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Logarithms Logarithms The logarithm of a number is the number of times 10 must be multiplied by itself to equal that number. Logarithms 1000 = 10 x 10 x 10 log 1000 = 3 Logarithms To find the logarithm of a number, count the zeroes. If the number is in scientific notation, look at the exponent. Logarithms 1 = 1 x 100 1 10 = 1 x 10 2 100 = 1 x 10 0.1 = 1 x 10-1 0.01 = 1 x 10-2 log 1 = 0 log 10 = 1 log 100 = 2 log 0.1 = -1 log 0.01 = -2 Logarithms You can multiply two numbers by adding their logarithms. Logarithms You can multiply two numbers by adding their logarithms. 100 x 1000 = 100,000 Logarithms You can multiply two numbers by adding their logarithms. 100 x 1000 = 100,000 2+3=5 Logarithms You can multiply two numbers by adding their logarithms. 1x 8 10 = 100,000,000 Logarithms You can multiply two numbers by adding their logarithms. 1x 8 10 = 100,000,000 0+8=8 Logarithms You can multiply two numbers by adding their logarithms. 2x 8 10 = 200,000,000 ?+8= ? Logarithms So what’s the logarithm of 2? You have to look it up. 2x 8 10 = 200,000,000 ?+8= ? Logarithms So what’s the logarithm of 2? You have to look it up. 8 10 2x = 200,000,000 0.301 + 8 = 8.301 Logarithms What if the number is small instead of big? Logarithms What if the number is small instead of big? 0.0003 = 3 x 10-4 Logarithms What if the number is small instead of big? 0.0003 = 3 x 10-4 log 0.0003 = log 3 + log 10-4 Logarithms What if the number is small instead of big? 0.0003 = 3 x 10-4 log 0.0003 = log 3 + log 10-4 = 0.477 – 4 Logarithms What if the number is small instead of big? 0.0003 = 3 x 10-4 log 0.0003 = log 3 + log 10-4 = 0.477 – 4 = -3.523 Logarithms Try a few! Logarithms log 3 10 = Logarithms log 3 10 =3 Logarithms log 8 10 = Logarithms log 8 10 =8 Logarithms log -10 10 = Logarithms log -10 10 = -10 Logarithms log 2 = Logarithms log 2 = 0.301 Logarithms log 5.8 = Logarithms log 5.8 = 0.763 Logarithms log 9.2 = Logarithms log 9.2 = 0.963 Logarithms log 4 x 12 10 = Logarithms log 4 x 12 10 = 0.602 + 12 Logarithms log 4 x 12 10 = 0.602 + 12 = 12.602 Logarithms log 8.3 x 5 10 = Logarithms log 8.3 x 5 10 = 0.919 + 5 Logarithms log 8.3 x 5 10 = 0.919 + 5 = 5.919 Logarithms log 7.1 x -3 10 = Logarithms log 7.1 x -3 10 = 0.851 - 3 Logarithms log 7.1 x -3 10 = 0.851 - 3 = -2.149 Logarithms log 4.8 x -11 10 = Logarithms log 4.8 x -11 10 = 0.681- 11 Logarithms log 4.8 x -11 10 = 0.681- 11 = -10.319 pH pH = -log + [H ] [OH ] pOH = -log pH + pOH = 14 + [H ] = 0.0035 What is the pH? + [H ] = 0.0035 0.0035 = 3.5 x -3 10 + [H ] = 0.0035 -3 10 0.0035 = 3.5 x -3 log 0.0035 = log 3.5 + log 10 + [H ] = 0.0035 -3 10 0.0035 = 3.5 x -3 log 0.0035 = log 3.5 + log 10 = 0.544 – 3 + [H ] = 0.0035 -3 10 0.0035 = 3.5 x -3 log 0.0035 = log 3.5 + log 10 = 0.544 – 3 = –2.456 + [H ] = 0.0035 -3 10 0.0035 = 3.5 x -3 log 0.0035 = log 3.5 + log 10 = 0.544 – 3 = –2.456 pH = 2.456 pH = 6.13 What is the + [H ]? pH = 6.13 –pH = –6.13 pH = 6.13 –pH = –6.13 = 0.87 – 7 pH = 6.13 –pH = –6.13 = 0.87 – 7 + -7 [H ] = 7.4 x 10 pH = 8.7 What is the pOH? pH = 8.7 pOH = 14 - pH pH = 8.7 pOH = 14 - pH = 14 – 8.7 pH = 8.7 pOH = 14 - pH = 14 – 8.7 = 5.3 pH = 8.7 pOH = 14 - pH = 14 – 8.7 = 5.3 The solution is acidic. Always Remember: Always Remember: The molarity of a solution refers to how many moles per liter it has. Always Remember: The molarity of a solution refers to how many moles per liter it has. 1.0 M = 1.0 mol/L Always Remember: A strong acid or base dissociates completely in water. Always Remember: A strong acid or base dissociates completely in water. 1.0 M HCl = 1.0 M + H Always Remember: A strong acid or base dissociates completely in water. + H 1.0 M HCl = 1.0 M 1.0 M NaOH = 1.0 M OH Always Remember: Polyprotic acids have more than one hydrogen. Always Remember: Polyprotic acids have more than one hydrogen. 1.0 M H2SO4 = 2.0 M + H . Suggested Homework Page 609 # 18 Page 611 # 19 Page 612 # 20 Daily Quiz – pH and logarithms Daily Quiz – pH and logarithms 1. What is true of [H+] and [OH-]? a. = b. [H+] x [OH-] = 1 x 10-7 + -7 c. [H ] ÷ [OH ] = 1 x 10 d. [H+] x [OH-] = 1 x 10-14 + -14 e. [H ] ÷ [OH ] = 1 x 10 + [H ] [OH ] Daily Quiz – pH and logarithms 2. In a neutral solution, pH = a. 0 b. 0.5 c. 1 d. 7 e. 14 Daily Quiz – pH and logarithms 3. 1 x a. b. c. d. -5 10 =? 5 100,000 0.000,01 0.000,001 Daily Quiz – pH and logarithms 4. Which number is bigger? a. 1 x 10-2 -6 b. 1 x 10 Daily Quiz [H+], [OH-], and pH 1. You have a 1.0M solution of HI (a strong acid). What is the pH? a. 0.0 b. 1.0 c. 10.0 d. 13.0 Daily Quiz [H+] & [OH-] to pH 2. You have a 1.0M solution of HNO3 (a strong acid). What is the pH? a. 0.7 b. 1.3 c. 2.0 d. 5.0 Daily Quiz [H+], [OH-], and pH 3. You have a 1.0M solution of KOH (a strong base). What is the pH? a. 0.0 b. 1.0 c. 7.0 d. 14.0 Daily Quiz [H+], [OH-], and pH 4. You have a 10-5M solution of Mg(OH)2 (a strong base). What is the pH? a. 4.32 b. 4.62 c. 9.38 d. 9.68 Daily Quiz – pH and logarithms 1. What is true of [H+] and [OH-]? a. = b. [H+] x [OH-] = 1 x 10-7 + -7 c. [H ] ÷ [OH ] = 1 x 10 d. [H+] x [OH-] = 1 x 10-14 + -14 e. [H ] ÷ [OH ] = 1 x 10 + [H ] [OH ] Daily Quiz – pH and logarithms 1. What is true of [H+] and [OH-]? a. = b. [H+] x [OH-] = 1 x 10-7 + -7 c. [H ] ÷ [OH ] = 1 x 10 d. [H+] x [OH-] = 1 x 10-14 + -14 e. [H ] ÷ [OH ] = 1 x 10 + [H ] [OH ] Daily Quiz – pH and logarithms 2. In a neutral solution, pH = a. 0 b. 0.5 c. 1 d. 7 e. 14 Daily Quiz – pH and logarithms 2. In a neutral solution, pH = a. 0 b. 0.5 c. 1 d. 7 e. 14 Daily Quiz – pH and logarithms 3. 1 x a. b. c. d. -5 10 =? 5 100,000 0.000,01 0.000,001 Daily Quiz – pH and logarithms 3. 1 x a. b. c. d. -5 10 =? 5 100,000 0.000,01 0.000,001 Daily Quiz – pH and logarithms 4. Which number is bigger? a. 1 x 10-2 -6 b. 1 x 10 Daily Quiz – pH and logarithms 4. Which number is bigger? a. 1 x 10-2 -6 b. 1 x 10 Daily Quiz [H+], [OH-], and pH 1. You have a 1.0M solution of HI (a strong acid). What is the pH? a. 0.0 b. 1.0 c. 10.0 d. 13.0 Daily Quiz [H+], [OH-], and pH 1. You have a 1.0M solution of HI (a strong acid). What is the pH? a. 0.0 b. 1.0 c. 10.0 d. 13.0 Daily Quiz [H+], [OH-], and pH 1. You have a 1.0M solution of HI (a strong acid). What is the pH? a. 0.0 b. 1.0 c. 10.0 d. 13.0 Why? Daily Quiz [H+], [OH-], and pH 1.0M HI + 0 [H ] = 1.0 x 10 + log[H ] = 0.00 + 0 pH = 0.00 Daily Quiz [H+] & [OH-] to pH 2. You have a 1.0M solution of HNO3 (a strong acid). What is the pH? a. 0.7 b. 1.3 c. 2.0 d. 5.0 Daily Quiz [H+] & [OH-] to pH 2. You have a 1.0M solution of HNO3 (a strong acid). What is the pH? a. 0.7 b. 1.3 c. 2.0 d. 5.0 Daily Quiz [H+] & [OH-] to pH 2. You have a 1.0M solution of HNO3 (a strong acid). What is the pH? a. 0.7 b. 1.3 c. 2.0 d. 5.0 Why? Daily Quiz [H+], [OH-], and pH 0.050M HNO3 + -2 [H ] = 5.0 x 10 + log[H ] = 0.70 – 2 pH = 1.30 Daily Quiz [H+], [OH-], and pH 3. You have a 1.0M solution of KOH (a strong base). What is the pH? a. 0.0 b. 1.0 c. 7.0 d. 14.0 Daily Quiz [H+], [OH-], and pH 3. You have a 1.0M solution of KOH (a strong base). What is the pH? a. 0.0 b. 1.0 c. 7.0 d. 14.0 Daily Quiz [H+], [OH-], and pH 3. You have a 1.0M solution of KOH (a strong base). What is the pH? a. 0.0 b. 1.0 c. 7.0 d. 14.0 Why? Daily Quiz [H+], [OH-], and pH 1.0M KOH 0 [OH ] = 1.0 x 10 log[OH ] = 0.00 + 0 pOH = 0.00 pH = 14.00 Daily Quiz [H+], [OH-], and pH 4. You have a 10-5M solution of Mg(OH)2 (a strong base). What is the pH? a. 4.32 b. 4.62 c. 9.38 d. 9.68 Daily Quiz [H+], [OH-], and pH 4. You have a 10-5M solution of Mg(OH)2 (a strong base). What is the pH? a. 4.32 b. 4.62 c. 9.38 d. 9.68 Daily Quiz [H+], [OH-], and pH 4. You have a 10-5M solution of Mg(OH)2 (a strong base). What is the pH? a. 4.32 b. 4.62 c. 9.38 d. 9.68 Why? Daily Quiz [H+], [OH-], and pH -5 10 M 2.4 x Mg(OH)2 -5 [OH ] = (2.4 x 10 ) x 2 log[OH ] = 0.68 – 5 pOH = 4.32 pH = 9.68 . Suggested Homework Page 609 # 18 Page 611 # 19 Page 612 # 20 .