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Papers Chen: New Nano-materials for H storage: The role of theory Landry : A future direction for Solar Energy Conversion: Quantum Dot Solar Cells Barbour :CO2 sequestration: Design and Utilization of nano-clusters Phys. 555/342:Kittell Ch 10 Plasmons, Polaritons, Polarons, and Excitons Chapter 10 in Kittell: Be carefull he uses CGS To map onto SI replace 4π with 1/ε0 We will discuss ε(ω,K)--energy and wavelength dependent ε(ω,0)---describes collective excitation: Plasmons, etc. ε(ω,K)---describes electrostatic screening, e-e, e-P, eimpurity D-displacement D = E + 4"P = #E E-field P-polarization ! " • D = " • #E = 4$% ext " • E = 4$% = 4$( % ext + % ind ) Phys. 555/342:Kittell Ch 10 Dielectric Function for Electron Gas Plasma Optics "(#,k) $ "(#,o) % "(# ) & $' with d2x m 2 = "eE dt ! 2 "# mx = "eE ! x " e i#t E " e i#t eE x= 2 " m ! "ex = "e 2 E /# 2 m 2 ne P =!"nex = " 2 E # m Dipole moment ! ! Phys. 555/342:Kittell Ch 10 Dielectric Function for Electron Gas Plasma Optics ne 2 P = "nex = " 2 E # m D(# ) P(# ) "(# ) = $ 1+ 4% E(# ) E(# ) 4$ne 2 "(# ) = 1+ m# 2 ! Plasma Frequency 2 4#ne " 2p = m # 2p "(# ) = 1+ 2 # ! ω=ωp when ε=0 Phys. 555/342:Kittell Ch 10 Dielectric Function for Electron Gas Plasma Optics But the positive background also has a dielectric constant labeled "(#) 2* ' ˜ # 4&ne p "(# ) = "($) % = " ($) 1+ ) 2 2, m# ( # + 2 ! 2 4#ne "˜ = m$(%) 2 p ! Again--- ! "˜ p = " #=0 Phys. 555/342:Kittell Ch 10 Dielectric Function for Electron Gas Dispersion EM wave equation " 2D 2 2 = c #E 2 "t and " "D = #($,K)E But " "E # e 2 2 2 "(#,K)# = c K i(K •r"$t ) ! • ε real and >0: For ω real, K is real and a transverse EM wave propagates with phase velocity c/ε1/2 • ε real and <0: For ω real, K is imaginary and the wave is damped with a characteristic length 1/|K| • ε is complex: For ω real, K is complex and the waves are damped in space. • ε is infinity: This means the system has a finite response in the absence of an applied force; thus the poles of ε(ω,K) define the frequesncies of the free oscillations of the medium. • ε=0: We shall see that longitudinally polarized waves are possible only at the zeros. ! ! Phys. 555/342:Kittell Ch 10 Transverse Optical Modes in a Plasma 2 2 "(#,K)# = c K For " "# < #˜ p For " "# > #˜ p ! 2 2 2 2 2 2 ˜ "(# )# = "($)(# % # p ) = c K K2 <0 so K is imaginary K2 >0 so K is real E "e #|K |x " 2 = "˜ 2p + c 2K 2 /#($) ! This describes a transverse electromagnetic wave in a plasma. ! Phys. 555/342:Kittell Ch 10 Plasmons Phys. 555/342:Kittell Ch 10 Transparency of Alkalki Metals in the Ultraviolet Metal should reflect below the plasma frequency Metals should transmit above the plasma frequency The Reflectance of Indium Antimonide with n=4x1018 cm-1 Phys. 555/342:Kittell Ch 10 Longitudinal Plasma Oscillations Zeros of dielectric function determine the frequency of the longitudinal modes of oscillation. "(# L ) = 0 2 #p "(# L ) = 1$ 2 = 0 # ! There is a free longitudinal oscillation mode (fig) of an electron gas at the plasma frequency. This is the low frequency cut off of the transfer mode ! Phys. 555/342:Kittell Ch 10 Plasma Oscillations A plasm oscillation is a collective longitudinal excitation of the conduction electrons. A plasmon is a quantum of plasm oscillations. Phys. 555/342:Kittell Ch 10 Plasmons Phys. 555/342:Kittell Ch 10 Kittell Problem 10.1 Phys. 555/342:Kittell Ch 10 Solution 10.1 ∂ϕ = kA sin kx e kz , and at the boundary this is equal to Exi. The normal ∂x component of D at the boundary, but outside the medium, is ( )kA cos kx, where for a plasma ( ) = 1 – p2/ 2. The boundary condition is –kA cos kx = ( )kA cos kx, or ( ) = –1, or p2 = 2 2. This frequency ω = ωp 2 is that of a surface plasmon. 1. E x0 = − Phys. 555/342:Kittell Ch 10 Kittell: Problem 10,2 Phys. 555/342:Kittell Ch 10 Kittell, solution 10.2 2. A solution below the interface is of the form ϕ(−) = A cos kx e kz , and above the interface ϕ(+ ) = A cos kx e − kz , just as for Prob. (1). The condition that the normal component of D be continuous across the interface reduces to 1( ) = – 2( ), or 1− ω2p1 ω2 = −1 + ω2p2 ω2 , so that ω2 = 1 2 (ωp1 + ω2p2 ) . 2 Phys. 555/342:Kittell Ch 10 Kittell, Problem 10.5 Phys. 555/342:Kittell Ch 10 Kittell, solution 10.5 5. md 2r/dt 2 = ! m"2r = !eE = 4#eP/3 = !4#ne 2r/3 . Thus "2$ = 4#ne 2 3m. Phys. 555/342:Kittell Ch 10