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General, Organic, and Biological Chemistry Fourth Edition Karen Timberlake Chapter 1 Chemistry and Measurements 1.5 Measured Numbers and Significant Figures © 2013 Pearson Education, Inc. Lectures Representing Measured Numbers Measured numbers are numbers obtained by using measuring devices, such as a scale or analytical balance, a graduated cylinder, a clock or stopwatch, or a ruler © 2013 Pearson Education, Inc. Chapter 1, Section 5 2 Representing Measured Numbers On a metric ruler with lines marking divisions of 0.1 cm, write the length to 0.1 cm and estimate the value of the final number to 0.01 cm by visual inspection. © 2013 Pearson Education, Inc. Chapter 1, Section 5 3 Rules for Significant Figures In a measured number, the significant figures (SFs) are all digits including the estimated number. A number is a significant figure if it is a nonzero number. (234 g, 3 SF) a zero between nonzero numbers. (50071 g, 5 SF) a zero at the end of a decimal number. (50.00 m, 4 SF) the coefficient of a number is written in scientific notation. (2.0 x 103 m, 2 SF) © 2013 Pearson Education, Inc. Chapter 1, Section 5 4 Scientific Notation and Significant Zeros When one or more zeros in a large number are significant, they are shown more clearly by writing the number in scientific notation. 5,000. kg 5.000 x 103 kg If zeros are not significant, we use only the nonzero numbers in the coefficient. 5,000 kg © 2013 Pearson Education, Inc. 5 x 103 kg Chapter 1, Section 5 5 Exact Numbers Exact numbers are those numbers obtained by counting items. those numbers in a definition comparing two units in the same measuring system. not measured and do not affect the number of significant figures in a calculated answer. © 2013 Pearson Education, Inc. Chapter 1, Section 5 6 Learning Check Identify the following as exact or measured numbers. 1. 824.75 cm 2. 23 students in the class 3. 1 m = 1000 cm © 2013 Pearson Education, Inc. Chapter 1, Section 5 7 Solution Identify the following as exact or measured numbers: 1. 824.75 cm measured number 2. 23 students in the class exact number 3. 1 m = 1000 cm exact number © 2013 Pearson Education, Inc. Chapter 1, Section 5 8 Learning Check How many significant figures are in the following numbers? 1. 8250 cm 2. 0.012 g 3. 8.20 L 4. 3.040 x 10−2 m © 2013 Pearson Education, Inc. Chapter 1, Section 5 9 Solution How many significant figures are in the following numbers? 1. 8250 cm 3 significant figures 2. 0.012 g 2 significant figures 3. 8.20 L 3 significant figures 4. 3.040 x 10−2 m 4 significant figures © 2013 Pearson Education, Inc. Chapter 1, Section 5 10