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Household Water Treatment and Safe Storage Factsheet: Chemical Coagulants The Treatment Process Potential Treatment Capacity Very Effective For: Somewhat Effective For: Not Effective For: Turbidity Dissolved chemicals Bacteria Viruses Protozoa Helminths Hardness Taste, odour, colour What are Chemical Coagulants? The sedimentation process can be quickened by adding coagulants to the water. Chemical coagulants are commonly used in community drinking water treatment systems though some application in household water treatment occurs. The main chemicals used for coagulation are aluminium sulphate (alum), polyaluminium chloride (also known as PAC or liquid alum), alum potash, and iron salts (ferric sulphate or ferric chloride). Lime (Ca(OH 2 )), lime soda ash (Na 2 CO 3 ) and caustic soda (NaOH) are sometimes used to "soften" water, usually ground water, by precipitating calcium, magnesium, iron, manganese and other minerals that contribute to hardness. then accumulate (flocculation) to form larger particles (flocs) which settle faster. The flocs can then be settled out or removed by filtration. Some bacteria and viruses can also attach themselves to the suspended particles in water that cause turbidity. Therefore, reducing turbidity levels through coagulation may also improve the microbiological quality of water. Operation Users follow the manufacturer’s instructions and add the prepared dose of coagulant to the water. The water is then stirred for a few minutes to help create flocs. The flocs can be settled out or removed by filtration. How Does it Remove Contamination? Particles that cause turbidity (e.g. silt, clay) are generally negatively charged, making it difficult for them to clump together because of electrostatic repulsion. But coagulant particles are positively charged, and they chemically attracted to the negative turbidity particles, neutralizing the latter’s negative charge. With mixing the neutralized particles Alum block (Credit: www.cdc.org) Household Water Treatment and Safe Storage Fact Sheet: Chemical Coagulants Key Data Inlet Water Quality No specific limits Treatment Efficiency Bacteria Laboratory 1 >90 to >99% Viruses Protozoa Helminths Turbidity >90 to >99%1 >90 to >99%1 >90 to >99%1 Not available Not available Not available Not available Not available 2 < 90% 3 95% Field 1 Sproul (1974), Leong (1982), Payment and Armon (1989) cited in Sobsey (2002) Ongerth (1990) cited in Sobsey (2002) 3 Wrigley (2007) 2 Maximum effectiveness requires careful control of coagulant dose, pH and consideration of the quality of the water being treated, as well as mixing Effectiveness of chemical coagulants varies from one to another Operating Criteria Flow Rate Batch Volume Daily Water Supply Not applicable Unlimited Unlimited Need to follow manufacturer’s instructions Robustness Difficult to optimize without training and equipment Requires coagulant supply chain and regular purchase Estimated Lifespan 6 months in liquid form and 1 year in solid form Manufacturing Requirements Worldwide Producers: Many producers around the world Local Production: Most chemical products are difficult and complex to manufacture and local production is not feasible Maintenance Chemicals should be stored in a dry location and away from children Direct Cost Capital Cost Operating Cost US$0 US$9-91/year 1 Replacement Cost US$0 Note: Program, transportation and education costs are not included. Costs will vary depending on location. 1 Sobsey (2002). Assumed 25 litres/household/day. Household Water Treatment and Safe Storage Fact Sheet: Chemical Coagulants Key Data Other Jar testing can be undertaken to optimize effectiveness of particular coagulants with water sources References Sobsey M. (2002). Managing Water in the Home: Accelerated Health Gains From Improved Water Supply, Water, Sanitation and Health, Department of Protection of the Human Environment, World Health Organization, Geneva, Switzerland. Wrigley. T. (2007) Microbial Counts and Pesticide Concentrations in Drinking Water After Alum Flocculation of Channel Feed Water at the Household Level, in Vinh Long Province, Vietnam, Journal of Water and Health; 05:1. CAWST (Centre for Affordable Water and Sanitation Technology) Wellness through Water.... Empowering People Globally Calgary, Alberta, Canada Website: www.cawst.org Email: [email protected] Last Update: October 2009