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AP Chemistry Please place your answers on the answer document provided. 1. A beaker in the laboratory has a volume of 250. mL. What is the volume of the beaker in liters? a. 2.50 L b. 2.00 L c. 250,000 L d. 0.250 L 2. The density of platinum metal is 21.4 g/cm3 . If you have a piece of platinum with mass of 11.23 g, what is its volume in cubic centimeters? a. 240. cm3 b. 0.525 cm3 c. 24.0 cm3 d. 1.91 cm3 3. The number of significant figures in the number 0.002354 is a. 4 b. 2 c. 3 d. 6 4. The number of significant figures in the number 1.03 x 10-3 is a. 4 b. 2 c. 3 d. 1 5. If you solve the expression (2.34 + 0.567 + 63.2 = ?), the answer is a. 66 b. 66.1 c. 66.10 d. 66.107 6. What is the answer to the following expression in the correct number of significant figures? 0.0821 0.0230 298.0 1.50 a. 0.37514227 b. 0.375 c. 0.4 d. 0.38 7. Fourteen carat gold is a mixture of gold and other metals, with gold present to the extent of 58.3%. If you have a 14-carat gold ring with a mass of 5.63 g, the mass of gold present is a. 4.80 g b. 3.28 g c. 2.35 g d. 0.305 g 8. What is the most correct name for P4O10 a. b. c. d. phosphorus oxide phosphorus (IV) oxide tetraphosphorus decoxide phosphate oxide e. quadraphosphorus decaoxide 9. You have a jar of chunky peanut butter. Is this a homogeneous or heterogeneous mixture? a. heterogeneous b. homogeneous 10. Which of the following is an alkali metal? a. Sr b. Al c. K d. Kr 11. How many grams are there in 1.50 moles of sulfur? a. 21.4 g b. 64.2 g c. 32.1 g d. 48.1 g AP Chemistry Please place your answers on the answer document provided. 12. How many moles are there in 16.0 g of aluminum? a. 0.593 mole b. 1.69 moles c. 432 moles d. 16.0 moles 13. What is the correct formula for a compound formed from the most common ions of aluminum and sulfur? a. Al3S2 b. AlS c. Al3S3 d. Al2S3 14. What is the correct name for Al2(SO4)3? a. argon sulfate b. aluminum sulfite c. aluminum sulfate d. aluminum sulfide 15. The molar mass of hydrazine, N2H4, is a. 32.05 g/mol b. 16.03 g/mol c. 28.00 g/mol d. 4.08 g/mol 16. What is the most correct name for H2SO4 A. hydrogen sulfate D. dihydrogen sulfate B. hydrosulfuric acid E. sulfurous acid C. sulfuric acid 17. How many moles are contained in 15.6g of NH4Cl? a. 0.309 mol b. 3.43 mol c. 834 g/mol d. 0.292 mol 18. What is the weight percent of carbon in oxalic acid, H2C2O4? a. 13.34% b. 71.08% c. 26.68% d. 2.24% 19. Cyclohexylbenzene has the empirical formula C3H4. Its molar mass is 160.3 grams/mol. Its molecular formula is a. C3H4 b. C6H8 c. C9H12 d. C12H16 20. Maleic acid, which is used to manufacture artificial resins, has the empirical formula CHO. Its molar mass is 116.1 g/mol. What is its molecular formula? a. CHO b. C2H2O2 c. C3H3O3 d. C4H4O4 21. Nitrogen and oxygen form an extensive series of at least seven oxides with the general formula N x O y . One of them is a blue solid that comes apart, reversibly, in the gas phase. It contains 36.84% N. What is the empirical formula of the oxide? a. N2O b. NO c. N2O3 d. NO2 AP Chemistry Please place your answers on the answer document provided. Questions 22 27: Match the ions below with their names. Name Formulas 22. Sulfate a. NO3- 23. Acetate b. HCO3c. NH4+1 24. Nitrate 25. Hydrogen carbonate 26. Phosphate 27. Bicarbonate e. SO42f. NO21g. SO32h. PO43- d. CH3COO- 28. A student determines that the molar mass of an unknown compound is 128.40 g/mol. If the accepted value is 123.87 g/mol, which expression correctly shows the calculations needed to determine the percent error? (A) 128.40 - 123.87 (B) 128.40 x 123.87 (C) 128.40 123.87 (D) 128.40 - 123.87 128.40 (E) 123.87 - 128.40 123.87 Questions 52 55: Match the correct name with the formula at the right. 29. 30. 31. 32. potassium permanganate sodium hydrogen carbonate potassium dichromate sodium bicarbonate a. b. c. d. NaOCl K2CrO4 K2MnO4 NaHCO3 e. Na2CO3 f. PMnO4 g. K2Cr2O7 h. KMnO4 33. Which of the following quantum numbers indicates the orientation? a. spin b. angular momentum c. magnetic d. principle 34. In naming binary covalent compounds, what prefix would be utilized to indicate 7 atoms? a. septab. hexac. heptad. pentae. deca35. What is the correct chemical formula and charge for the permanganate ion a. MgO41- b. MnO31- c. MnO42- d. MnO41- e. MnO43- AP Chemistry Please place your answers on the answer document provided. 36. Aluminum reacts with oxygen to give aluminum oxide. If you have 6.0 moles of Al, a. you need 3.0 moles of O2 for complete reaction and produce 2.0 moles of Al2O3 b. you need 18.0 moles of O2 for complete reaction and produce 2.0 moles of Al2O3 c. you need 3.0 moles of O2 for complete reaction and produce 2.0 moles of Al2O3 d. you need 4.5 moles of O2 for complete reaction and produce 3.0 moles of Al2O3 e. you need 6.0 moles of O2 for complete reaction and produce 6.0 moles of Al2O3 37. Which of the following represent a homogeneous mixture? a. Italian dressing b. brass c. raisin pudding d. cement e. granite 38. In the balanced molecular equation for the neutralization of sodium hydroxide with sulfuric acid, the products are: a. b. c. d. e. NaSO4 + H2O NaSO3 + 2 H2O 2NaSO4 + H2O Na2S + 2 H2O Na2SO4 + 2 H2O 39. In a certain experiment 20.0g of HBr and 20.0g of Ca(OH)2 are allowed to react. How many grams of water form? a. (20/81) (2/2) (18) g b. (20/74) (2/2) (18) g c. (20/81) (2/1) (18) g d. (20/74) (2/1) (18) g e. (20/74) (1/2) (18) g 40. In the reaction: 3 Mg + 2FeCl3 → 2Fe + 3MgCl2, how many moles of Iron III chloride are produced when using 6.75 moles of Magnesium? a. 4.50 mol b. 6.75 mol c. 13.50 mol d. 3.38 mol e. 5.45 mol 41. What is the maximum number of electrons that can occupy the 5f sublevel? a. 2 b. 5 c. 10 d. 14 e. 18 42. What is the maximum number of orbitals in a 4d sublevel? a. 2 b. 5 c. 10 d. 14 e. 18 43. How many electrons in the ground state of a copper atom have quantum numbers n=3 and l=2? a. 2 b. 6 c. 8 d. 10 e. 18 AP Chemistry Please place your answers on the answer document provided. 44. Which set of quantum numbers is not allowed? a. 2, 2, 1, ½ b. 3, 2, 0, ½ c. 4, 3, -3, ½ d. 5, 4, 4, ½ e. 6, 2, -1, ½ 45. Which is the correct ground state electron configuration for the Ag atom? a. [Kr] 4d10 5s1 b [Kr] 4d9 5s2 c. [Kr] 4d8 5s2 d. [Ar] 3d10 4s1 e. [Ar] 3d9 5s2 46. The maximum number of electrons in an atom that can have quantum numbers n=4, l=2 is: a. 2 b. 6 c. 8 d. 10 e. 14 47. ___CuFeS2 + ___O2 → ___Cu2S + ___FeO + ___SO2 When the half-reaction above is balanced, what is the coefficient for O2 if all the coefficients are reduced to the lowest whole number? a. 2 b. 3 c. 4 d. 6 e. 8 48. If C4H10O undergoes complete combustion, what are the coefficients when the equation is completed and balanced? a. 2, 5, 7, 5 b. 1, 6, 4, 5 c. 2, 4, 4, 5 d. 1, 5, 4, 9 e. 4, 12, 8, 10 49. In the reaction: 3 Mg + 2FeCl3 → 2Fe + 3MgCl2, how many moles of Iron III chloride are produced when using 6.75 moles of Magnesium? a. 4.50 mol b. 6.75 mol c. 13.50 mol d. 3.38 mol e. 5.45 mol 50. In the lab, Percent yield of Copper, what device did you use as a safety precaution for the dangerous fumes produced in the reaction? a. fan b. mask c. gloves d. fume hood