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QUESTIONS xv Atoms and Molecules 3 CHAPTER Tips and Tricks l A compound is composed of two or more elements chemically combined in definite proportions. l Ion is a charged particle and can be positively or negatively charged. l During chemical changes, the sum of masses of all the reactants remains equal to the masses of products. This is known as Law of conservation of mass. l The combining capacity of an element is known as its valency. l The chemical formula of a molecular compound is determined by the valency of the combining elements. l In ionic compounds, the charge on positive ions and negative ions is taken into account so that the overall chemical formula gives a neutral compound. l To bring uniformity, relative masses of all atoms are given in atomic mass unit (u) taking mass of one atom of a particular isotope of carbon (C-12) as 1/12 u. l The number of atoms present in 12 g of carbon –12 is 6.023 × 1023 which is called Avogadro number or Avogadro constant. l A mole denotes 6.023 × 1023 atoms, molecules or ions. l Mass of 1 mole of a substance expressed in grams is called its molar mass. l l In a compound, the elements are always present in definite proportion of mass. This is known as law of Definite Proportions. According to Dalton’s atomic theory, all matter whether element or compound is composed of small particles called atoms or molecules. l Each element has a name and a unique chemical symbol. l An atom is the smallest particle of an element and retains its identity throughout all physical or chemical changes. l A molecule is a group of two or more atoms that are chemically bonded together and forms the smallest part of an element or a compound. This can exist independently and shows all the properties of that substance. 2 3 ATOMS AND MOLECULES Elements, their Symbol, Atomic Number and Molar Mass Element Actinium Aluminium Americium Antimony Argon Arsenic Astatine Barium Berkelium Beryllium Bismuth Bohrium Boron Bromine Cadmium Caesium Calcium Californium Carbon Cerium Chlorine Chromium Cobalt Copper Curium Dubnium Dysprosium Einsteinium Erbium Europium Fermium Fluorine Francium Gadolinium Gallium Germanium Gold Hafnium Hassium Helium Holmium Symbol Atomic number Ac Al Am Sb Ar As At Ba Bk Be Bi Bh B Br Cd Cs Ca Cf C Ce Cl Cr Co Cu Cm Db Dy Es Er Eu Fm F Fr Gd Ga Ge Au Hf Hs He Ho 89 13 95 51 18 33 85 56 97 4 83 107 5 35 48 55 20 98 6 58 17 24 27 29 96 105 66 99 68 63 100 9 87 64 31 32 79 72 108 2 67 Molar mass/ (g mol–1) 227.03 26.98 (243) 121.75 39.95 74.92 210 137.34 (247) 9.01 208.98 (264) 10.81 79.91 112.40 132.91 40.08 251.08 12.01 140.12 35.45 52.00 58.93 63.54 247.07 (263) 162.50 (252) 167.26 151.96 (257.10) 19.00 (223) 157.25 69.72 72.61 196.97 178.49 (269) 4.00 164.93 Element Hydrogen Indium Iodine Iridium Iron Krypton Lanthanum Lawrencium Lead Lithium Lutetium Magnesium Manganese Meitnerium Mendelevium Mercury Molybdenum Neodymium Neon Neptunium Nickel Niobium Nitrogen Nobelium Osmium Oxygen Palladium Phosphorus Platinum Plutonium Polonium Potassium Praseodymium Promethium Protactinium Radium Radon Rhenium Rhodium Rubidium Ruthenium Symbol Atomic number Molar mass/ (g mol–1) H In I Ir Fe Kr La Lr Pb Li Lu Mg Mn Mt Md Hg Mo Nd Ne Np Ni Nb N No Os O Pd P Pt Pu Po K Pr Pm Pa Ra Rn Re Rh Rb Ru 1 49 53 77 26 36 57 103 82 3 71 12 25 109 101 80 42 60 10 93 28 41 7 102 76 8 46 15 78 94 84 19 59 61 91 88 86 75 45 37 44 1.0079 114.82 126.90 192.2 55.85 83.80 138.91 (262.1) 207.19 6.94 174.96 24.31 54.94 (268) 258.10 200.59 95.94 144.24 20.18 (237.05) 58.71 92.91 14.0067 (259) 190.2 16.00 106.4 30.97 195.09 (244) 210 39.10 140.91 (145) 231.04 (226) (222) 186.2 102.91 85.47 101.07 4 Element Rutherfordium Samarium Scandium Seaborgium Selenium Silicon Silver Sodium Strontium Sulphur Tantalum Technetium Tellurium Terbium CCE SCIENCE–IX Symbol Atomic number Molar mass/ (g mol–1) Element Symbol Rf Sm Sc Sg Se Si Ag Na Sr S Ta Tc Te Tb 104 62 21 106 34 14 47 11 38 16 73 43 52 65 (261) 150.35 44.96 (266) 78.96 28.08 107.87 22.99 87.62 32.06 180.95 (98.91) 127.60 158.92 Thallium Tl 81 204.37 Thorium Th 90 232.04 Thulium Tm 69 168.93 Tin Sn 50 118.69 Titanium Ti 22 47.88 Tungsten W 74 183.85 Uranium U 92 238.03 Vanadium V 23 50.94 Xenon Xe 54 131.30 Ytterbium Yb 70 173.04 Yttrium Y 39 88.91 Zinc Zn 30 65.37 Zirconium Zr 40 91.22 The value given in parenthesis is the molar mass of the isotope of largest known half-life. Atomic number Molar mass/ (g mol–1) 5 ATOMS AND MOLECULES Formative Assessment ORAL QUESTIONS (Conversation Type) 1. (a) Are the laws of combinations based on conservation of energy or conservation of mass? (b) What is the advantage of this law in chemical reactions? (c) Which statement of Dalton’s atomic theory is in conformity with the above law? (d) On what accounts regarding nature of atoms, Dalton’s atomic theory fails? (e) Does the fact that ‘atom can be subdivided’ affect normal chemical reactions? 2. (a) What is an atom? (b) Do elements exist as atoms? (c) How are atoms of elements represented in chemistry? (d) What is the purpose of writing atoms by symbols? (e) What is the symbol of mercury and silver? 3. (a) How is the mass of an atom measured? (b) What is one atomic mass unit? (c) Why is such a scale chosen? (d) How do you account the fractional masses of many elements? 4. (a) What is valency? (b) How is valency of an element determined? (c) What is the use of valency? (d) Give an example. (e) What is molecular mass? ORAL QUESTIONS 1. Mass of reactants is equal to mass of products. Which postulate of Dalton‘s atomic theory demonstrates this? 2. What is the Latin name and symbol of sodium? 3. What is the Latin name and symbol of gold? 4. What is the atomicity of phosphorous? 5. What is the atomicity of sulphur? 6. Give the name and symbol of a triatomic molecule. 7. Hydrogen and oxygen always combine in the ratio of 1 : 8 to form water. Which law of combination does it demonstrate? 8. Which parameter gives the combining capacity of an element? 9. In what form atoms of a solid exist? 10. What is the smallest particle of a compound capable of stable existence? 11. What is a charged particle called? 12. What unit represents weight of 1 th mass of 12 C-12 atom? 13. What represents the chemical composition of a compound? 14. What mass represents 1 mole? 15. What number represents 1 mole? 16. What is Avogadro number constant? 17. How many molecules will be present in 1 gram molecular mass of a substance? 18. How are C12 and C14 related? 19. How are C14 and N14 related? 20. What is the term used for mass in grams of 1 mole of a substance? TRUE OR FALSE 1. A compound may consist of two or more elements in varying composition. 2. Law of conservation of mass states that energy can neither be created nor destroyed. 3. The occurrence of isotopes leads to drawback of Dalton’s atomic theory of matter. 4. Lead is represented as Ld. 5. A molecule of a compound is indicative of its properties. 6. Copper carbonate is a heteroatomic molecule. 7. Nitrate is a polyatomic anion. 8. The molecular formula of aluminium nitrate is AlN. 9. The atomic mass of Mg is 24 grams. 10. One mole of a gas occupies 22.4 litres at any temperature and pressure. 6 CCE SCIENCE–IX QUIZ B. ⇒ Across 1. Symbolic representation of a compound (7) 1. According to me a compound is composed of the same elements combined together in the same proportion by mass. 3. A quantity giving 6.02 × 1023 molecules of a compound (4) 2. I had announced that atoms of a given element are identical in mass and chemical properties. 3. I am the building block of an element. 4. I represent sodium as Na. 5. I am the smallest unit that gives the relative mass of an atom. 6. I am a monoatomic molecule. 7. I am a giant molecule containing sixty carbon atoms. 8. I decide how many atoms of two elements will combine to form a molecule? 9. I am a number that gives one gram atom of the element. 10. I give mass in grams of 1 mole of a substance. PUZZLES A. ⇒ Across 1. Smallest particle of a compound (8) 3. Two atoms with same atomic mass but different atomic numbers (7) ⇓ Down 2. Scientist who gave atomic theory of matter (6) 4. An element having atomicity of 4 (11) ⇓ Down 2. A representation of an atom of an element. (6) 4. An element with a symbol of Cr (8) SUGGESTED PROJECT/ACTIVITY 1. Carry out simple precipitative reaction and see that law of conservation of mass is followed. Mix weighed amount of (a) barium chloride and sodium sulphate (b) lead nitrate and sodium chromate. and see that the amount of products formed remains the same. 7 ATOMS AND MOLECULES Assignments Name: ............................ Class: ......... Section: ......... Roll No.: ........ Grade: .......... Teacher’s sign: ....................... CLASS ASSIGNMENT 1. Which postulate of Dalton’s atomic theory is a result of law of conservation of mass? ..................................................................................... ..................................................................................... 2. In what way occurrence of isobars contradicts Dalton’s atomic theory? ..................................................................................... 6. Give the value of one atomic mass unit. ..................................................................................... ..................................................................................... ..................................................................................... 7. What is the symbol of gold? ..................................................................................... ..................................................................................... 8. Give names of three triatomic molecules. ..................................................................................... ..................................................................................... ..................................................................................... ..................................................................................... 3. Three samples of ammonia obtained in three different ways contain nitrogen and hydrogen in the ratio 3 : 14. Which law of combination does it conform to? Explain. ..................................................................................... ..................................................................................... ..................................................................................... ..................................................................................... 4. What is an atom? What would be the size of the smallest atom? ..................................................................................... ..................................................................................... ..................................................................................... ..................................................................................... 5. What do you mean by symbol of elements? ..................................................................................... ..................................................................................... ..................................................................................... ..................................................................................... 9. Are one atom of carbon and 2 atoms of oxygen equal to one molecule of carbon dioxide? Explain. ..................................................................................... ..................................................................................... ..................................................................................... ..................................................................................... ..................................................................................... 10. Write down the formulae of (i) (ii) (iii) (iv) hydrogen sulphide aluminium sulphate calcium bicarbonate barium sulphate. ..................................................................................... ..................................................................................... ..................................................................................... ..................................................................................... 8 CCE SCIENCE–IX Name: ............................. Class: ........ Section: ........ Roll No.: ........ Grade: ......... Teacher’s sign: ........................... HOME ASSIGNMENT 1. How is Avogadro constant defined? 6. Define and explain atomic mass of an element. ..................................................................................... ..................................................................................... ..................................................................................... ..................................................................................... ..................................................................................... ..................................................................................... 2. Give an example to show that chemical reactions obey law of conservation of mass. ..................................................................................... ..................................................................................... 7. How does an atom differ from a molecule? ..................................................................................... ..................................................................................... ..................................................................................... ..................................................................................... ..................................................................................... ..................................................................................... ..................................................................................... ..................................................................................... ..................................................................................... 8. Discuss the utility of mole concept. 3. Define and explain law of multiple proportions. ..................................................................................... ..................................................................................... ..................................................................................... ..................................................................................... ..................................................................................... ..................................................................................... ..................................................................................... ..................................................................................... ..................................................................................... 4. State drawbacks of Dalton’s atomic theory of matter. 9. Calculate the number of atoms in 1 g of copper. (Atomic mass of copper is 63.50.) ..................................................................................... ..................................................................................... ..................................................................................... ..................................................................................... ..................................................................................... ..................................................................................... ..................................................................................... ..................................................................................... 5. How do atoms exist? ..................................................................................... ..................................................................................... ..................................................................................... 10. How many moles of oxygen atoms are present in one mole of the following compounds? NaNO3, H2SO4, Cl2O7 ..................................................................................... ..................................................................................... ..................................................................................... ..................................................................................... ..................................................................................... .....................................................................................