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TEST I (Aldehyde - Ketones) 1. The compound X with the formula C3H8O gives an oxidation the compound with formula C3H8O X is most likely to be : A) an aldehyde B) a ketone C) a tertiary alcohol D) a secondary alcohol E) an ether 2. Which compound yields a ketone upon mild oxidation ? A) CH3CH2CH2CH2OH B) CH3CH2CHCOH2OH C) CH3CH2OCH2CH3 D) (CH3)2CHCH2OH E) (CH3)3COH 3. 4. 5. 1 mol of an organic compound I. gives 2 mol of CO2 when burned II. gives an acid when oxidized III. doesn’t react with metallic sodium to form H2 What is the organic compound? A) C2H5OH B) HCHO C) CH3CHO D) CH3OH E) CH3COCH3 6. Which one of the following gives CH3COC2H5 when oxidized? A) 2-butanol B) 2-propanol C) 1-butanol D) t-butanol E) isopropyl alcohol 7. Which one of the following compounds reduces Cu2+ in Fehling’s reagent to Cu2O? Which one of the following will reduce silver nitrate to silver? A) CH3COCH3 B) CH3CHO C) CH3CHOHCH3 D) CCl3CH(OH)2 E) CH2ClCHOHCH3 A) H – C = O | H B) O || CH3 – C – CH3 C) CH3CH2OCH3 1 mol of an organic compound I. gives 3 mol of CO2 when burned II. gives a primary alcohol when reduced D) H | CH3 – C – CH3 | OH E) H H C=C H H What is the formula of the compound? A) CH2 – OH | C2H5 B) C2H5 | C=O | H C) CH3 | C=O | CH3 D) CH3 | C=O | H 8. E) CH3 | O | C2H5 1 Which one of the following gives 2-pentanol when reduced? O || A) CH3 – CH2CH2CH2 – C – H B) CH3 – CH2 – C – CH2CH3 || O C) CH3 – C – CH2CH2CH3 || O O || D) CH3 – C – CH2CH2COOH E) OH | CH3 – C – CH2CH2CH3 | COOH TEST I (Alcohols - Ethers) 9. What is the molecular formula of an aldehyde which has %40 carbon in its molecule? A) HCHO B) CH3CHO C) CH3CH2CHO D) CH3CH2CH2CHO E) CH3CH2CH2CH2CHO 13. 10. For an aldehyde molecule; I. it reacts with AgNO3 solution II. it is oxidized by Fehling’s reagent to acid III. when reduced; a primary alcohol forms Which one(s) is/are correct? A) I B) I–II C) II–III D) I–III E) I–II–III 14. 11. For the compound, CH3 – C = O | CH3 I. oxidized by AgNO3 solution (Tollen’s reagent) II. reacts with Na III. gives addition reaction with H2 Which one(s) is/are correct? A) I B) III C) I-II D) II–III E) I–II–III CH3 – CH – C = O for this organic compound; | | OH H I. gives a reaction with Na II. adds H2 III. reacts with Fehling’s reagent Which one(s) is/are correct? A) I B) I–II C) III D) I–III 12. When ethanol is oxidized completely, which of the following forms? A) ethylalcohol B) acetaldehyde C) acetic acid D) formic acid E) oxyethane 15. E) I–II–III H | I. H – C – OH | H–C–H | R1 R1 | III. R2 – C – OH | R3 I. after reaction with Na, 0.5 mol of H2 liberates II. when oxidized; acid forms III. doesn’t react with Zn 1 mol of an organic compound shows these properties what is the formula? A) CH3 | CHOH | CH2 | H–C=O B) CH3 | C=O | CHOH | CH3 C) CH2OH | C–H || C–H | CH2OH | CH2 | CH3 D) CH2OH | CH2 | C=O | CH2 R1 | II. H – C – OH | H – C – OH | R2 Which alcohol(3) can form aldehyde when oxidized? A) I B) III C) I-II D) II–III E) I–II–III 16. CH3 – CH2 – CH – CH – C = O | | | CH3 CH3 H What is the correct name of given organic compound? A) 2,4 – dimethyl pentanal B) 2,3 – dimethyl – 1 – pentanal C) 2,3 – dimethyl – 1 – pentanol D) 2 – methyl – 3 – wthyl – 1 – bütanal E) n - heptanal 17. E) CH2OH | CH2 – C – CH2O | CH2 | C=O | H I. CH3OH II. H – C = O | H III. CH4 What is the correct order of increasing boiling points of given compounds? A) III<II<I B) III>II>I C) I=II=III D) II>I>III E) III>I>II 2 TEST I (Alcohols - Ethers) 18. 25. For given organic compound; CH3 – CH – C = O | | CH3 H I. methanal II. ethanal III. propanal Which one(s) doesn’t/don’t has/have any isomer of ketone? A) II B) III C) I-II D) II–III E) I–II–III I. 2 – methyl propanal II. reacts with Na metal III. reacts with Tollen’s reagent Which one(s) islare expected to be correct? A) I B) II C) I-III D) II–III E) I–II–III 19. 26. CH3 – CH – CH – C = O for this compound; | | | OH CH3 H Which one(s) can not be oxidized? A) I B) II C) III D) II–III E) I–III 27. 21. which of following reduces the Ag+ for to the Ag in the Tollen’s reagent? A) Aldehyde B) Ketone C) Alkene D) Carboxylic acid E) Ester CH3 – CH2 – C – CH3 for this organic compound; || O I. methyl ethyl ketone II. 2 - butanone III. butane – 2 – one Which name(s) is/are correct? A) I B) I-II C) II-III D) I–III E) I–II–III 23. For ketones I. gives addition reaction II. contains carbonyl group III. produced as a result of oxidation of secalcohols Which one(s) is/are correct? A) II B) III C) I-II D) II–III E) I–II–III 24. What is the smallest carbon number of the simplest ketone? A) 2 B) 3 C) 4 D) 5 E) 6 I. CH3 – C = O | H II. CH CH III. CH3 – CH – C = O | | OH H Which one(s) reduce(s) the Ag+ ion in Tollen’s reagent to Ag metal? A) I B) III C) I-III D) II–III E) I–II–III Which one of the following gives 2 – methyl – 3 – pentanone when oxidized? A) 2 – methyl – 3 – pentano l B) 2 – oxy – hexane C) 2 – methyl – 2 – oxy pentane D) 3 – methyl – 2 – oxy pantanol E) n - hexanol 22. II. CH3 – C = O | CH 3 III. CH3 – C = O | H I. liberates H2 gas from the reaction of Na II. reacts with Tollen’s reagent III. adds H2 Which one(s) is/are correct? A) I B) I-II C) II-III D) I–III E) I–II–III 20. I. H – C = O | H 28. Which of the following forms when isopropyl alcohol oxidizes only one step? A) propanal B) dimethyl ether C) acetone D) methyl ethyl ketone E) propanoic acid 3