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Weathering of Rocks Why we see weathering 1. Most minerals are not stable at the Earth’s surface 2. The Earth wants to be flat – lowest energy state • Topography provides energy Weathering in the Rock Cycle Erosion + Deposition Igneous Sedimentary Melting Metamorphic Three Dynamic Processes of Breaking and Removing rock 1. Weathering - the disintegration and decomposition of rock at or near the surface 2. Erosion 3. Mass wasting Types of Weathering Mechanical – physical breakdown of rocks. Chemical – decomposition of rocks by chemical reactions. Mechanical Weathering Mechanical weathering breaks down rocks/minerals Smaller particles increases the amount of exposed surface area Does not change the chemical composition of the minerals\ Mechanical Weathering - making smaller pieces Mechanical Weathering 1. 2. 3. 4. 5. Frost Wedging Salt Wedging Biological Wedging Unloading Thermal Expansion Types of Mechanical Weathering Frost wedging – water penetrates into cracks, expands when it freezes. Must have: • Adequate moisture • Cracks in rocks • Freeze/thaw cycles Frost Wedging Types of Mechanical Weathering Salt wedging – growth of minerals in cracks • Desert environments • Water evaporates, ions in solution combine to form minerals Salt Wedging Types of Mechanical Weathering Biological wedging – plant roots penetrate into cracks causing cracks to widen. Must have: • Climate hospitable for plants. • Adequate moisture and temperature. Biological Wedging Unloading Exfoliation Domes Removal of overlying material allows rock to expands Top layers expand more than deeper layers Causes sheeting or exfoliation Unloading Sheeting Sheeting Thermal Expansion 1. repeated daily heating and cooling of rock; ex. Desert environments 2. heat causes expansion; cooling causes contraction. Chemical Weathering • Chemical alteration of minerals. • Results in new minerals and ions in solution. • Water and acid are essential. Types of Chemical Weathering 1. Hydrolysis - any reaction in which water participates. a) Ion exchange – H+ replaces other cations. b) Dissolution - mineral completely dissolves, leaving only ions in solution. c) Oxidation - reaction in which elements gain or lose electrons (example: rust). Acid Hydrolysis - Dissolution Carbon Dioxide + Rain H2O + CO2 H2CO3 Becomes Acid CaCO3 + H2CO3 Ca2+ + 2HCO3- Dissolves Minerals (i.e. carbonates such as calcite) Carries away---Ions Acid Hydrolysis & Secondary Minerals Carbon Dioxide + Rain Becomes Acid Dissolves Minerals (i.e. silicates) Leaves ----Clay Carries away---Ions Silica Dissolution Minerals dissolve in water For example: salts Oxidation 1. Iron silicate dissolves 2. Iron oxidizes 3. Oxidized iron combines with water 4. Leaves iron oxide Weathering Products Regolith – a loose layer of broken rock and mineral fragments. Sediments Dissolved Ions Products of Weathering Mineral Residual Products Material in Solution Quartz quartz grains silica Feldspar clay minerals silica, K +, Na+, Ca2+ Amphibole (hornblende) clay minerals, limonite, hematite silica, Mg2+, Ca2+ Olivine limonite, hematite silica, Mg2+ Factors influencing Weathering Rates 1. Rock structures – chemical/mineral composition, physical features 2. Topography 3. Climate 4. Vegetation 5. Time Climate and Weathering Benefits of Weathering • Creates soil • Produces clay, sand, and gravel • Produces minerals Soils Terminology Regolith – blanket of loose, weathered rock debris covering unweathered bedrock. Soil – uppermost part of regolith. Rock particles, new minerals, organics How soil differs from regolith: 1. More chemical weathering in soil. 2. Soil has structure (layers called soil horizons). 3. Soil retains nutrients and moisture, essential for abundant plant growth. More Terminology Soil profile – sequence of soil horizons. Soil horizon – layer within a soil profile that has distinct characteristics. Composition, color, texture Soil Horizons A horizon • Zone of leaching (lots of chemical weathering) • Organic rich, often dark in color • Decaying organic matter releases nutrients B horizon • Zone of accumulation – minerals (clay and iron oxide) are washed down from above. • High clay content, reddish color from iron. • Able to retain moisture because of clay content C horizon Parent material – grading from weathered to unweathered. Parent material can be: 1. Bedrock 2. Stream sediments 3. Volcanic ash Controls of Soil Formation 1. Parent Material 2. Time 3. Climate 4. Plants and Animals 5. Slope