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Counting by weighing • Calculate the amount of pennies in the cup by weighing them. You may take 10 pennies out of the cup to weigh them, but do not count what is in the cup • Atoms are too small to count so we weigh an amount (mole) and calculate the number Some words mean numbers • Pair • Dozen • Baker’s dozen • Gross • Ream Mole 1 mole = 6.02 x 1023 representative particles ( the number of carbon-12 atoms in 12.00 g obtained by counting by weighing) Atom, Molecule and Ions • Representative particles – smallest particle of that substance Substance Representative Particle element molecular compound (covalent bond) ionic compound atom molecule formula unit Practice: 1. Determine the number of FU in .866 moles of AgNO3? 2. Find the molecules in 0.98 moles of Cl2 3. Determine the moles in 7.83 x 1017 atoms of Fe Molar Mass (counting by weighing mass) Mass of 1 mole of a substance Element atomic mass in g Compound add up all the atomic masses for the atoms in the substance all Calculate the Molar mass • Ca • H2 • KNO3 • (NH4)2S Remember 1 mole = 6.02 x 1023 r.p. 1 mole = molar mass(g) Try these: • Calculate the • Calculate the Fe(OH)3 • Calculate the • Calculate the of CO moles of 1.2 g H2 moles of 5.6 x 1025 f.u. grams of 6.7 moles SO3 molecules of 4.0 moles Molar Volume The volume of 1mole of a gas at standartd temperature – 0oC standard pressure – 1 atmosphere (pressure at sea level) 1 mole gas at STP = 22.4 L Remember 1 mole = 6.02 x 1023 r.p. 1 mole = molar mass(g) 1 mole = 22.4 L gas Multistep problems • How many atoms on 47.8L of Ar? • How many fu in 18.9 g NaCl? • How many g in 4.5 x 1013 atoms K? Percent Composition % element = g element x 100% g total Formulas • Empirical simplest whole number ratio • Molecular Formula actaul number of atoms in the formula Empirical formula Get moles • Use moles as subscripts • Divide by common factor (usually smallest number) • Get whole number Practice: A compound has 13.5 g Ca 10.8 g O .675 g H What is its empirical formula? Molecular formula Set up table: Empirical Molecular Molar Mass formula Reactions of an Iron Nail • Do steps 1,2,3,4,5 • Return to class • Do steps6,7,8,9,10,11 Chemical Measurements • Atomic Mass The weighted average of all the mass numbers for all the isotopes of the atom (a.m.u.) • Formula Mass The sum of all the atomic masses for all atoms in the compound. (a.m.u.) Calculate the atomic mass or formula masses • Na 22.99 amu • Cl 35.45 amu • Br2 159.80 amu • NaCl 58.45 amu • H2O • Mg(OH)2 18.02 amu 58.33 amu Molar mass element The mass of 1 mole = atomic mass (g) What is the mass of 1 mole of He? Pb? Cl? Molar Mass = = = The mass of 1 mole ( 6.02 x 1023) of representative particles The atomic mass in g The formula mass in g