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Factors affecting metallic bond strength
Metallic crystal structures
Factors affecting metallic bond strength:
1. Atomic (metallic) radius
2. No. of valence electrons
Decrease
Increase
Na
371K
K
336K
Rb
312K
Mg
922K
Al
933K
Melting
Point (K)
Open Structure
(1 Type)
Close-packed
Structure
(2 types)
Open Structure:
Body-centered
cubic
Co-ordination
number: 8
Number of atom
in a unit cell:
1 + 8 ( 1/8)
= 2
Unit Cell
Open Structure:
Body-centered
cubic
Examples:
Close-Packed Structure:
Hexagonal
close-packed
abababab…..
Co-ordination
number: 12
(6 in its own layer, 3
in the layer above
and 3 below.)
hexagonal
Close-Packed Structure:
Hexagonal
close-packed
Example:
Close-Packed Structure:
Cubic
close-packed
abcabcab…..
Co-ordination
number: 12
(6 in its own layer, 3
in the layer above
and 3 below.)
also called face-centered cubic
Close-Packed Structure:
Cubic
close-packed
Examples:
Tetrahedral hole
Octahedral hole
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