be described by the following parameters: water table, water content, direction and rate of groundwater flow, hydraulic conductivity, and value of aquifer. The hydrogeological situation is a significant aspect which determines the geotechnical concept of a planned landfill. The groundwater table below the landfills base and the mechanical properties of the geological barrier determine the level of the landfill base. The hydraulic conductivity (kf) of the saturated zone can be determined with various methods. These include pumping tests, well bore tests (slug/bail, drill-stem, water pressure and vibratory methods), and infiltration tests. While pumping tests are suitable for the determination of hydraulic conductivities of aquifers, other tests (e.g. drill-stem, slug/bail, pulse test) are also applicable in potential barrier material with low hydraulic conductivities. The term infiltration describes the entry of water into the soil through the ground surface. Lysimeters and double ring infiltrometers are devices to study the infiltration processes. Groundwater Dynamics Groundwater dynamics – the temporal behavior of groundwater- as one aspect of the hydrogeological conditions is determined by the following parameters: • • • • • • • groundwater gradient, direction and rate of groundwater flow, depth of groundwater table, hydrodynamic dispersion, groundwater recharge, hydraulic interaction between aquifers, and seepage from aquifers and surface waters. Water level measurements in observation wells allow the determination of groundwater contours, groundwater flow direction, and groundwater gradient. Furthermore, by investigating time series of water levels and geological information, confined and unconfined aquifers can be distinguished. Based on the understanding of the hydrogeological conditions at the site, derived from the aforementioned data, the hydrogeological model for the site can be developed. The measurements of the groundwater levels are generally taken over longer time periods, if possible throughout a full hydrological year (i.e. comprising all seasons, usually 1 November until 31 October) and correlated with measurements taken over many years from neighboring observation wells. Only by this procedure the natural fluctuations in the water levels and their effects on the hydraulic system can be interpreted. Civil engineering measures for the construction of the landfill base (e.g. assessing distance to the groundwater in all seasons, required depth of the drainage system) can be adequately planned if this information is at hand. aquifer filling material filter gravel counter filter seal L d BH F screen casing water level Figure 4: Schematic sketch of monitoring well filter section. 13 1.4 Geophysical Investigation Geophysical measurements are necessary to investigate the structure of the subsurface at the site of a planned landfill and the surrounding. Geophysical methods are most appropriate to get an overview on the layering, the depth to the different layers and their lateral and vertical extent. In order to proof the existence of the geological barrier and it’s homogeneity geophysical investigations are indispensable. Once a conceptual hydrogeological model is developed geophysical overview measurements should be done. These aim at proofing the model and assessing the heterogeneity of the subsurface. Based on the geophysical results the conceptual model should be refined. Furthermore detailed geophysical measurements might be required. The location of the boreholes should be decided upon based on the refined conceptual model. Suitable Geophysical Methods Many geophysical methods can be used for the investigation of the subsurface of a planned landfill, i.e. magnetics, gravimetry, dc-resistivity, electromagnetics, ground penetrating radar, reflection and refraction seismics and Surface Nuclear Magnetic Resonance (SNMR). In this chapter only dc14 resistivity, electromagnetics (EM) and refraction seismics will be described in more detail. The magnetic and gravimetric methods will be described in the chapter on hazardous sites. Reflection seismics often lacks resolution in the upper 20 m. It is used for the investigation of the deeper subsurface, if required. The investigation depth of ground penetrating radar is very limited in electrical conductive material such as clay. Both methods have many merits and might be required in certain cases. The SNMR method detects the free water quantitatively but and is currently in an experimental stage. DC-Resistivity The direct current (dc)-resistivity method reveals the structures and the layering of the subsurface in terms of electrical resistivity. To carry out dc-resistivity measurements current is induced into the subsurface by two electrodes (A and B) and the voltage is measured between two other electrodes (M and N). The investigation depth depends on the distance between the current electrodes A and B, the AB spacing. As a rule of thump the investigation depth is about 1/10 of the maximum AB-spacing. dc-resistivity measurements can be carried out in three different ways: dc-soundings, dc-resistivity mapping and multi-electrode measurements. The latter are used to pro- duce 2D-resistivity sections. These show the structures along a profile up to a certain depth, depending on the profile length, i.e. maximum AB-spacing (Figure 5). Different electrode configuration can be used, such as Schlumberger, Wenner or Dipole-Dipole. The most appropriate configuration depends on the situation and can be decided upon in advance by forward modeling. Many geological formations with low hydraulic conductivities also show low electrical resistivities thus dc-resistivity measurements are recommended for mapping the geological barrier properties of the subsurface. Sand and clay differ in electrical resistivity as do dry sand and water saturated sand. Dry sand shows normally high resistivities and clay, shale and mudstone normally show low resistivities. But the resistivities often overlap, thus borehole information is required for calibration. EM-Investigation Electromagnetic (EM) - mapping is the most often used method to investigate the lateral changes in the subsurface of a planned landfill site. The EM-method, as does the dc-resistivity method, looks upon the subsurface in terms of electrical resistivity. The electromagnetic waves, however, pose certain advantages. The contact to the ground is achieved by electromagnetic in- duction, not by electrodes, which might be difficult to stick into hard layers or might not get sufficient electrical contact in loose dry sand. EM-measurements are often done along profiles and the electrical resistivity is measured. The investigation depth depends on the frequency and the distance between transmitter and receiver. Instruments usually offer more than five frequencies and some fixed transmitter-receiver distances. Mostly measurements are carried out for investigation depths of up to 30m, deeper measurements are possible but rarely used. Refraction Seismics Refraction seismic looks upon the subsurface in terms of seismic velocities. An elastic wave is called refracted, if it runs at the interface of two layers with different velocities. The refracted wave can only be recorded at the surface, if the velocity is increasing with depth. This generally happens, if young soft sediments cover older and harder ones, or if they cover even hard rocks. The stronger the velocity contrast between the layers, the better the method works. A velocity gradient inside a layer can bias the depth of its lower layer boundary. The correlation of the seismic velocity to lithologies is ambiguous, as is the correlation between electrical resistivity and lithologies. Borehole information should be used to calibrate the measurements in terms of lithologies. an explosion and recorded along a surface profile by geophones. If the layers in the subsurface are inclined, the measurements must be done with reversed shooting, at least with shots at the start point and at the end point of the profile. If a subsurface layer is expected to be curved, more shotpoints in between are needed. The investigation depth depends on the profile length and the geological situation (attenuation and strength of velocity contrasts). As a rule of thump it is about 1/5 – 1/10 of the profile length. The required profile length and receiver distances can easily be calculated from expected velocity contrasts and depth. The elastic waves are generated by a hammer, a falling weight, a vibrator or even by Figure 5: dc-resistivity profile from a site consisting of a sandstone formation (reddish color, high resistivity) with interbedded mudstone layers (greenish color, low resistivity). The mudstone layer is discontinuous. Both, the geoelectrical section and the EM-Mapping (not shown), point to strong fracturing. Potable water was found in a borehole at profile length 650 m at a depth of 30 m. This site is therefore not suggested for landfill construction due to the lack of homogeneous barrier layers. 15 1.5 Geochemical and Hydrochemical Investigation The geochemical investigation in the study area is primarily focused on characterizing the complex chemical inventory of soil, rock, stream and lacustrine sediments, groundwater, surface water and soil gas. In case of planning and construction of a new landfill the geogenic background values and the anthropogenic input from former land use have to be determined for comparison with the later changes caused by the landfill. An hydrochemical assessment during operation and aftercare phase of a landfill is only possible with observations of the undisturbed state (hydrochemical background). Sampling Proper collection of the samples is necessary to obtain exact analytical results and thus a correct assessment of the site being investigated. Errors made in collecting the sample cannot be recognized in the laboratory and hence cannot be corrected afterwards. 16 Sampling of Water Sampling and analysis of water must be done in accordance with international standards (DIN, ISO, ASTM, EPA). • Groundwater samples from observation wells: DIN 38402-A13:12.85 and ISO 5667-11:03.93 • Preservation and handling of samples DIN EN ISO 5667-3:0496 • Surface water bodies DIN 38402A12:06.85 • Standing water bodies DIN 38402A15:06.86 Normally groundwater samples are taken from an observation well. Stagnant water has to be removed from the well before sampling, by purging. In the case of pumped groundwater samples, it is important to continually record changes in the well during the sampling (pH, electrical conductivity, temperature, oxygen concentration, depth to water table, and pumping rate) in order to determine the appropriate time for taking the sample and as documentation for the interpretation. The pumping for purging or during sampling must be such that the resultant lowering of the groundwater table is minimal. A submersible pump together with a pressure-retaining bailer fulfils the practi- cal requirements for sampling best. The need of on-site sample analysis as well as sample preservation measures must be assessed by the laboratory staff in accordance with the objectives of investigation. Sampling of soil In geochemical site characterisation samples of soil, rock, stream and lacustrine sediments (summarized as “soil”) are taken in order to determine the background contents and the location-specific properties. Soil samples can be taken form: dug holes, percussion core drillings, trenches, piles of soil, liner samples. The samples must be representative for a defined area and depth at a defined time. Samples are taken for laboratory analysis of: • texture, structure and environmental parameter values, • contents and distribution of substances, • physical, chemical and biological properties, • migration processes of interaction between the groundwater and the sediments, • microbiological and geochemical processes of natural attenuation Water Chemistry Analysis Soil Analysis For the characterization of the water type and the geogenic background of the investigation area, a spectrum of main ions and parameters should be analyzed, containing at least: The specific properties of a soil, the source rock of the soil, chemical environmental parameters (pH, redox) and sorption-effective components (organic carbon, clay mineral content) are significant for the migration behavior of contaminants and/or the sorption potential of the soil. They are therefore of prime importance for the characterization of the geological barrier. cations: Sodium, magnesium, calcium, potassium, aluminium, manganese, iron and silicon. ammonia. anions: chloride, sulphate, nitrate, and hydrogencarbonate/carbonate (total inorganic carbon). furthermore: TOC (total organic carbon), or DOC (dissolved organic carbon), pH-value, electrical conductivity, oxygen content, and redox potential. Basic soil parameter to be analyzed: • physical-chemical parameters dry bulk density, hydraulic conductivity, pH-value, electrical conductivity, grain size distribution, water con- tent, porosity , cation exchange capacity, neutralizing capacity (against acids and bases), and shrinkage/swell behavior of clay minerals. • mineralogical parameters clay mineral composition, contents of iron compounds, and carbonates. • chemical parameter: organic carbon content and the main ions in an aqueous extract.. Furthermore the methods described under 1.6. “Natural Attenuation Capability” should be included in the assessment of soil parameter for site characterization. For monitoring purposes and to trace the water quality changes during and after the operation of the planned landfill the following components, typical for waste site influence should be included in the analysis program: boron, sum parameters (COD, BOD) or groups of organic contaminants (e.g. phenols, mineral oil content), heavy metal(e.g. arsenic, cadmium, chromium, copper, mercury, nickel, lead, and zinc) Figure 6: Sampling of water with on site measurements and treatment. 17 1.6 Natural Attenuation Capability Natural Attenuation The effectiveness of the geological barrier is based not only on geohydraulical effects (low levels of water conductivity and diffusion) but as well on hydrochemical/biological and geochemical/-biological processes. These determine the natural attenuation capability of soil and sediments. Two of the most important processes of natural attenuation are the retardation and biodegradation of contaminants. Retardation is synonymous with delayed transport of a contaminant compared with the movement of water without contaminants. Causes for contaminant retention comprise the processes of adsorption/desorption with a transport-retarding effect. The preferred barrier material is a clay-rich substrate of low hydraulic conductivity which, unlike any other material, offers both low water conductivity and a large surface for reaction with pollutants, respectively. The retardation of cations and organic contaminants takes place primarily via sorption on fine grained mineral and organic components. In comparison with retardation biodegradation is the most important process of natural attenuation because of its sustainable reduction of contaminants. Biodegradation is also effected 18 by structure and texture of soil and sediments. These determine the level of redox potential and the availability of electron acceptors as well. and carbonates, cation exchange capacity, ion coating and exchangeable cations, main ions in aqueous extractions, pH-value as well as acid and alkali capacity. Worst Case Scenario For municipal landfills metal-sulfide systems (sulphide precipitation) and the formation of complexes by organic substances are of concern. It is suggested to examine the leachate from existing landfills for contaminants typically found in the dumped waste of the area. The propagation of substances from landfills takes place primarily in dissolved form. The worst case scenario is that the substances are not retarded (adsorbed) and biodegradated in soil and sediments, respectively. If this is the case the time until the leachate has passed through the geological barrier depends on the barrier thickness, its fine structure, its hydraulic conductivity, its porosity, and the hydraulic/hydrological boundary conditions (e.g. hydraulic gradient). This time is predictable using geohydraulic models. Each soil or sediment has more or less natural attenuation capability. For estimation of specific retardation and biodegradation parameters laboratory tests are necessary. Laboratory Tests for Retardation and Biodegradation Only laboratory tests provide the possibility for correlating retardation and biodegradation with the following parameters of the barrier material (soil or sediment): Clay mineralogical composition, content of organic carbon, contents of ion-compounds Because of the complexity of the different reactions between leachate and soil or sediment it is necessary to use original leachate and uncontaminated soil or sediment from the aquifer downstream of the landfill. Two laboratory test methods are common for estimation of retardation and biodegradation parameters. These are subdivided in batch and column tests. Batch tests are used for parameter estimation of sorption and transformation like biodegradation. Transport processes are not considered in batch tests. These tests may be performed on soil samples which are disturbed/undisturbed, consolidated/unconsolidated, saturated, or with a water/solid ratio of 1 or higher. One distinguishes, in general, between static and dynamic batch tests, depending on whether the soil and water are in motion during the batch test. Movement in those tests is used to accelerate the averaging process. Column tests are used for parameter estimation of transport, retardation and exchange between different phases like soil, air and water. The evaluation of column test data is based on the complete one-dimensional mathematical migration model. Therefore the length-diameter ratio of columns should be greater than 5:1 (3:1 at a minimum). A column experiment has to be performed until the output concentration of the contaminants reaches the input concentration in order to attain a break-through curve. 1.7 Geotechnical Stability For risk assessment of waste disposal sites knowledge about the stability of the ground is necessary. The landfill base sealing system and the stability of the landfill body is not to be jeopardized by settlement of the landfill body. Current and archival aerial photographs very often contain indications for destabilization processes like subsidence caused by subrosion and mining activities, landslides and sinkholes. Terrain feature indicating destabilization processes are fracturing and jointing, subsidence of Earth surface, caves to the surface, bedding slippage of slopes, break edges as well as tension and relaxation indications. Stability of the landfill base and the landfill body are required inter alia to ensure the functionality of the seepage collection as well as the base and surface seal. Settlement Calculation The calculations of the landfill settlement can be undertaken either analytically or numerically (e.g. finite element method). Rough settlement calculations can be performed „by hand“ and computer software is available in many versions. However, settlement calculations ultimately always represent approximations and the results can differ from reality to greater or lesser extent. For the calculation the modulus of resistance (Es ) of the different layers must be determined in the laboratory on soil samples using a compression-permeability test or other suitable tests. Es differs for the different soil types; typical values are 10 – 80 [MN/m2] in sand and 2 - 20 [MN/m2] in silty clay. As far as the function of the drainage systems and the base seal of landfills are concerned, it is not only the absolute figures for settlement of the subsurface which are critical but primarily the probability of settlement differences and the resulting stretching. The degree of settlement difference is mainly dependent upon the properties of the near surface beds. It is therefore of utmost importance to investigate the homogeneity of the planned landfills subsurface since lateral variations might be a hazard for the landfills stability. Settlement Time Settlements over thick cohesive beds can last about 100 – 200 years before they come to an end. This is a consequence of the slow rate of consolidation of the subsurface (as a comparison, the operating period of the landfill is approx. 10 years). If for example the clay bed has a thickness of 15 m, the settlement could rise to s = 9.75 cm and the time period could be t = 180 a. Stability Hazards Regretfully thick clay beds which offer effective barrier properties form particularly unstable slopes. Furthermore, in the case of soft substrata it is possible for deep reaching collapse figures to occur since loads can generate pore water overpressures which reduce the shear strength of the soil to solely that of the cohesion fraction (angle of friction). In order to alleviate the risk of slope failure the landfill construction must be preceded by a careful engineering study. 19 Part 2: Investigation of Sites Suspected to be Hazardous 2.1 Overview Investigation Old landfills, industrial sites and mining activities are rarely located on a geological barrier of sufficient quality. They are often a source of pollution of water, soil and air, thus possibly having harmful effects on humans and the environment. The objectives of the study are to investigate those sites in detail, to estimate their possible pollution risk and to suggest measures for the remediation of such risk. It is necessary to analyze the toxicity or danger of the material, the amount of toxic or otherwise dangerous material, the amount of leakage/contaminant transport and to estimate the area threatened by leakage/contaminant transport. The contamination by volatile substances (gaseous phase) and dust like particles also need to be assessed. As far as investigation of the landfill body is concerned, special safety regulations apply not least because of the risk of injury or impairment to the health of the personnel and the inadvertent carry-over of contaminants. Investigation is made more difficult by any inhomogeneities and instabilities of the landfill body. A further aspect is that the 20 landfill body may cover the geological underground strata. When investigating landfill bodies the focus must be on noninvasive techniques such as remote sensing and geophysics. Drilling work should be used very sparingly, if at all. The overview investigation of such sites suspected to be hazardous is subdivided into two parts: the overview investigation and the detailed investigation. First Tasks The first step is to gather all available information (recent and historic) of the sites suspected to be hazardous. This entails information about the former owner/user of the site, the kind of material deposited, details on the deposition methods and the usage of the site after termination of the deposition/use of the site. Site Typology There are three typical examples of sites suspected to be hazardous. These are classified as follows: ¾ industrial sites, ¾ waste deposits, and ¾ mining sites. Site Master Data The following data on the site are to be gathered ¾ site location: The site and its lateral extent must be marked on a topographic map with appropriate accuracy (±10m). GPS measurements may be required to ensure this accuracy, ¾ current owner and user of the site, ¾ type of waste deposition (e.g. stockpiling, heap on a slope, backfill of a quarry, backfill of a gravel pit, etc.) and amount of deposited waste or hazardous material, ¾ type of material deposited, its origin, and process of waste generation (e.g. uncontaminated excavated soil, natural rocks, minerals from mining industry, industrial waste, hospital waste, sludge from tanneries, etc.), ¾ type of contaminants expected (e.g. water soluble substances, gaseous and volatile substances, inorganic substances, organic substances, toxic substances, etc.), ¾ present use of the site, and ¾ owners of the adjacent properties. Site Historic Data All historic data on the site must be collected by whatever sources available. Multitemporal aerial photographs and satellite images should be evaluated in order to discover the site’s development and the former land use in the area. A report should be compiled containing the above mentioned and the following information: ¾ person(s) or company(s) responsible for release of harmful substances, ¾ operation time of the industrial sites, landfills or mining sites, and ¾ past use of the site. Site Screening by Field Surveys All indications of spreading of harmful substances by all possible pathways need to be analyzed. This task entails site surveys for vegetation changes, surface- and groundwater contamination, emissions of harmful volatile substances, and any other conspicuous occurrences. Remote sensing methods are particularly useful for parts of this study. The following themes have to be assessed: ¾ subsidence and/or indications for land slides and flooding, ¾ conspicuous changes (e.g. change in the color of soil, vegetation changes, death or illness of fishes or other species), ¾ ground- and surface water quality on and in the vicinity of the site. The chemical analysis must be done for all substances which can be expected to occur, ¾ seepage and/or other drainage signs near the site, samples are to be taken and analyzed for all substances important to assess the possible risk, and ¾ smell nuisance and Figure 7: Water conductivity in the shallow wells around the Mae harmful volatile sub- Hia Waste site in September 2002 (after Liese, 2004) stances in the vicingeoscientific criteria. However, other criteity of the sites with appropriate tools. ria, such as urgent economical needs, might have to be incorporated. The current status Site Ranking of national and international legislation has If there are several sites suspected to be to be adhered to. hazardous in an area the most dangerous A workplan for the detailed investigation of sites with pose urgent public health hazards the sites must be developed. must be outlined by applying an appropriate ranking scheme to the sites. A stepwise investigation procedure with the least detrimental effects for the human health and the environment must be developed. The ranking scheme has to be fully comprehensible for all stakeholders and must be based on 21 2.2 Detailed Investigation Aim of the detailed investigation is to examine all contaminant pathways of the most highly ranked sites suspected to be hazardous during a comprehensive field study. The pathways to be investigated are soil, water and air. Often contaminants are not easily traced. New methods use indicators to trace the environmental effects of contaminants by analyzing occurrence, abundance and health of most sensitive species. The most hazardous situation occurs when food plants can tolerate high contaminant loads. Under these circumstances the contaminants can easily enter into the food chain. Contaminant Inventory A contaminant inventory for each site must be established. Base for this inventory is the information on the former use of the site and the material deposited as already established during the orientating survey. The contaminant inventory must specify organics, inorganics, radionuclides and microbials in the highest possible detail. The Soil Pathway Contaminants might be deposited on the soil by erosion or reach the soil by leakage, by microbial activity or by capillary transport. The most common soil pollutants of metal22 lic (industrial) origin are Arsenic, Cadmium, Chromium, Copper, Lead, Mercury, Nickel and Zinc. Metal contamination can persist in the soil for very long periods. Other contaminants which might accumulate in the soil are pesticides, antibiotics, dioxin, endocrine disruptors and aggressive substances such as sulphates, chlorides and acids. Soil samples are to be taken on the site and all areas where the pollution might have spread by erosion, leakage, and other ways of transport. A map on soil contaminant spreading has to be prepared. Sampling and analysis should be done as described in 1.5. The Water Pathway Ground- and surface water contamination is of utmost concern. The main emission pathway from landfills and contaminated sites is the migration of leachate, carrying contaminants into the ground, initially into the unsaturated zone, from there into the groundwater and then transported with the groundwater flow into the surrounding area. For the investigation of this pathway firstly the ground- and surface water situation in the area is to be established. A hydrological and hydrogeological report on each site should be compiled comprising: ¾ maps on the hydrological and hydrogeological situation at the site, ¾ ground- and surface water flow direction in all surface waters and in all contaminated aquifers and the highest aquifer not yet contaminated, ¾ runoff amount, ¾ contaminant load and concentration in all surface waters and all aquifers, ¾ hydraulic conductivity of the aquifers, ¾ hydraulic conductivity of the aquifers, and ¾ estimation of groundwater/surface water interaction. In order to assess the ground- and surface water contamination sufficient amounts of samples are to be taken and analyzed for all important harmful substances and at all places deemed adequate to assess the contamination due to the site in a comprehensive way. The Air Pathway The gaseous phase and dust like particles on the site and in the vicinity must be measured with appropriate tools. It is necessary to extrapolate the spatial area likely to be effected by these gaseous phases. Seasonal changing wind speed and direction is to be taken into account. 2.3 Geophysical Investigation Geophysical investigation methods are particularly useful to determine the lateral and vertical extent of sites expected to be hazardous and to evaluate the spreading of harmful substances in the groundwater. However, what can be traced by geophysical means depends on the kind of substances deposited and leaking from the site. In addition to the dc-geoelectric method, the EMmapping and the refraction seismics, which is explained in section one, magnetic and gravimetric measurements, are recommended to detect buried sites and to discover the spatial extent of partly hidden objects. Geomagnetic Measurements Many sites expected to be hazardous contain metallic objects such as barrels, batteries, building rubbish with steel lining, cans, metallic industrial waste, wrecked vehicles or damaged vehicle appliances and ashes. Those items can be detected by magnetic measurements and an area where those items are scattered can be mapped by the geomagnetic method. The total magnetic field or the magnetic vertical gradient can be used for this study. The measurements are done on a regular grid covering the site and the magnetic read- ings are plotted. Data filtering and smoothing might be necessary to reduce the data scatter caused by ferromagnetic objects directly at the surface. If the total magnetic field is measured the values have to be reduced to account for the natural magnetic field at the site. Only the anomaly field is plotted and areas with scattered and buried ferromagnetic objects are often obvious by strong small scale variations of the magnetic readings. The surrounding area, where the magnetic field is only due to natural sources often shows an only slightly varying magnetic field. If the magnetic vertical gradient is measured the distance between the two sensors and the measurement height can be used for smoothing. The values of the gradient are plotted and the landfill often shows itself by high negative or positive values of the vertical gradient compared to the surrounding area, where only the natural magnetic field exists. Gravity Measurements extent of a buried landfill can be discovered by the gravimetric method. The gravity measurements are done on a regular grid and utmost care must be taken to determine the elevation of every single measurement point, the required accuracy is < 3 cm. It is necessary to carry out the measurements in a loop and to repeat a certain amount of readings to correct for the instrumental drift and the tidal signal. The normal gravimetric corrections must be applied and the anomalies are plotted on a map. The buried landfill often shows itself as a distinct negative anomaly compared to the surrounding having undisturbed layers. The hope to detect buried cavities, however, is often in vain, since they normally cause a very small signal which remains hidden in the overall noise of the measurements. Depending on the anticipated size of the cavity and the density of the surrounding material the expected signal of the cavity should be modeled in order not to attempt hopeless endeavors. Most landfills contain apart from single heavy objects loose material. The overall density of the landfill contents may be about 1540 kg/m3 while the surrounding geological strata might have a density of 2400 kg/m3. On account of this often the lateral 23 2.4 Hydrogeological Investigation Investigation of the groundwater situation is one of the key objectives when exploring a landfill or contaminated site. The groundwater is in most cases the main pathway for the migration of contaminants. The main objectives of the hydrogeological investigation in the course of site searching for a new landfill are the assessment of the geological barrier because its proper function inhibits contaminant migration. Normally the investigation of an old site or site suspected to be hazardous is initiated by the occurrence of contaminants in the surrounding of the site. Therefore the objectives of the investigation are: • assessment of the current state of contamination, • prognosis on the progress of contamination, and • planning of measures for remediation. The methods used for investigation are similar or identical to the methods described under 1.3, but sampling and drilling becomes even more important. After the assessment of the hydrogeological conditions and the groundwater dynamics, 24 in most cases it will be necessary to drill and establish a new monitoring system by constructing high quality monitoring wells. These drillings and wells are important for the determination of quality, quantity and distribution of contaminants. Production wells, dug wells and old monitoring wells of doubtful conditions may only serve as indication of contamination. Nevertheless a preliminary survey to determine whether there are any existing monitoring wells that may be suitable for integration into the planned monitoring network is always the first step during the planning of any monitoring program. In order to ensure the proper functioning of monitoring wells (e.g. no leakage), it is of utmost importance to carry out technical in situ tests (pumping or infiltration tests, borehole television, and geophysical borehole logging). tial distribution of contaminants and their changing conditions in time can be evaluated. They are also used for groundwater table monitoring. If the groundwater flow direction is unknown, as a first step three monitoring wells must be installed around the contaminated site (in a so called hydrogeological triangle) in order to determine the local groundwater dynamics. Drilling Technique The borehole drilling technique used must suit the conditions at the site and the questions to be answered. Each method has advantages and disadvantages in relation to the aim of investigation and the geological conditions. Investigation boreholes provide information about the geological profile. They are used to calibrate the geophysical measurements, to identify aquifers, to take rock samples, and to determine the depth of the groundwater table. Drilling techniques can be divided into percussion and driving methods or into dry methods and methods with fluid circulation. Common methods are: • cable tool techniques, • percussion drilling, • auger drilling (solid and hollow stem auger), and • rotary drilling. Monitoring wells should be constructed in such a way as to tap the different aquifers at different depths. From these wells the spa- Auger technique is the most desirable method for drilling on waste or contaminated sites. Using this method the geologi- Investigation Boreholes cal profile of the subsurface can be evaluated by the drill cuttings. These are transported to the surface and their depth can normally be determined as accurate as some 50 cm. The cuttings are used for grain size analysis and for geochemical laboratory investigations (batch tests). The hollow stem auger technology allows to take undisturbed sediment samples and also to install monitoring wells. Direct Push Methods There are two direct push methods: cone penetration testing (CPT) and percussion drilling. Prerequisite for the use of directpush technology is unconsolidated rock. Different tools are used to identify the lithology of different layers, the depth of the groundwater table, the thickness of the capillary fringe, or to detect the distribution of contaminants in the subsurface. There are also tools for collecting soil, water, and soil gas samples. CPT tools can be used with geophysical sensors, for example to measure: • electrical conductivity to determine sediment type and contaminations, • natural gamma measurements to determine the clay content, • neutron-neutron to determine the water content, and • gamma-gamma measurements to determine the density. Geophysical logging methods provide very detailed information about the strata. Geotechnical tools can provide a highly detailed, 3-dimensional picture of the subsurface in less time than needed by traditional methods. soil-gas, and groundwater samples can be taken at selected depths. Open direct-push boreholes provide a path for contaminant migration. Therefore these boreholes have to be sealed with bentonite once the investigation is terminated. Special tools are available for detecting types of contaminants, e.g.: • petroleum hydrocarbons, • BTEX (benzene, toluene, ethyl benzene, xylene), • volatile organic halogen compounds (VOC), • PAH (polycyclic aromatic hydrocarbons), and • Phenols. Individual compounds cannot be identified and the results are only semiquantitative. Other tools are able to detect inorganic substances (e.g., heavy metals). Sample Collection Sample collection is also possible with direct-push technologies. When the lithology and the type and distribution of contaminants has been determined using geotechnical and contaminant-detecting tools, soil, Figure 8: Typical lithological log resulting from drilling. 25 References / Further Reading ALLABY, M. (1977): A dictionary of the environment. Van Nostrand Reinhold Company, New York. BANNERT, M., BERGER, W., FISCHER, H., HORCHLER, D., KEESE, K., LEHNIK-HABRINK, P., LÜCK, D., PRITZKOW, J. & WIN, T. (2001): Anforderungen an Probennahme Probenvorbehandlung und chemische Untersuchungsmethoden auf Bundesliegenschaften. Ed. Bundesanstalt für Materialforschung und -prüfung (BAM) Berlin, Amts- und Mitteilungsblatt der BAM, Sonderheft 2/2001. BOWEN, H. J. M. (1979): Environmental chemistry of the elements. Academy Press, London. COHEN, R. M. & MERCER, J. W. (1993): DNAPL site evaluation. C.K. Smoley, Boca Raton, FL. DAVIS, N. S. & DE WIEST, R. J. M. (1966): HYDROGEOLOGY. Wiley & Sons, New York. DORN, M. & TANTIWANIT, W. (2002): New methods for the delineation of geological barrier rocks for waste disposal sites in northern Thailand. Episodes, 25, 4, 240-247. FANG, Z. (1995): Flow injection atomic absorption spectrometry. Wiley. FETTER, C. W. (1994): Applied hydrogeology. MacMillan College Publishing Co. FREEZE, R. A. & CHERRY, J. A. (1979): Groundwater. Prentice-Hall, Englewood Cliffs, N.J. GILLHAM, R. W. & O’HANNASIN, S. F. (1994): Enhanced degradation of halogenated aliphatics by zero-valent iron. Groundwater, 32, 6, 958-967. JACKSON, J. A. (Ed.) (1997): Glossary of Geology. 4th edition. American Geological Institute, Alexandria, Virginia. 26 KNOEDEL, K., LANGE, G. & VOIGT, H.-J. (2006): Site Investigation Methods. Methods in Environmental Geology, vol. 2, Springer, Berlin. LAKE, D. L., KIRK, W. W. & LESTER, J. N. (1984): Fractionation, characterization, and speciation of heavy metals in sewage sludge and sludgeamended soils: A Review. LANG, H-J., HUDER, J. & AMANN, P. (1996): Bodenmechanik und Grundbau. 6. Aufl. Springer, Berlin, Heidelberg, NewYork. LIESE, MANJA (2002): Hydrogeological site investigation at the waste disposal site Mae Hia, Thailand. Diploma Thesis, Brandenburg, Technological University Cottbus. LOHMANN, S. W. et al. (1972): Definitions of selected ground-water terms – revisions and conceptual refinements. U.S. Geological Survey. Water-Supply Paper 1988. LUCKNER, L. & SCHESTAKOW, W. M. (1991): Migration Processes in the Soil and Groundwater Zone. Lewis Publishers. MCNAUGHT, A. D. & WILKINSON, A. (1997). IUPAC Compendium of Chemical Terminology – The Gold Book. 2nd edition. Blackwell Science. Also available online: http://www.iupac.org/publications/compendium/i ndex.html NAS-NRC: National Academy of Science, National Research Council (1994): Alternatives for groundwater cleanup. National Academy Press, Washington, D.C.. NIELSEN, D. M. (1991): Practical Handbook of Ground-Water Monitoring. Lewis Publishers. PCD (1998/2000): Regulation and Guideline of Municipal Solid Waste Management. Pollution Control Department (PCD), Bangkok. QUEVAUVILLE, P. (1996): Harmonization of leaching/extraction tests for environmental risk assessment. Sci. Tot. Environ. 178, 1-132. SABINS, F. F. (1997): Remote Sensing: Principles and Interpretation. 3rd edition. Freeman & Co., New, York. SHERIFF, R. E. (1991): Encyclopedic Dictionary of Exploration Geophysics, Third Edition. Society of Exploration Geophysicists. SMALL, H. (1989): Ion Chromatography. Plenum Press, New York. STANGER, G. (1994): Dictionary of hydrology and water resources. Lochnan, Adelaide, South Australia. TASi (1993): Technical Instructions on Waste from Human Settlements (TA Siedlungsabfall), Germany. TESSIER, A., CAMPBELL, P. G. C. & BISSON, M. (1979): Sequential extraction procedure for the speciation of particulate trace metals. Anal. Chem. 51, 844-851. TOLMAN, C. F. (1937): Groundwater. McGraw-Hill, New York. URE, A. M. & DAVIDSON, C. M. (1995): Chemical speciation in the environment. Blackie, London. USCE: U.S. Army corps of Engineers (1991): Glossary of hydrologic engineering terms. Hydrologic Engineering Center, Davis, CA. USEPA: U.S. Environmental Protection Agency (1994) Terms of environment, glossary, abbreviations, and acronyms. U.S. Environmental Protection Agency EPA 175-B 94-015. WILSON, W. E. & MOORE, J. E. (eds.) (2001): Glossary of Hydrology. American Geological Institute.