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Give the IUPAC Name
CH 3
H3C
C
H2
C
H
CH 3
CH
CH 2
a. 3,4,5-methyl-4-propyloctane
b. 4-propyl-trimethyloctane
c. 4,5,6-trimethylethyoctane
CH 2
CH 3
d. 3,4,5-trimethyl-4-propyloctane
e. 4,5-dimethyl-4-methylpropyloctane
CH 3
C
H
C
H2
C
H2
CH 3
Give the IUPAC Name
a.
b.
c.
d.
e.
4-t-butylheptane
4-isobutylheptane
4-(1,1-dimethylethyl)heptane
4-(1-methylpropyl)heptane
a. and c.
Give the IUPAC Name
(H 3C) 3C
a.
b.
c.
d.
e.
C
H2
I
CH 2CH 3
C
H
C
H
C
H2
C
H2
CH 3
5-ethyl-4-iodo-2-methyloctane
5-ethyl-4-iodo-2,2-dimethyloctane
1,1-dimethyl-3-iodo-4-propyloctane
3-iodo-4-ethyl-1,1,1-trimethylheptane
4-ethyl-5-iododecane
Give the IUPAC Name
Cl
a.
b.
c.
d.
e.
2-chloro-5,5-dimethylhexane
1-t-butyl-3-chlorobutane
2-chloro-4-(2-methylpropan-2-yl)butane
2-chloro-4-t-butylbutane
5-chloro-2,2-dimethylhexane
Alkene and Alkyne Nomenclature
Practice
•
What is the correct Preferred IUPAC name for the following
structure?
a.
b.
c.
d.
e.
(Z)-6-methyl-4-propyloct-2-ene
(Z)-3-methyl-4-(prop-1-en-1-yl)octane
(Z)-3-methyl-5-(prop-1-en-1-yl)octane
(E)-6-methyl-4-propyloct-2-ene
(E)-6-methyl-4-(prop-1-en-1-yl)octane
Alkene and Alkyne Nomenclature
Practice
What is the correct acceptable IUPAC name for this structure?
a.
b.
c.
d.
1,1-dimethyl-3-butyne
4,4-dimethyl-1-butyne
4-methyl-1-pentyne
2-methyl-4-pentyne
CH3
CH
H3C
C
H2
C
C
H
Alkene and Alkyne Nomenclature
Practice
•
What is the correct Preferred IUPAC name for the following
structure?
a.
b.
c.
d.
e.
(Z)-6-methyl-4-propyloct-2-ene
(Z)-3-methyl-4-(prop-1-en-1-yl)octane
(Z)-3-methyl-5-(prop-1-en-1-yl)octane
(E)-6-methyl-4-propyloct-2-ene
(E)-6-methyl-4-(prop-1-en-1-yl)octane
Alkene and Alkyne Nomenclature
Practice
What is the correct acceptable IUPAC name for this structure?
a.
b.
c.
d.
1,1-dimethyl-3-butyne
4,4-dimethyl-1-butyne
4-methyl-1-pentyne
2-methyl-4-pentyne
CH3
CH
H3C
C
H2
C
C
H
Nomenclature of Alcohols
(IUPAC preferred)
Cl
a.
b.
c.
d.
e.
1-chloro-3-hydroxycyclopentane
1-chlorocylopentan-3-ol
3-chlorocyclopentan-1-ol
3-chloro-1-hydroxycyclpentane
3-chlorocyclpentyl alcohol
OH
Nomenclature of Alcohols
(IUPAC acceptable)
a. 4-chloro-3,3,5-trimethyl-7-octanol
b. 5-chloro-6-ethyl-4,6-dimethyl-2-heptanol
c. 5-chloro-4,6,6-trimethyl-2-octanol
d. 3-chloro-2-ethyl-2,4-dimethyl-6-heptanol
e. 3-chloro-2-ethyl-2,4-methylheptanol
• What is the IUPAC name for the following compound?
HO
a.
b.
c.
d.
e.
(Z)-2-(1-hydroxy-2,2-dimethyl)-2-hexene
(Z)-2,2,4-trimethyl-4-octen-3- ol
(Z)-1-t-butyl-2-methyl-2-hexen-1-ol
(E)-2,2,4-trimethyl-4-octen-3- ol
(E)-1-t-butyl-2-methyl-2-hexen-1-ol
Amine Nomenclature
What is an appropriate name for the following
compound?
H2N
a.
b.
c.
d.
e.
(Z)-3-amino-4-methyl-4-octene
(E)-2-(1-aminopropyl)-2-hexene
(Z)-2-(1-aminopropyl)-2-hexene
(Z)-6-amino-5-methyl-4-octene
(E)-3-amino-4-methyl-4-octene
Aromatic Nomenclature Practice
•
a.
b.
c.
d.
e.
What is the an appropriate preferred IUPAC
name for the following compound?
o-bromomethylbenzene
3-bromomethylbenzene
p-bromomethylbenzene
2-bromotoluene
3-bromotoluene
CH3
Br
Aromatic Nomenclature Practice
•
a.
b.
c.
d.
e.
What is the preferred IUPAC name for the following
compound?
1-chloro-4-ethyl-3-(propan-2-yl)benzene
1-chloro-5-ethyl-4-(propan-2-yl)benzene
4-chloro-1-ethyl-2-(propan-2-yl)benzene
1-chloro-4-ethyl-5-(propan-2-yl)benzene
1-ethyl-2-(propan-2-yl)-4-chlorobenzene
H
C
C
H
3
3
C
H
H
2
C
H
C
3
C
l
Aromatic Nomenclature Practice
• Which of the
following structures
is aniline?
O
H
O
NH2
OCH3
OH
C
NH2
C
a.
b.
c.
d.
e.
IUPAC Nomenclature For
Aldehydes and Ketones
O
CH 3
Cl
a.
b.
c.
d.
e.
2-chloro-1-methylcyclohexanone
4-chloro-5-methylcyclohexanone
3,4-chloromethylcyclohexanone
1-chloro-2-methylcyclohexanone
4-chloro-3-methylcyclohexanone
IUPAC Nomenclature For
Aldehydes and Ketones
O
H
a.
b.
c.
d.
e.
(E)-pent-2-ene-1,5-dione
(E)-hex-2-ene-2,5-dione
(E)-4-oxopent-2-enal
(E)-2-oxopent-3-enal
(E)-4-oxypent-2-enal
O
IUPAC Nomenclature For
Aldehydes and Ketones
• What is the preferred name for salicylaldehyde?
O
C
H
a.
b.
c.
d.
2-hydroxybenzaldehyde
o-hydroxybenzaldehyde
2-hydroxybenzenecarbaldehyde
o-hydroxybenzenecarbaldehyde
OH
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