Download distinguishing between organic compounds

Survey
yes no Was this document useful for you?
   Thank you for your participation!

* Your assessment is very important for improving the work of artificial intelligence, which forms the content of this project

Document related concepts
no text concepts found
Transcript
Distinguishing between
organic compounds
Organic substances can look
the same – you must be able to
distinguish between common
compounds by comparing their
properties and performing
simple tests.
12 Chemistry 2.2 organic chemistry CR 07
Common compounds
Alcohols, carboxylic acids,
alkanes, alkenes, esters
- all colourless liquids!
How could you distinguish
between them??
12 Chemistry 2.2 organic chemistry CR 07
Alcohols, carboxylic acids,
alkanes, alkenes, esters
1.
2.
3.
4.
5.
6.
Questions you could ask:
Is it flammable?
Is it miscible with water?
Does it react with an oxidant?
Does it react with halogens?
Does it smell?
Does it behave as an acid?
12 Chemistry 2.2 organic chemistry CR 07
Alcohols, carboxylic acids,
alkanes, alkenes, esters
1. Mix with water
Miscible
Not miscible
- 2 layers
Alcohol
Alkane
(short chain) Alkene
Carboxylic
Ester
acid
12 Chemistry 2.2 organic chemistry CR 07
Alcohols, carboxylic acids,
alkanes, alkenes, esters
2. Add magnesium
Reaction
No reaction
Carboxylic acid
Fizzing and
litmus will go
pink
Alkane
Alkene
Ester
Alcohol
12 Chemistry 2.2 organic chemistry CR 07
Alcohols, carboxylic acids,
alkanes, alkenes, esters
3. Add Br2
Reaction
orange 
Alkane slow –
requires UV light
Alkene fast – no
catalyst required
No reaction
Carboxylic acid
Ester
Alcohol
12 Chemistry 2.2 organic chemistry CR 07
Alcohols, carboxylic acids,
alkanes, alkenes, esters
4. Add Cr2O72-/H+
Reaction
orange  green
Alcohol for
primary alcohols
No reaction
Carboxylic acid
Ester
Alkene
Alkane
12 Chemistry 2.2 organic chemistry CR 07
Alcohols, carboxylic acids,
alkanes, alkenes, esters
5. Carefully smell
Fruity smell
Ester
* Carboxylic acid
may smell
unpleasant
Not fruity
Carboxylic acid
Alkene
Alkane
Alcohol
12 Chemistry 2.2 organic chemistry CR 07
Alcohols, carboxylic acids,
alkanes, alkenes, esters
6. Carefully ignite – not necessary as
other tests will identify them
flammable
Ester volatile
Alkene sooty orange
flame
Alkane clean burning
Alcohol clean burning
Not flammable
Carboxylic acid
12 Chemistry 2.2 organic chemistry CR 07
Related documents