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Chemistry 130 Exam 1 Spring 2007 April 26, 2007 Oregon State University Dr. Richard Nafshun Fill in the front page of the Scantron answer sheet with your last name, first name, middle initial, and student identification number. Leave the class section number and the test form number blank. This exam consists of 15 multiple-choice questions. Each multiple-choice question has five points associated with it. Select the best multiple-choice answer by filling in the corresponding circle on the rear page of the answer sheet. 1. The systematic name of (A) (B) (C) (D) (E) 2. is 3,4,5-trimethylnonane is 4,5-dimethyl-7-ethyloctane is 2-ethyl-3,4-dimethylnonane is 3-ethyl-4,5-dimethyloctane is 3,4,5-trimethyloctane The molecular formula of (A) (B) (C) (D) (E) is C9H20 is C9H10 is C9H4 is C8H7 is C8H10 3. The systematic name of (A) (B) (C) (D) (E) 4. Consider 2-pentanol, 3-pentanol, pentane, 2-pentene, and 2-methylpentane. Which of the following is true? (A) (B) (C) (D) (E) 5. is cis-butene is cis-1,2-dimethylethene is trans-1,2-dimethylethene is cis-3-heptene is trans-3-heptene 2-pentanol and 3-pentanol are isomers pentane and 2-pentene are isomers 2-pentene and 2-methylpentane are isomers 2-pentanol and 2-pentene are isomers 2-pentanol and 2-methylpentane are isomers Complete the following substitution reaction: Cl + Br2 __________ + HBr Cl Cl Br (A) (B) + Br Br (C) Cl (D) Br 6. Complete the following substitution reaction: NO 2 + Br2 __________ + HBr NO 2 NO2 Br (A) (B) + Br NO2 (C) NO2 (D) Br 7. Which of the following is true? (A) CH3CH2CH3 has a higher boiling point than CH3CH2OCH3 because of hydrogen bonding. (B) CH3CH2CH3 has a higher boiling point than CH3CH2CH2OH because of dipole-dipole forces. (C) CH3CH2OCH3 has a higher boiling point than CH3CH2CH2OH because of dipole-dipole forces. (D) CH3CH2OCH3 has a higher boiling point than CH3CH2CH2OH because of hydrogen bonding. (E) CH3CH2CH2OH has a higher boiling point than CH3CH2OCH3 because of hydrogen bonding. 8. Complete the following reaction: 9. In a condensation reaction, an alcohol and a carboxylic acid produce: (A) (B) (C) (D) (E) an amide an ether an ester an aldehyde a ketone 10. The name of NO2 Br (A) (B) (C) (D) (E) 11. is 5-bromonitrobenzene is 1-bromonitrobenzene is p-bromonitrobenzene is m-bromonitrobenzene is o-bromonitrobenzene Complete the following addition reaction: + HBr Br Br (A) (B) Br Br (C) (D) Br 12. How many of the five alcohols shown below are primary alcohols? (A) (B) (C) (D) (E) 1 2 3 4 5 13. Identify the functional groups in the following molecule: Cl HO O O O N C H O (A) (B) (C) (D) (E) amide, ether, alcohol, aldehyde, amine amide, alcohol, ester, aldehyde carboxylic acid, amine, ether, ketone alkene, 2 ketones, alcohol, carboxylic acid ester, carboxylic acid, aldehyde, amide 14. What is produced from the elimination of 1-hexanol with warm H2SO4? (A) (B) (C) (D) (E) 15. a thioalcohol a disulfide an aldehyde an alkene an ester Complete the following oxidation reaction: O C H [O] (A) H C (B) H O C (C) OH O C H OH (D) (E) OH O