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What do you think is Liang doing? THERMOELECTRIC ENERGY CONVERSION ROBERTO DIMALIWAT, GALENA PARK HIGH SCHOOL GALENA PARK ISD PROFESSOR/MENTOR CHOONGHO YU, PH.D MECHANICAL ENGINEERING DEPT. TEXAS A & M UNIVERSITY LIANG YIN, GRADUATE RESEARCH ASSISTANT Nano-Energy Laboratory Principal Investigator: Dr. ChoonghoYu Graduate Assistants: Liang Yin, Yeontack Ryu, Kyungwho Choi, Marion Okoth, Vinay Naranunni, Wongchang Park, Daniel Mcleod Research Focus: Thermoelectric energy conversion Photovoltaic energy conversion Energy Storage Thermal Managements Design and Fabrication of Nano MEMS Systems and Biomedical Devices Introduction Thermoelectric Energy Conversion • Thermoelectric Effect direct conversion of temperature differences to electric voltage and vice versa. • A thermoelectric device creates a voltage when there is a different temperature on each side. •Thermoelectric devices presently use“bulk materials”. • While all materials have some nonzero thermoelectric effect, it is typically too small to be useful. • Materials which are sufficiently cheap and have strong thermoelectric effect can be used for large-scale thermoelectric applications. • Thermoelectric effect are based on the Seebeck effect and Peltier effect . Seebeck effect - is the conversion of temp. differences directly into electricity. Temp difference = electricity Peltier effect - When a voltage is applied to the Voltage difference different sides of a = device, it creates a Temp difference temperature difference Let’s see how it works http://www.thermoelectrics.caltech.edu/dem os_page.htm The research Thermoelectric energy conversion • Study of the electrical and thermal characteristics of nanowires, (SiGe). •The objective is to find out whether the nanowires have similar thermoelectric properties as bulk materials. • OR are there some differences in these materials to make devices that we can use to improve our way of living? Y?Y?Y?Y?Y?Y? Y?Y?Y?Y?Y?Y? Y?Y?Y?Y?Y?Y? Y?Y?Y?Y?Y?Y? • The energy conversion efficiency depends on the dimensionless figure of merit of thermoelectric materials, ZT, The higher the ZT, the higher the efficiency ZT= S² σT/k T = average temperature σ= electrical conductivity S= seebeck coefficient k= thermal conductivity • Currently, the low ZT values of available materials restrict the efficient applications of this technology. • However, significant enhancements in ZT were recently reported in nanostructured materials. • Higher ZT is mainly due to their low thermal conductivities.. • Thermoelectric devices using bulk materials applications are limited, producing devices with low efficiency. • If waste heat can be harnessed and used in devices with higher efficiency, then it will economically and environmentally impact the way we use the earth’s resources. • Exploring the small scale materials can bring answers to the efficiency problem. That is Y the Research Experimental Set Up How does the set up work? The Micromodule The micro module under the optical microscope What measurements are taken? Independent variables: Temperature difference Controls The seebeck effect constant is established The electrical conductivity is ZT= S² σT/k established T= average temperature Dependent variable: σ= electrical conductivity S= seebeck coefficient Thermal conductivity k= thermal conductivity http://www.thermoelectrics.caltech.edu/ Present Findings 100 Si nanowire 115nm Ge nanowire 115nm Si/Si0.7Ge0.3 superlattice film 10 Thermal conductivity(W/mK) Si0.9Ge0.1 film 5 32 40 Si0.4Ge0.6 Bulk 40 Si0.5Ge0.5 Bulk 41 83nm Si/SixGe1-x nanowire 15 15 Core Si0.29Ge0.71 NW2(109nm) Core-shell Si0.29Ge0.71 NW2(133nm) Core-shell Si0.50Ge0.50 NW3(181nm) 1 Core-shell Si0.19Ge0.81 NW1(132nm) Core Si0.19Ge0.81 NW1(96nm) Ge Einstein model Si Einstein model SiGe Einstein model 0.1 0 100 200 • SiGe nanowires have lower thermal conductivity than bulk materials. 300 400 Temperature(K) ZT= S² σT/k ZT is inversely proportional to thermal conductivity • As the nanowires get smaller, the thermal conductivity lessens. • • electrical conductance tends to be constant with temperature change, • thus the possible efficiency increase. This research can lead to the use of nanowires in thermoelectric devices with higher efficiency than devices using bulk materials. Now, maybe we know what Liang is doing! The Future Liang’s car is partially powered by heat generated from its exhaust…. cooooool How will I use this in my classroom? I am designing an experiment using a Peltier module to show thermoelectric energy conversion, that is, a temperature gradient will produce voltage strong enough to make a motor run. The flip side will be, the students will design an experiment to show that the process is reversible using some of the original materials plus a few additions. Concepts/TEKS – There is a lot of Physics and Chemistry concepts involved in this activity. I will outline them in detail in the final presentation Acknowledgements ChoonghoYu, Ph.D Mechanical Engineering Dept ,TAMU Liang Yin, Graduate Assistant National Science Foundation Nuclear Power Institute Texas Workforce Commission Chevron