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BIOMASS-DERIVED ACTIVATED CARBON THROUGH SELF-ACTIVATION PROCESS Changlei Xia PhD Dissertation Defense Monday, March 14th, 2016 10:00 – 12:00 Discovery Park, Room A131, College of Engineering Conference Room Abstract Self-activation is a process that takes advantage of the gases emitted from the pyrolysis process of biomass to activate the converted carbon. The pyrolytic gases from the biomass contain CO2 and H2O, which can be used as activating agents. As two common methods, both of physical activation using CO2 and chemical activation using ZnCl2 introduce additional gas (CO2) or chemical (ZnCl2), in which the CO2 emission from the activation process or the zinc compound removal by acid from the follow-up process will cause environmental concerns. In comparison with these conventional activation processes, the self-activation process could avoid the cost of activating agents and is more environmentally friendly, since the exhaust gases (CO and H 2) can be used as fuel or feedstock for the further synthesis in methanol production. In this research, many types of biomass were successfully converted into activated carbon through the self-activation process, including kenaf core, kenaf fiber, sugarcane bagasse, sugarcane leaf, coconut fiber, peanut shell, sawdust, and pine wood. A novel activation model was developed to describe the changes of specific surface area and pore volume during the activation process. The relationships between the activating temperature, dwelling time, yield, specific surface area, and specific pore volume were detailed investigated using the kenaf core, kenaf fiber and pine wood as raw materials. The highest specific surface area and pore volume of the biomass-derived activated carbon through the self-activation process were up to 2738 m2 g-1 and 2.209 cm3 g-1, respectively. Moreover, the applications of the activated carbons from the self-activation process have been studied, including lithium-ion battery (LIB) manufacturing, water cleaning, oil absorption, and electromagnetic interference (EMI) shielding.