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應用物理學系 0932365 張勝騏 Pedrotti OPTICS: Problem 4-23 Estimate the Doppler broadening of the 706.52-nm line of helium when the gas is at 1000K. Use the root-mean-square velocity of a gas molecule given by 3RT M where R is the gas constant, T the Kelvin temperature, and M the molecular weight. r m s Ans: rms = J K/mole.K 3 8.314 1000 ( ) = 2.497 10 3 (m/s) kg/mole 0.004 ' = 1 c , ' (1 - 2.497 10 3 ) 706.52 (nm) , ' = 706.514 (nm) 3 10 8 ' - = 0.006 (nm) So the answer is ,because spectral width is 2 2 = 0.012 (nm).