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The Arithmetic of Equations
Balanced Chemical Equations
• You can determine the quantities of reactants
and products in a chemical reaction from a
balanced chemical equation.
• When you know the quantity of one
substance in a reaction, you can calculate the
quantity of any other substance consumed or
created in the reaction.
Balanced Chemical Equations
• The calculation of quantities in chemical
reactions is a subject of chemistry called
stoichiometry.
• Calculations using balanced equations are
called stoichiometric calculations.
Interpreting Chemical Equations
• You can describe a chemical reaction in terms
of quantities of products and reactants. These
quantities include number of molecules,
atoms, and moles; mass; and volume.
• Two quantities – number of atoms and mass –
do not change during a reaction.
Interpreting Chemical Equations
• A balanced equation indicates that the
number and type of each atom that makes up
each reactant also makes up each product.
• Both the number and types of atoms are not
changed in a reaction.
Interpreting Chemical Equations
• A balanced chemical equation also tells you
the number of moles of reactants and
products.
• The coefficients of a balanced chemical
equation indicate the relative numbers of
moles of reactants and products in a chemical
reaction.
Interpreting Chemical Equations
• A balanced chemical equation obeys the law
of conservation of mass – mass can be neither
created nor destroyed in an ordinary chemical
or physical process.
Interpreting Chemical Equations
• If you assume standard temperature and
pressure, the equation also tells you about the
volumes of gases.
• 1 mol of any gas at STP occupies a volume of
22.4 L.
Interpreting Chemical Equations Practice
• Interpret this equation in terms of the
interaction of the following three relative
quantities.
• 2H2S(g) + 3O2(g)  2SO2(g) + 2H2O(g)
– A. the number of representative particles and
moles
– B. masses of reactants and products.
Interpreting Chemical Equations Practice
• A. The coefficients give the relative number of
molecules and moles. Two moles/molecules of
H2S react with 3 moles/molecules of O2 to
form two moles/molecules SO2 and two
moles/molecules H2O.
Interpreting Chemical Equations Practice
• B. to find the masses multiply the number of
moles of each reactant and product by its
molar mass:
– 2 mol H2S = 68.2g
– 3 mol O2 = 96g
• 2 mol SO2 = 128.2g
• 2 mol H2O = 36g
• 164.2 g = 164.2 g
Practice Problems
• 3. interpret the equation for the formation of
water from its elements in terms of numbers
of molecules and moles and volumes of gases
at STP?
– 2H2(g) + O2(g)  2H2O(g)
Practice Problems
• 4. Balance the equation for the combustion of
acetylene. Interpret the equation in terms of
relative numbers of moles, volumes of gas at
STP, and masses of reactants and products.
– C2H2(g) + O2(g)  CO2(g) + H2O(g)
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