Download Los Angeles Mission College 13356 Eldgridge Avenue Sylmar, CA 91342

Los Angeles Mission College
13356 Eldgridge Avenue
Sylmar, CA 91342
Phone (818) 833-3382; CMS-244
12890 Harding Street, Sylmar, CA 91342
E-mail: [email protected]
Course Syllabus
CHEM 212
ORGANIC CHEMISTRY II, SPRING 2016
Course Hours:
Lecture
TTh 8:15 am - 9:40 am in CMS-222 (section # 0170)
Laboratory
TTh 9:50 am - 1:10 pm in CMS-206
G. Godjoian, Ph.D.
Monday/Wednesday 12:25 pm– 12:55 pm & 3:30 – 5:00 pm
Tuesday/Thursday 7:25 am – 8:10 am & by appointment
Instructor:
Office hours:
The best resource for help is the instructor. The purpose of office hours is to set aside a block of time for the instructor to
be available for students. You are not interrupting something important when you go to an instructor's office hour. You
and your questions are the most important thing! Please make use of this resource. You can stop by in person, or email
me your questions. Try to get your questions answered as soon as possible.
Course Prerequisites: A grade of C or better in Chem. 211 is required. It is assumed that you have command
of the concepts covered in Chemistry 211.
Chemistry 212: Organic Chemistry II Student Learning Outcome (SLO)
At the end of Chemistry 212 course the student will be able to:
1) Demonstrate an understanding of the mechanism of organic reactions by proposing mechanisms for reactions of
moderate complexity, and be able to predict patterns of reactivity on the basis of mechanistic reasoning.
2) Design multi-step synthesis for compounds of moderate complexity using conceptual models and retro-synthetic
analysis strategies.
3) Analyze and interpret mass, ultraviolet, infrared and nuclear magnetic resonance spectra to propose the
structure of organic molecule.
Course Goals and Objective: Offered for students in physical and biological sciences, medical and dental
professions and other majors concerned with the nature of organic substances.
Chem. 212 is the second course sequence in organic chemistry. This first course provides the context for
students to develop the analytical skills necessary for an understanding of the structure and reactivity of organic
molecules. This second course provides the context for students to develop an understanding of organic
reactions, how does product formation occurs (mechanism), and synthesis of organic molecules. It is with this
knowledge that the student will be able to understand the role of molecular science in his/her own academic
major and career objective. The course will be developed as discussions among the students and instructor, and
will necessarily depend on the active participation by the student. The student should be reminded that the
study of organic chemistry is a systematic one and that each new topic is based on what was learned earlier.
ORGANIC CHEMISTRY CANNOT BE MASTERED BY ROTE MEMORIZATION, but must be approached
from a thorough understanding of its basic principles. If you have trouble, please come to see me as early as
possible.
The objectives are to show the overall organization of classes of organic compounds, factors involved in
classification, characteristic reactions of functional groups and subgroups, the application of physical and
chemical methods of characterizing organic compounds. A mechanistic approach to reactions and a focus on
multistep synthesis will be emphasized throughout the course.
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Materials for the class:
1)
Paula Yurkanis Bruice, Organic Chemistry 7th edition, ISBN-10: 0-321-80322-1
2) Weeks, Pushing Electrons: A Guide for Students of Organic Chemistry 4th edition, ISBN10: 1-133-95188-0 (Recommended)
3) Pavia, Lampman, Kriz, Engel, Introduction to Organic Laboratory Techniques,
customized edition, ISBN-10: 0-495-08282-1
4) Colored pens/pencils or highlighters
5)
Molecular Model Kit (Recommended)
6) Safety Goggles or Safety Glasses (Z-87 code)
7) Laboratory Coat (Recommended)
8) Disposable Gloves (Required for most experiments)
9) Laboratory Notebook: a bound notebook with carbon copies and page numbers throughout
is required
10) Non-programmable scientific calculator
COLLEGE RESOURCES FOR CHEMISTRY STUDENTS
Admissions and Records: Students can register for classes, request transcripts, file petitions for graduation, and drop classes at this
office. For more information call (818) 833-3322 or visit: http://www.lamission.edu/admissions/
Assessment Center: Offers student assessments in English, English-as-a-Second-Language (ESL) and Mathematics. Please contact
the Assessment Center at (818) 364-7613 for more information or visit http://www.lamission.edu/assessment/
Science Success Center (SSC): Free tutoring and workshops are available for chemistry students in Room CMS 101. During Fallsemester the SSC is open Monday-Thursday from 10 am-8 pm, and Saturday from 10 am-2pm. For more information visit their
Facebook page LAMissionSSC or call (818) 364-7600 x 7133.
STEM Office: For information on free tutoring, resources, internship opportunities, and academic counseling for STEM (Science,
Technology, Engineering, and Math) students visit the STEM Center in Room CMS 8 or http://www.lamission.edu/stem
Bookstore: For hours of operation, book availability, buybacks, and other information call (818) 364-7767 or 7768 or visit
http://eagleslanding.lamission.edu/default.asp
Counseling Department: For appointments and information call (818) 364-7655 or visit http://www.lamission.edu/counseling/
Disabled Students Programs and Services (DSP&S): For appointments, eligibility, services, and information call (818) 364-7732 or
visit http://www.lamission.edu/dsps/
Extended Opportunity Programs and Services (EOPS): For appointments, eligibility and information call (818) 364-7645 or visit
http://www.lamission.edu/eops/
Financial Aid: For information and applications call (818) 364-7648 or visit http://www.lamission.edu/financialaid/
Library: For information on hours, resources, workshops, and other services contact (818) 364- 7106 or visit
http://www.lamission.edu/library/
Tutoring Services in Learning Center: Laboratories for Learning, Writing, & some Math classes. Walk-in and appointments. Call
(818) 364-7754 or visit www.lamission.edu/learningcenter/
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Student Code of Conduct & Academic Honesty:
Students are expected to respect and obey standards of student conduct while in class and on the campus. Students shall
demonstrate individual work in lecture, exams, homework/assignment, and laboratory data and reports. All students are
required to follow “NO CHEATING AGREEMENT” which states if a student is caught cheating, the student will receive
a "0" for the assignment or test and will be reported to the Dean of Student Affairs. If the student is caught a second time,
the student will be reported to Vice President of Student Services. In addition, please note the following for this course:
• Collaboration with other students in this course is encouraged for classwork/homework, lab reports and
in-class activities. This means that you are encouraged to verbally discuss your thoughts, arguments, etc.
on these assignments. You may not, however, copy another student’s work directly or submit the exact
same answers as another student. For individual assignments, all problems must be worked out by you
(work shown), and written answers must be in your own words. Failure to follow this policy will result
in a zero for the assignment.
• Collaboration of any kind is NOT allowed on quizzes or exams.
• Any form of cheating (this includes copying lab reports, "dry-labbing", copying or allowing some one to
copy answers on a laboratory activity, lab report, quiz, test, or giving information about the quiz or test to
another student) is not tolerated.
• Using, receiving, or providing unauthorized information during tests or on any written assignments.
• Changing answers on assignments after work has been graded.
• Having another student take an examination for you or taking an examination for another student, or
using unauthorized electronic devices, such as cell phones, PDAs, electronic dictionaries, IPODs during
examination are not allowed.
• Plagiarizing or presenting someone else’s work as your own.
• Violating any other standard that an instructor identifies as cheating in that particular course or subject
area.
To prevent academic dishonesty the following guidelines will be followed. You are allowed to bring colored pens,
pencils, and a non-programmable calculator to quizzes, exams, laboratory, and the final. The following are not allowed
during lecture and laboratory: headphones, audio recorders, image capturing devices (cameras, scanners, etc.), food, and
drinks. Breaks during an exam are not permitted.
Tardy: Arriving late disrupts the class. I expect all students to arrive on time and ready to work. If you are unavoidably
detained, respect your fellow students and instructor by entering the classroom quietly. If you are late to a quiz or exam,
no extra time will be granted. Showing up on time is especially important in the laboratory section as important safety
information is discussed at the beginning of the lab period. For this reason, students arriving more than 10 minutes late
to lab will receive a 10% penalty on their lab report.
Assignments: Chapter assignments will be announced in lecture along with due dates. Assigned problems may come
from your text (odd and even problems) plus some additional problems (not from textbook), or problems made by your
instructor. These problems will be collected, graded, and returned to you. Assignments must be turned in at the beginning
of the class period on the due date. Late assignments will not be accepted except for legitimate absences. All sheets must
be stapled, problems written in the numerical order assigned, and neatness counts. It is your responsibility to successfully
complete each assignment. You may also want to consider forming a study group with other class members, and attend
tutoring available free of charge.
Quizzes and Exams: Weekly quizzes will cover recent materials from lecture. They will be given in lecture time. There
are no make-ups for missed quizzes. There are 13 quizzes total (starting second week of the semester, given on
Thursdays; however, weeks 4, and 12 quizzes will be Tuesday). I will choose 12 best quiz scores out of 13 toward your
final grade.
Exams will be administered during the laboratory portion of the course (about 90-120 minutes, followed by laboratory
work). All quizzes and exams will be closed book and closed notes. You may use a calculator on quizzes and exams (if
necessary) but it must not have any stored information (no Visors, Palms, language translators, or cell phones). Three
exams will be given during the semester. All exam dates are listed on the Schedule provided. It is important that you take
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each exam on the assigned date. No make-up exams will be given unless there was a valid, verifiable reason for missing
that exam. No make-up exams will be given after the test has been returned. If you are going to miss an exam, you
should get in touch with your instructor as soon as possible and make arrangements to take the test earlier. All exams will
be cumulative.
Laboratory: The laboratory section is an important component of the course and worth 35% of your grade.
Laboratory Quizzes
10%
Laboratory Reports
15%
Laboratory Written Final Exam
10%
This is your chance to get “hands-on” experience with the topics covered in lecture and to learn/practice important
laboratory skills that you’ll need in future science courses or employment involving laboratory work. It is essential that
you keep your lab notebook current and that you enter all data directly into the notebook (using black or blue ink pen). To
make sure of this your lab notebook will be checked periodically in the lab. Our goal is to make the laboratory a true
learning experience and not just a test of your ability to follow directions. No late lab reports are accepted. Because
important safety information is discussed at the beginning of the period, you must show up on time to lab. For your safety
and the safety of your classmates, it is very important that you follow proper lab procedures at all times. Students who do
not follow directions or otherwise engage in unsafe behavior in the lab will be dismissed from the laboratory and will be
given a zero for that lab assignment.
For safety purposes, students must dress appropriately when working in the laboratory. Goggles (Z87-code) and
closed-toed shoes must be worn during all laboratory work. If you frequently wear sandals to school, you may leave a
pair of close-toed shoes in your car. Body parts facing the lab bench/hood must be covered. This may be accomplished
by wearing a lab coat or apron. Long hair must be tied back. Students who are not appropriately dressed for laboratory
work will be dismissed from class and given a "0" for the scheduled experiment. It will be up to the student to schedule a
make-up session for the experiment.
Laboratory quizzes will be announced during laboratory time and will be given during laboratory section of the
course. Laboratory quizzes and laboratory written final exam will be closed book, closed notebook and notes, covering
the experimental techniques, laboratory reading materials, and all the experiments done in the laboratory. There are
no make-ups for missed quizzes; however, one lowest quiz grade will be dropped at the end of the semester.
Grading:
Grades will be assigned based on the following percentages:
Grading Scale:
Assignments
5%
90-100% = A
Exams
30%
80-89% = B
Quizzes
15%
70-79% = C
Final Exam -ACS
15%
60-69% = D
Laboratory
35%
59 and below = F
Important Dates:
Friday, February 19th 2016
Sunday, February 21st 2016
Sunday, May 8h 2016
Last Day to Add
Last Day to Drop with no “W”
Last Day to Drop with “W”
ABSOLUTELY NO BEEPERS OR CELL PHONES WILL BE TOLERATED
IN LECTURE OR LABORATORY SECTIONS!
YOU MUST COME TO CLASS ON TIME!
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CHEM. 212
LECTURE TENTATIVE SCHEDULE*
SPRING 2016
Week Date
Lecture on
Chapter
Lecture Schedule
Reading Assignments
(Read Before Class)
1
2/9
2/11
Ch. 8
Ch. 19
Benzene and Aromaticity (8.1-8.3, and 8.7-8-12)
Reactions of Benzene
2
2/16
2/18
Ch. 19
Ch. 19
Reactions of Benzene and Substituted Benzene
Quiz #1; Reactions of Benzene and Substituted Benzene
3
2/23
2/25
Ch. 19
Ch. 11
Reactions of Benzene and Substituted Benzene
Quiz #2; Alcohols: Properties and Reactions of Alcohols
4
3/1
3/3
Ch. 11
Ch. 11
Quiz #3; Reactions and Synthesis involving Alcohols
Ethers: Properties & Reactions
5
3/8
3/10
Ch. 11
Ch. 11
Reactions of Epoxides, Thiols and Sulfides
Quiz #4; Reactions of Amines
6
3/15
3/17
Ch. 16
Ch. 16
Reactions of Carboxylic Acids and Carboxylic Acid Derivatives
Quiz #5; Reactions of Carboxylic Acids and Carboxylic Acid Derivatives
7
3/22
3/24
Ch. 16
Ch. 17
Reactions of Carboxylic Acids and Carboxylic Acid Derivatives
Quiz #6; Reactions of Aldehydes and Ketones
8
3/29
3/31
Ch. 17
Reactions of Aldehydes and Ketones
No Classes- Cesar Chavez Day
SPRING BREAK (April 4th – 9th)
9
4/12
4/14
Ch. 17
Ch. 17
Reactions of α, β-Unsaturated Carbonyl Compounds
Quiz #7; Reactions of α, β-Unsaturated Carbonyl Compounds
10
4/19
4/21
Ch. 18
Ch. 18
Reactions at the α-Carbon of Carbonyl Compounds
Quiz #8; Reactions at the α-Carbon of Carbonyl Compounds
11
4/26
4/28
Ch. 18
Ch. 20
Reactions at the α-Carbon of Carbonyl Compounds
Quiz #9; Amines and Heterocyclic Compounds
12
5/3
5/5
Ch. 20
Ch. 20
Quiz #10; Reactions of Heterocyclic Compounds
Heterocyclic Compounds in Synthesis
13
5/10
5/12
Ch. 21
Ch. 21
Carbohydrates
Quiz #11; Carbohydrates
14
5/17
5/19
Ch. 21 & 22
Ch. 22
Carbohydrate & Amino Acids, Peptides, and Proteins
Quiz #12; Amino Acids, Peptides, and Proteins
15
5/24
5/26
Ch. 26
No Classes- Memorial Day
Quiz #13; Amino Acids, Peptides, and Proteins
FINAL EXAM: Tuesday, May 31st 7:30 -9:30 am (Comprehensive)
*This schedule is tentative and subject to change as the class progresses. *Instructor reserves the right to change this schedule as class
progresses.
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CHEM. 212
Week Date
1
2/9
2/11
2
3
2/16
2/18
2/23
2/25
4
3/1
3/3
5
3/8
3/10
6
3/15
3/17
3/22
3/24
7
8
9
10
11
12
3/29
3/31
4/12
4/14
4/19
4/21
4/26
4/28
5/3
5/5
13
14
15
5/10
5/12
5/17
5/19
5/24
5/26
LABORATORY TENTATIVE SCHEDULE*
SPRING 2016
Laboratory Schedule
Review of Spectroscopy (IR & NMR Exercises); Laboratory Notebook & Locker
Check-in
Iodination of Vanillin
Purification and Analysis of Iodination of Vanillin Product Molecule
Synthesis of Methyl Orange
Analysis of Methyl Orange by Visible Spectrum & Use of Methyl Orange as a Dye, and
the Effect of a Bleach on Dye
Dehydration of 2-Methylcyclohexanol and Analysis of Product by Spectroscopy and
Chemical Tests
Oxidation of Cyclohexanol
Lecture Exam #1; Oxidation of Cyclohexanol & Product Analysis by Spectroscopy
and Chemical Tests
Introduction to Mass Spectroscopy
Interpreting Mass Spectroscopy of Organic Molecules & Determination of Organic
Molecule Structure by Combination Spectroscopy
Mass Spectroscopy Exercises
Introduction to Ultraviolet Spectroscopy
Interpreting Ultraviolet Spectroscopy of Organic Molecules
Williamson Ether Synthesis & Library Assignment
Lecture Exam #2; Continue with Williamson Ether Synthesis
No Classes- Cesar Chavez Day
SPRING BREAK (April 4th – 9th)
Synthesis of 1-Phenyl-3-butene-1-ol & Product Analysis
Product Analysis of 1-Phenyl-3-butene-1-ol &
Wittig Reaction: Synthesis of 1,4-Diphenyl-1,3-butadiene
Wittig Reaction: Synthesis of 1,4-Diphenyl-1,3-butadiene, continues
Identification of an Unknown by Fischer Esterification
Identification of an Unknown by Fischer Esterification, continues
Aldol Reaction: Synthesis, Purification and Analysis of 1,5-Diphenyl-1,4-pentadiene-3one
Lecture Exam #3; Continue with Aldol Reaction
Reaction of Acetophenone with Clorox
Multi-step synthesis: First Step
Multi-step synthesis: Second Step
Multi-step synthesis: Third Step
Analysis of Multi-Step Synthesis and Clean-up & Check-out
Written Final Exam
*This schedule is tentative and subject to change as the class progresses.
*Instructor reserves the right to change this schedule as class progresses.
*Use of cell-phones is not allowed during laboratory time.
*Laboratory Quizzes will be announced during laboratory time.
Students are required to wear safety goggles during laboratory. Failure to comply will be reflected in
your laboratory grade. Food, Gum, or Drinks are not allowed in the laboratory at any time.
grade. Food, Gum, or Drinks are not allowed in the laboratory at any time.
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