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The Bohr Model of the Atom By the end of this lesson, I will be able to: Explain the following terms: energy level, atomic emission spectrum, wavelength, frequency, speed of light, energy, wave, photon, Planck’s constant. Relate the pattern in an element’s atomic emission spectrum to the atomic structure of the atom. Compare the relative sizes of the wavelength, frequency, and energy of different colors of light. Calculate the wavelength, frequency, and energy of different colors of light. Compare the Bohr model of the atom to the earlier RutherfordChadwick model of the atom. Energy Levels Rutherford-Chadwick Model Bohr Model ? What is the main difference between the Rutherford-Chadwick model and the Bohr model? Vocabulary! Energy level: a specific electron orbit around the nucleus of the atom – an electron must gain energy to move to a higher energy level. Part 1: Atomic Emission Spectra The presence of energy levels in the atom, explains the origin of hydrogen’s atomic emission spectrum. Vocabulary! The atomic emission spectrum of an atom is a specific pattern of colored lines that is seen when the light emitted from a sample of identical superheated atoms is viewed through a prism. Look at the handout titled “Atomic Emission Spectra”. The top section of this handout shows the atomic emission spectra of several elements including hydrogen. The pattern of colored lines is different for each element and can be used to identify the elements in a mixture. The bottom section of the handout shows the atomic emission spectra of four mixtures of elements. For each mixture, compare its atomic spectrum to the atomic spectra of the individual elements in the top section of the handout. ? Use the atomic spectra patterns to identify the elements in each of the mixtures in the bottom section of the “Atomic Emission Spectra” handout. Mixture A Elements Mixture B Elements Mixture C Elements Mixture D Elements In order to understand how Bohr’s model explains the atomic emission spectrum of hydrogen, we are going to create large-scale models of some hydrogen atoms. Your teacher has drawn the energy levels of an atom on the floor. Four of your classmates will take turns pretending to be hydrogen’s single electron. (They have each been provided with secret instructions!) Each of your four classmates will show a different way that hydrogen’s one electron can move between energy levels and what happens when it does. ? Record what happens to each electron on the atom diagrams below. The energy levels are each numbered. Hydrogen Atom #1 The electron: Hydrogen Atom #2 The electron: Hydrogen Atom #3 The electron: Hydrogen Atom #4 The electron: starts in level_____ starts in level_____ starts in level_____ starts in level_____ absorbs energy absorbs energy absorbs energy absorbs energy jumps to level_____ jumps to level_____ jumps to level_____ jumps to level_____ falls to level_____ falls to level_____ falls to level_____ falls to level_____ releases energy as light - color_______ releases energy as light – color_______ releases energy as light – color_______ releases energy as light – color_______ Compare the colors emitted by each of the electrons above to the atom emission spectrum for hydrogen on the “Atomic Emission Spectra” handout. ? What do you think is the origin of the four colored lines in the atomic emission spectrum of hydrogen? Part 2: The Nature of Light In order to understand Bohr’s model, we need to learn a little bit about the nature of light and color. Open the envelope labeled “Colors of Light Card Set”. This card set contains cards that illustrate the energy, wavelength, frequency, and speed of light of different colors of light. The symbols that are used for wavelength, frequency, energy, and the speed of light are indicated in parenthesis. Locate the card that describes red light. Look at the wavelength section of the card. ? What is the symbol for wavelength? ? Based on the illustration, what do you think is the definition of the wavelength of a wave? Vocabulary! Wavelength: the distance between the adjacent peaks of a wave. Look at the frequency section of the card. ? What is the symbol for frequency? ? Based on the illustration, what do you think is the definition of the frequency of a wave? Vocabulary! Frequency: the number of wavelengths that pass a designated point in one second. Arrange the cards as they appear in a rainbow: red, orange, yellow, green, blue, violet ? What happens to the size of the wavelength as you move from red towards violet? ? What happens to the size of the frequency as you move from red towards violet? ? What is the relationship between wavelength and frequency? (i.e. Do they both increase or decrease together or does one decrease when the other one increases?) ? What is the symbol for energy? ? What happens to the amount of energy in the wave as you move from red towards violet? ? What is the symbol for the speed of light? ? Compare the speed of light for each color. Is the speed of light the same or different for different colors of light? Light appears to behave as both a wave and a particle. Wave Vocabulary! Particle (photon) Wave-Particle Duality: Light appears to be able to behave as both a particle (photon) and a wave. Photon: A particle of light Part 3: Light Calculations The relationship between wavelength, frequency, and the speed of light is illustrated by the following formula. Formula in Words: speed of light = (frequency)(wavelength) Formula in Symbols: c = fλ Units: speed of light m/s frequency s-1 or 1/s wavelength m Constants: c = speed of light = 3.00 x 108 m/s The following example shows how to calculate the wavelength of a light wave when you are given the frequency. What is the wavelength of a wave of green light with a frequency of 6.01 x 1014 s-1? Formula: c = fλ Rearrange the Equation to Isolate λ: c = fλ c=λ f Substitute Values: (3.00 x 108 m/s) = λ (6.01 x 1014 s-1) Divide: λ = (3.00 x 108 m/s) = 4.99 x 10-7 m (6.01 x 1014 s-1) ? Try it! What is the wavelength of light with a frequency of 7.66 x 1014 s-1? Formula: Rearrange the Equation to Isolate λ Substitute Values: Divide: The following example shows how to calculate the frequency of a light wave when you are given the wavelength. What is the frequency of a wave of violet light with a wavelength of 3.88 x 10-7 m? Formula: c = fλ Rearrange the Equation to Isolate f: c = fλ c=f λ Substitute Values:: (3.00 x 108 m/s) = f (3.88 x 10-7 m) Divide: f = (3.00 x 108 m/s) = 7.73 x 1014 s-1 (3.88 x 10-7 m) ? Try it! What is the frequency of light with a wavelength of 5.20 x 10-7 m? Formula: Rearrange the Equation to Isolate f Substitute Values: Divide: The relationship between the wavelength, frequency, and energy of a wave is illustrated by the following two formulas. Formula in Words: Formula in Words energy = (Planck’s constant)(frequency) energy = (Planck’s constant)(speed of light) wavelength Formula in Symbols: Formula in Symbols: E = hf E = hc λ Units: Planck’s constant J•s speed of light m/s frequency s-1 or 1/s Constants: c = speed of light = 3.00 x 108 m/s wavelength m h = Planck’s constant = 6.63 x 10-34 J•s The following example shows how to calculate the energy of light when you are given the frequency. What is the energy of a photon of light with a frequency of 5.00 x 1014 s-1? Formula: E = hf Substitute Values: E = (6.63 x 10-34 J•s)(5.00 x 1014 s-1) Multiply: E = (6.63 x 10-34 J•s)(5.00 x 1014 s-1) = 3.32 x 10-19 J ? Try it! What is the energy of violet light with a frequency of 7.50 x 1014 s-1? Formula: Substitute Values: Multiply: The following example shows how to calculate the energy of light when you are given the wavelength. What is the energy of a photon of light with a wavelength of 5.62 x 10-7 m? Formula: E = hc λ Substitute Values: E = (6.63 x 10-34 J•s)(3.00 x 108 m/s) 5.62 x 10-7 m Multiply and Divide: E = (6.63 x 10-34 J•s)(3.00 x 108 m/s) = 5.62 x 10-7 m 3.54 x 10-19 J ? Try it! What is the energy of violet light with a wavelength of 7.20 x 10-7 m? Formula: Substitute Values: Multiply and Divide: Ask your teacher for an “Excite” game board , a pair of dice, and a set of game cards. You will also need the “Game Card Answer Sheet” and a small object to use as a game piece. Practice calculating wavelength, frequency, and energy by playing a game of “Excite” as described below. “Excite!” Game Rules 1. Separate the game cards into stacks of “Light” cards and “Energy” cards. 2. The first player rolls the dice and advances their game piece the indicated number of spaces. 3. If the player lands on a “Light” space, he or she draws a “Light” card. If the player lands on an “Energy” space, he or she draws an “Energy” card. 4. The player calculates the answer to their card and records the answer on their “Game Card Answer Sheet”. The other players should also calculate the answer at the same time. 5. The other players must agree that current player’s answer is correct. If the answer is incorrect, the player loses a turn. Disputes will be settled by the teacher. 6. If a player lands on a space at the bottom of a ladder, he or she must climb back to the space at the top of the ladder. If a player lands on a space at the top of a chute, he or she gets to slide down to the space at the bottom of the chute. 7. The player that gets the last space on the game board first is the winner. Game Card Answer Sheet Show your work for each card in the boxes below. Write the card number of each card in the smaller box. You do not have to use all of the boxes. Vocabulary Energy Level: a specific electron orbit around the nucleus of the atom an electron must gain energy to move to a higher energy level. Atomic Emission Spectrum: a specific pattern of colored lines that is seen when the light emitted from a sample of identical superheated atoms is viewed through a prism. Wavelength: the distance between adjacent peaks in a wave. Frequency: the number of wavelengths that pass a designated point in one second Speed of Light: the speed of all colors of light – the speed of light is equal to 3.00 x 108 m/s. Energy: absorbed by electrons causing them to become “excited” and jump to higher energy levels. Light Wave: a type of electromagnetic energy – waves transfer energy. Photon: a particle of light Planck’s Constant: a constant needed to calculate the energy of a photon of light – Planck’s constant is equal to 6.63 x 10-34 J•s. The Bohr Model of the Atom Study Sheet Atomic Emission Spectra Speed of Light Calculations Energy Calculations Copyright © Shari Kendrick