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Yesterday’s Homework Yesterday’s Homework The concentration of either the H+ ion or the OH- ion is given for three aqueous solutions at 298oK. For each solution, + calculate [H ] or [OH ]. State whether the solution is acidic, basic, or neutral. Yesterday’s Homework If this wasn’t easy, you’re doing it wrong. Yesterday’s Homework + [H ] = 1.0 x -13 10 M Yesterday’s Homework + [H ] -13 10 M = 1.0 x -1 [OH ] = 1.0 x 10 M Yesterday’s Homework + [H ] -13 10 M = 1.0 x -1 [OH ] = 1.0 x 10 M basic Yesterday’s Homework [OH ] = 1.0 x -7 10 M Yesterday’s Homework [OH ] -7 10 M = 1.0 x + -7 [H ] = 1.0 x 10 M Yesterday’s Homework [OH ] -7 10 M = 1.0 x + -7 [H ] = 1.0 x 10 M neutral Yesterday’s Homework [OH ] = 1.0 x -3 10 M Yesterday’s Homework [OH ] -3 10 M = 1.0 x + -11 [H ] = 1.0 x 10 M Yesterday’s Homework [OH ] -3 10 M = 1.0 x + -11 [H ] = 1.0 x 10 M basic Yesterday’s Homework Any questions? Daily Quiz Questions Daily Quiz Questions 1. What is true of [H+] and [OH-]? a. = b. [H+] x [OH-] = 1 x 10-7 + -7 c. [H ] ÷ [OH ] = 1 x 10 d. [H+] x [OH-] = 1 x 10-14 + -14 e. [H ] ÷ [OH ] = 1 x 10 + [H ] [OH ] Daily Quiz Questions 2. In a neutral solution, pH = a. 0 b. 0.5 c. 1 d. 7 e. 14 Daily Quiz Questions 3. 1 x a. b. c. d. -5 10 =? 5 100,000 0.000,01 0.000,001 Daily Quiz Questions 4. Which number is bigger? a. 1 x 10-2 -6 b. 1 x 10 . Daily Quiz Questions 1. What is true of [H+] and [OH-]? a. = b. [H+] x [OH-] = 1 x 10-7 + -7 c. [H ] ÷ [OH ] = 1 x 10 d. [H+] x [OH-] = 1 x 10-14 + -14 e. [H ] ÷ [OH ] = 1 x 10 + [H ] [OH ] Daily Quiz Questions 1. What is true of [H+] and [OH-]? a. = b. [H+] x [OH-] = 1 x 10-7 + -7 c. [H ] ÷ [OH ] = 1 x 10 d. [H+] x [OH-] = 1 x 10-14 + -14 e. [H ] ÷ [OH ] = 1 x 10 + [H ] [OH ] Daily Quiz Questions 2. In a neutral solution, pH = a. 0 b. 0.5 c. 1 d. 7 e. 14 Daily Quiz Questions 2. In a neutral solution, pH = a. 0 b. 0.5 c. 1 d. 7 e. 14 Daily Quiz Questions 3. 1 x a. b. c. d. -5 10 =? 5 100,000 0.000,01 0.000,001 Daily Quiz Questions 3. 1 x a. b. c. d. -5 10 =? 5 100,000 0.000,01 0.000,001 Daily Quiz Questions 4. Which number is bigger? a. 1 x 10-2 -6 b. 1 x 10 Daily Quiz Questions 4. Which number is bigger? a. 1 x 10-2 -6 b. 1 x 10 Logarithms Logarithms The logarithm of a number is the number of times 10 must be multiplied by itself to equal that number. Logarithms 1000 = 10 x 10 x 10 log 1000 = 3 Logarithms To find the logarithm of a number, count the zeroes or, if the number is in scientific notation, look at the exponent. Logarithms 1 = 1 x 100 1 10 = 1 x 10 2 100 = 1 x 10 0.1 = 1 x 10-1 0.01 = 1 x 10-2 log 1 = 0 log 10 = 1 log 100 = 2 log 0.1 = -1 log 0.01 = -2 Logarithms Logarithms You can multiply two numbers by adding their logarithms. Logarithms You can multiply two numbers by adding their logarithms. 100 x 1000 = 100,000 Logarithms You can multiply two numbers by adding their logarithms. 100 x 1000 = 100,000 2+3=5 Logarithms You can multiply two numbers by adding their logarithms. 1x 8 10 = 100,000,000 Logarithms You can multiply two numbers by adding their logarithms. 1x 8 10 = 100,000,000 0+8=8 Logarithms You can multiply two numbers by adding their logarithms. 2x 8 10 = 200,000,000 ?+8= ? Logarithms So what’s the logarithm of 2? You have to look it up. 2x 8 10 = 200,000,000 ?+8= ? Logarithms So what’s the logarithm of 2? You have to look it up. 8 10 2x = 200,000,000 0.301 + 8 = 8.301 Logarithms What if the number is small instead of big? Logarithms What if the number is small instead of big? 0.0003 = 3 x 10-4 Logarithms What if the number is small instead of big? 0.0003 = 3 x 10-4 log 0.0003 = log 3 + log 10-4 Logarithms What if the number is small instead of big? 0.0003 = 3 x 10-4 log 0.0003 = log 3 + log 10-4 = 0.477 – 4 Logarithms What if the number is small instead of big? 0.0003 = 3 x 10-4 log 0.0003 = log 3 + log 10-4 = 0.477 – 4 = -3.523 Logarithms You can find the logarithm of any number by pressing the “log” key on a calculator… Logarithms You can find the logarithm of any number by pressing the “log” key on a calculator… but Logarithms You can find the logarithm of any number by pressing the “log” key on a calculator… but …if you don’t understand what the calculator is doing, the information is useless to you. Logarithms Try a few! Logarithms log 3 10 = Logarithms log 3 10 =3 Logarithms log 8 10 = Logarithms log 8 10 =8 Logarithms log -10 10 = Logarithms log -10 10 = -10 Logarithms log 2 = Logarithms log 2 = 0.301 Logarithms log 5.8 = Logarithms log 5.8 = 0.763 Logarithms log 9.2 = Logarithms log 9.2 = 0.963 Logarithms log 4 x 12 10 = Logarithms log 4 x 12 10 = 0.602 + 12 Logarithms log 4 x 12 10 = 12.602 Logarithms log 8.3 x 5 10 = Logarithms log 8.3 x 5 10 = 0.919 + 5 Logarithms log 8.3 x 5 10 = 5.919 Logarithms log 7.1 x -3 10 = Logarithms log 7.1 x -3 10 = 0.851 - 3 Logarithms log 7.1 x -3 10 = -2.149 Logarithms log 4.8 x -11 10 = Logarithms log 4.8 x -11 10 = 0.681 - 11 Logarithms log 4.8 x -11 10 = -10.319 pH pH = -log + [H ] [OH ] pOH = -log pH + pOH = 14 + [H ] = 0.0035 What is the pH? What is the pOH? Is it acidic or basic? + [H ] = 0.0035 + [H ] = 0.0035 0.0035 = 3.5 x -3 10 + [H ] = 0.0035 0.0035 = 3.5 x -3 10 log 0.0035 = log 3.5 + log 10-3 + [H ] = 0.0035 0.0035 = 3.5 x -3 10 log 0.0035 = log 3.5 + log 10-3 = 0.544 – 3 + [H ] = 0.0035 0.0035 = 3.5 x -3 10 log 0.0035 = log 3.5 + log 10-3 = 0.544 – 3 = –2.456 + [H ] = 0.0035 0.0035 = 3.5 x -3 10 log 0.0035 = log 3.5 + log 10-3 = 0.544 – 3 = –2.456 pH = 2.456 + [H ] = 0.0035 pH = 2.456 pOH = 14 – 2.456 = 11.544 The solution is acidic. Homework Page 611 # 19 Page 612 # 20