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The Arithmetic of Equations Balanced Chemical Equations • You can determine the quantities of reactants and products in a chemical reaction from a balanced chemical equation. • When you know the quantity of one substance in a reaction, you can calculate the quantity of any other substance consumed or created in the reaction. Balanced Chemical Equations • The calculation of quantities in chemical reactions is a subject of chemistry called stoichiometry. • Calculations using balanced equations are called stoichiometric calculations. Interpreting Chemical Equations • You can describe a chemical reaction in terms of quantities of products and reactants. These quantities include number of molecules, atoms, and moles; mass; and volume. • Two quantities – number of atoms and mass – do not change during a reaction. Interpreting Chemical Equations • A balanced equation indicates that the number and type of each atom that makes up each reactant also makes up each product. • Both the number and types of atoms are not changed in a reaction. Interpreting Chemical Equations • A balanced chemical equation also tells you the number of moles of reactants and products. • The coefficients of a balanced chemical equation indicate the relative numbers of moles of reactants and products in a chemical reaction. Interpreting Chemical Equations • A balanced chemical equation obeys the law of conservation of mass – mass can be neither created nor destroyed in an ordinary chemical or physical process. Interpreting Chemical Equations • If you assume standard temperature and pressure, the equation also tells you about the volumes of gases. • 1 mol of any gas at STP occupies a volume of 22.4 L. Interpreting Chemical Equations Practice • Interpret this equation in terms of the interaction of the following three relative quantities. • 2H2S(g) + 3O2(g) 2SO2(g) + 2H2O(g) – A. the number of representative particles and moles – B. masses of reactants and products. Interpreting Chemical Equations Practice • A. The coefficients give the relative number of molecules and moles. Two moles/molecules of H2S react with 3 moles/molecules of O2 to form two moles/molecules SO2 and two moles/molecules H2O. Interpreting Chemical Equations Practice • B. to find the masses multiply the number of moles of each reactant and product by its molar mass: – 2 mol H2S = 68.2g – 3 mol O2 = 96g • 2 mol SO2 = 128.2g • 2 mol H2O = 36g • 164.2 g = 164.2 g Practice Problems • 3. interpret the equation for the formation of water from its elements in terms of numbers of molecules and moles and volumes of gases at STP? – 2H2(g) + O2(g) 2H2O(g) Practice Problems • 4. Balance the equation for the combustion of acetylene. Interpret the equation in terms of relative numbers of moles, volumes of gas at STP, and masses of reactants and products. – C2H2(g) + O2(g) CO2(g) + H2O(g)