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AP Chemistry Syllabus 2011-2012 Introductory/Review concepts (Chapters 1-3) 2 weeks Classroom Laboratory A. The Scientific Method A. Safety in the Laboratory B. Measurement B. Determination of the Empirical Formula of C. Atomic Theory Silver Oxide D. Nomenclature C. Analysis of Silver Alloy E. Stoichiometry a. Mole b. Determining chemical formula c. Limiting reactants * Challenge problems that incorporate d. Amount of reactant and products appropriate units, significant figures, e. Solutions limiting reactants and dimensional analysis Types of Chemical Reactions of Solution Stoichiometry (Chapter 4) 3 Weeks Classroom Laboratory A. Nature of aqueous solutions – strong and weak A. Synthesis of Alum electrolytes B. Identification of Alum B. Composition of solutions C. Finding the Ratio of Moles of C. Types of chemical reactions Reactants in a Chemical Reaction a. Acid-Base D. Determination of Solutions using i. Arrhenius Solubility Rules ii. Lowry-Brønsted iii. Lewis b. Precipitation c. Oxidation-Reduction D. Reactions in Solution E. Balancing oxidation-reduction reactions * Test on chapters 1-4 Gases (Chapter 5) 1 Week Classroom A. Define Pressure B. Gas Laws a. Boyle b. Charles c. Avogadro d. Dalton C. Gas Stoichiometry D. Kinetic Molecular theory of gases E. Effusion and diffusion F. Real Gases Laboratory A. Molecular Mass of a Volatile Liquid B. Determining the Molar volume of a Gas C. Value of a Gas Constant 1 AP Chemistry Syllabus 2011-2012 Thermochemistry (Chapter 6) 2 Weeks Classroom A. Nature of energy B. Enthalpy and calorimetry C. Hess’s Law D. Standard enthalpies of formation E. Energy sources a. Present b. New sources Laboratory A. Thermochemistry and Hess’s Law B. Vapor pressure and Enthalpy of Vaporization of Water Atomic Structure, Periodicity, Nuclear Structure (Chapter 7, 18) 3 Weeks Classroom Laboratory A. Atomic Structure A. An Activity Series a. Electromagnetic Radiation B. Using flame tests to identify metallic ions b. Development of atomic theory C. Gas discharge tubes and the spectroscope c. The quantum mechanical model of the atom d. Quantum numbers, atomic spectra, orbitals B. Periodicity a. History of the periodic Table b. Periodic Trends in atomic properties C. Nuclear Structure a. Nuclear stability and radioactivity b. Kinetics of radioactive decay c. Fission and fusion d. Effects of radiation Chemical Bonding (Chapters 8 and 9) 3 Weeks Classroom A. Types of bonds a. Ionic b. Covalent c. Metallic B. Electronegativity and polarity of bonds C. Covalent Bond Energies and chemical Reactions D. The Localized Electron bonding Model a. Lewis Structures b. VSEPR c. Atomic Orbitals – hybridization, resonance, sigma and pi bonds E. Relationship of molecular structure to physical properties Laboratory A. Gravimetric Analysis of a Metal Carbonate B. Permanganate Determination of an Iron Sample C. Laws of Definite and Multiple Proportions * Development of molecular orbital energy level diagrams for all first and second period homonuclear diatomic molecules to predict their stability, bond order, bond length, and magnetic properties. 2 AP Chemistry Syllabus 2011-2012 Liquids, Solids and Solutions (Chapters 10 and 11) 3 Weeks Classroom Laboratory A. Intermolecular forces A. Molar Mass by Freezing Point B. Structural models Depression a. Liquids B. Liquid Chromatography b. Solids i. Metals ii. Network Atomic solids iii. Molecular iv. Ionic C. Vapor Pressure and Changes of State D. Phase Diagrams E. Solution Composition F. Energies of Solution Formation G. Factors affecting solubility a. Structure b. Pressure c. Temperature H. Vapor Pressures of Solution * Marathon Problem p. 552 I. Osmotic Pressure * Application of solubility rules to predict J. Colligative Properties chemical reactions K. Colloids Chemical Kinetics (Chapter 12) 2 Weeks Classroom A. Reaction Rates B. Rate Laws C. Determining the form of the Rate Law D. The Integrated Rate Law E. Reaction Mechanisms Laboratory A. Kinetics of a Reaction B. Flow Rate of a Buret * Marathon Problem pp. 605-606 Chemical Equilibrium (Chapter 13) 3 Weeks Classroom A. Characteristics of Chemical Equilibrium B. Equilibrium Constants C. Applications D. LeChatelier’s Principle Laboratory A. Equilibrium and LeChatelier’s Principle B. Determination of the Equilibrium Constant for the Formation of FeSCN-2 * Challenge Problems p.650 #76, 78, 80, 82 Acids and Bases (Chapter 14) 3 Weeks Classroom A. The Nature of Acids and Bases B. pH Scale C. Calculating the pH a. Strong acid solutions b. Weak acid solutions D. Polyprotic acids E. Bases F. Acid-Base Properties of Salts Laboratory A. Acid-Base Titrations * Challenge Problems p.709: #140, 146, 148, 150 3 AP Chemistry Syllabus 2011-2012 Applications of Aqueous Equilibria (Chapter 15) 2 Weeks Classroom Laboratory A. Weak Acids and Bases A. Buffered Ssolutions a. pH B. Determination of Ka of Weak Acids b. pOH C. Solubility Product c. Buffers D. Determination Of The Equivalent Mass B. Solubility Product and pKa of an Unkknown Acid Spontaneity, Entropy, and Free Energy (Chapter 16) 1 Week Classroom Laboratory A. State Functions A. The Thermodynamic Constants for a Redox Reaction B. Laws of Thermodynamics C. Free energy a. Chemical Reactions b. Pressure c. Equilibrium d. Work Electrochemistry (Chapter 17) 2 Weeks Classroom A. Galvanic Cells B. Standard Reduction Potentials C. Electrolytic Cells D. Electrolysis E. Oxidation-reduction Reactions Laboratory A. Electrochemical Cells B. Charge of an Electron Transition Metals and Coordination Chemistry (Chapter 21) 1 Week Classroom Laboratory A. Transition Metals A. Preparation and Analysis of B. Coordination Compounds Tetraamminecopper(II) Sulfate C. Isomerism Monohydrate D. Bonding E. Applications Organic Chemistry (Chapter 22) 2 Weeks Classroom A. Saturated Hydrocarbons a. Nomenclature b. Reactions B. Alkenes and Alkynes C. Aromatic Hydrocarbons D. Hydrocarbon Derivations E. Polymers Laboratory A. Synthesis, Isolation, and Purification of an Ester 4