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For chemists, a mole is NOT a small furry animal. A mole is the SI unit for amount of substance. QuickTime™ and a TIFF (Uncompressed) decompressor are needed to see this picture. This is a dozen eggs that's an amount. QuickTime™ and a TIFF (Uncompressed) decompressor are needed to see this picture. A mole is like a dozen only MORE. One gram bar of gold. Today, gold is selling for $$$ per gram. One gram bar of gold. Actual Size 9 mm X 15 mm X 2 mm 3/ 3/ inch X 1/ in inch X 8 4 16 One gram bar of gold. 196.96655 of these bars would contain a MOLE of gold molecules. One gram bar of gold. 196.96655 of these bars would contain a MOLE of gold molecules. cm3 A mole is equal to 23 6.02 X 10 of anything. cm3 23 10 6.02 X is known as Avogadro's number. QuickTime™ and a TIFF (Uncompressed) decompressor are needed to see this picture. Avogadro's Hypothesis: equal volumes of gases at the same temperature and pressure contain equal numbers of molecules. He also proposed that oxygen gas and hydrogen gas were diatomic molecules. A mole of a substance is equal to its formula mass in grams. cm3 There are 23 6.02 X 10 molecules of water is this cylinder. cm3 There are 23 6.02 X 10 molecules of water is this cylinder. cm3 cm3 The formula mass of water is 18 amu. cm3 Water has a density of 3 1 g/cm . cm3 3 cm 18 of water has a mass of 18 grams. cm3 18 grams of water contains a mole of molecules. The mole concept is important because it allows us to actually WEIGH atoms and molecules in the lab. cm3 What is the mass of a water molecule? cm3 18 grams = 6.02 X 1023 H2O molecules 3 X 10-23 g / H2O molecule 2 Important Mole Calculations 1. Convert mass to moles and moles to molecules (particles). 2 Important Mole Calculations 2. Determine the concentration of solutions - Molarity. Most mole calculations use the Factor-Label method of problem solving - also called dimensional analysis. First: Write what you are given. Then: Multiply by fractions equal to one until all units cancel except what you are asked for. Finally: Punch buttons on the calculator to get the number. Qu ic kTi me™ a nd a TIFF (Unc om pres se d) de co mp re ss or are n ee de d to s ee th is pi ctu re . 1 Setting up the problem is as important as the answer. Qu ic kTi me™ a nd a TIFF (Unc om pres se d) de co mp re ss or are n ee de d to s ee th is pi ctu re . 2 Form the habit of working neatly, canceling units as you go, and circling the answer. Qu ic kTi me™ a nd a TIFF (Unc om pres se d) de co mp re ss or are n ee de d to s ee th is pi ctu re . 3 Remember, units are just as important as numbers in the answer... Qu ic kTi me™ a nd a TIFF (Unc om pres se d) de co mp re ss or are n ee de d to s ee th is pi ctu re . 3 when the units are right, the answer will be right. Write these conversion factors on your Paper Periodic Table RIGHT NOW: 1 mole = 6.02 X 1023 = formula mass particles in grams atoms molecules Practice Problem #1: What is the mass in grams 15 of 2.2 X 10 molecules of K2S2O8? Write this problem, then put your pen DOWN until told to pick it up. To work this problem, you would: 2.2 X 1015 molecules K2S2O8 Write what is given. 2.2 X 1015 molecules K2S2O8 Draw these lines. 2.2 X 1015 molecules K2S2O8 What does this line mean? 2.2 X 1015 molecules K2S2O8 What does this line mean? 2.2 X 1015 molecules K2S2O8 What units go here? 2.2 X 1015 molecules K2S2O8 molecules Why? 2.2 X 1015 molecules K2S2O8 molecules What units go here? 2.2 X 1015 molecules K2S2O8 grams molecules Why? 2.2 X 1015 molecules K2S2O8 grams molecules Where do we get the numbers? Useful conversion factors: 1 mole = 6.02 X 1023 = formula mass particles in grams atoms molecules 2.2 X 1015 molecules K2S2O8 formula mass in grams = 6.02 X 1023 molecules K2S2O8 2.2 X 1015 molecules K2S2O8 formula mass in grams = 6.02 X 1023 molecules K2S2O8 These units cancel. 2.2 X 1015 molecules K2S2O8 K = 2 X 39 = 78 S = 2 X 32 = 64 O = 8 X 16 = 128 270 270 grams = 6.02 X 1023 molecules K2S2O8 Formula mass calculation. 2.2 X 1015 molecules K2S2O8 K = 2 X 39 = 78 S = 2 X 32 = 64 O = 8 X 16 = 128 270 270 grams 6.02 X 1023 molecules K2S2O8 These are the units are asked for. = 2.2 X 1015 molecules K2S2O8 K = 2 X 39 = 78 S = 2 X 32 = 64 O = 8 X 16 = 128 270 270 grams 6.02 X 1023 molecules K2S2O8 The problem is worked punch buttons to get the number. = 2.2 X 1015 molecules K2S2O8 K = 2 X 39 = 78 S = 2this X 32 = 64 number O = 8 X 16 = 128 270 270 grams 6.02 X 1023 molecules K2S2O8 = 2.2 X 1015 molecules K2S2O8 K = 2 X 39 = 78 number S =times 2 X 32 this = 64 O = 8 X 16 = 128 270 270 grams 6.02 X 1023 molecules K2S2O8 = 2.2 X 1015 molecules K2S2O8 270 grams 6.02 X 1023 K = 2 X 39 = 78 molecules S = 2 X 32 = 64 K2S2O8 O = 8 X 16 = 128 divided by270 this number = 2.2 X 1015 molecules K2S2O8 K = 2 X 39 = 78 S = 2 X 32 = 64 O = 8 X 16 = 128 EQUALS 270 270 grams 6.02 X 1023 molecules K2S2O8 -7 9.9 X 10 g K2S2O8 = 2.2 X 1015 molecules K2S2O8 270 grams = 6.02 X 1023 molecules have the right K2S2O8 K = 2 X 39 = 78 S = 2 X the 32 = answer 64 Does O = 8 X 16 = 128 number of270 significant digits? -7 9.9 X 10 g K2S2O8 2.2 X 1015 molecules K2S2O8 K = 2 X 39 = 78 S = 2 X 32 = 64 O = 8 X 16 = 128 270 NOW write this solution under the problem. 270 grams 6.02 X 1023 molecules K2S2O8 9.9 X 10 -7 g K2S2O8 = Practice Problem #2: A sample of CaCO3 has a mass of 25.5 grams. How many total atoms are in the sample? Write this problem down. Practice Problem #2: A sample of CaCO3 has a mass of 25.5 grams. How many total atoms are in the sample? First one with this answer gets 20 points added to their lowest test grade. 7.68 X 1023 atoms 25.5 g CaCO3 7.68 X 1023 atoms 25.5 g CaCO3 6.02 X 1023 molecules 100 g CaCO3 Ca = 1 X 40 = 40 C = 1 X 12 = 12 O = 3 X 16 = 48 100 7.68 X 1023 atoms 25.5 g CaCO3 6.02 X 1023 molecules 5 atoms 100 g CaCO3 Ca = 1 X 40 = 40 C = 1 X 12 = 12 O = 3 X 16 = 48 100 1 molecule 7.68 X 1023 atoms Practice Problem #3: Given 100 grams of silver nitrate, how many atoms of silver are 4 X 1023 in the sample? atoms Ag Set up the factor-label solution for this problem. 100 g AgNO3 6.02 X 1023 molecules AgNO3 170 g AgNO3 Ag = 1 X 108 = 108 N = 1 X 14 = 14 O = 3 X 16 = 48 170 1 atom Ag 1 molecule AgNO3 4 X 1023 atoms Ag Practice Problem #4: Calculate the mass, in kilograms, of 0.55 mole of chlorine 0.039 kg Cl2 molecules. Set up the factor-label solution for this problem. 0.55 mole Cl2 70 g Cl2 1 kg 1 mole Cl2 1000 g Cl = 2 X 35 = 70 0.039 kg Cl2 Practice Problem #5: The density of C2H5OH is 0.8 g/cm3. If a sample of this substance contains 3.2 X 1023 molecules, what is the 31 cm3 volume of the sample? C2H5OH Set up the factor-label solution for this problem. 3.2 X 1023 molecules 46 g C2H5OH C2H5OH C - 2 X 12 = 24 H-6X 1= 6 O - 1X 16 = 16 1 cm3 6.02 X 1023 molecules C2H5OH 0.8 g 46 31 3 cm C 2H5OH Galvanized Nail End The Mole