Download 3640–3610  s sh O–H stretch, free hydroxyl 

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Frequency (cm‐1)
Str
Sh/B
3640–3610 3500–3200 (s,b) 3400–3250 (m) 3300–2500 3330–3270 (n, s) 3100–3000 3100–3000
3000–2850 2830–2695 2260–2210 (v) 2260–2100 (w) 1760–1665 1760–1690
1750–1735
1740–1720 1730–1715 1715‐1665
1710–1665 1680–1640 1650–1580 1600–1585 1550–1475 1500–1400 1500–1400
1470–1450 1370–1350 1360–1290 1335–1250 1320–1000 1300–1150 1300–1150 1250–1020 1000–650 950–910 910–665 900–675 850–550 725–720
700–610 690–515 s
s
m
m
sh
b
sh
sh
s
m
m
m
s
s
s
s
s
s
s
m
m
m
s
m
m
m
m
s
s
m
m
m
s
m
s
s
m
m
s
m
b
b
Functional Group
O–H stretch, free hydroxyl O–H stretch, H–bonded N–H stretch O–H stretch –C(triple bond)C–H: C–H stretch C–H stretch =C–H stretch C–H stretch H–C=O: C–H stretch C(triple bond)N stretch –C(triple bond)C– stretch C=O stretch C=O stretch C=O stretch C=O stretch C=O stretch C=O stretch C=O stretch –C=C– stretch N–H bend C–C stretch (in–ring) N–O asymmetric stretch C–C st
C–C
stretch
retch (in–ring)
(in–ring) C–H bend C–H rock N–O symmetric stretch C–N stretch C–O stretch C–H wag (–CH2X) C–H wag (–CH2X) C–N stretch =C–H bend O–H bend N–H wag C–H "oop" C–Cl stretch C–H rock –C(triple bond)C–H: C–H bend C–Halide stretch Typical Compound
alcohols, phenols
alcohols, phenols
primary, secondary amines, amides
carboxylic acids
alkynes (terminal)
aromatics
alkenes
alkanes
aldehydes
nitriles
alkynes
carbonyls (general)
carboxylic acids
esters, saturated aliphatic
aldehydes, saturated aliphatic
alpha,beta–unsaturated esters
ketones, saturated aliphatic
alpha,beta–unsat. aldehydes, ketones
alkenes
primary amines
aromatics
nitro compounds
aromatics
aromatics
alkanes
alkanes
nitro compounds
aromatic amines
alcohols, carb. acids, esters, ethers
alkyl halides
alkyl halides
aliphatic amines
alkenes
carboxylic acids
primary, secondary amines
aromatics
alkyl halides
alkanes
alkynes
alkyl halides
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