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Presolar Silicates Presolar Silicates in meteorites in Primitive Chondrites K. Nagashima, S. Kobayashi, N. Sakamoto, 永島一秀, 小林幸雄, 坂本直哉, 殿谷梓, 圦本尚義 東工大・地球惑星科学 A. Tonotani, and H. Yurimoto Earth and Planetary Sciences, Tokyo Institute of Technology Mar. 02, 2005 Presolar grains 26Al 12C, 18O Supernova ejecta 16 O Solar System Meteorite 28Si Onion-type structure of massive star before supernova 1µm Stellar outflow AGB star (source of s-process nuclides) SiC from Murchison (Amari et al., 1994) Presolar grains Diamond SiC Graphite Spinel Corundum Silicate 0.001 0.01 0.1 1 10 100 1000 ppm 10000 are susceptible to aqueous It Silicates was about a year ago that alteration, which transformed silicates into hydrous silicates. elusive This presolar first discovered. processsilicates erases anywere presolar isotopic signatures. Nagashima et al., 2004; Nguyen and Zinner, 2004; Difficulties to locate presolar silicates among boundlessly abundant Mostefaoui and Hoppe, 2004 solar system silicates that are major constituents of meteorites. Analytical methods • Isotope microscope (Yurimoto et al., 2003) Secondary Ion Mass Spectrometry: SIMS + 2-D ion detector: SCAPS Isotope ims-1270 ESAMicroscopeMagnetic Sector SIMS SCAPS SCAPS sample 10 mm Spatial resolution of isotope image Sample name of chondrite Acfer 094 pristine class C3-ungrouped Yamato-81025 CO3.0 ALHA 77307 CO3.0 Adelaide altered Murchison C3-ungrouped CM2 BSE 17O QuickTimeý Dz GIF êLí£ ÉvÉçÉOÉâÉÄ Ç™Ç±ÇÃÉsÉNÉ`ÉÉǾå©ÇÈÇ…ÇÕïKóvÇÇ• ÅB Adelaide (ungrouped) 16O 18O QuickTimeý Dz GIF êLí£ ÉvÉçÉOÉâÉÄ Ç™Ç±ÇÃÉsÉNÉ`ÉÉǾå©ÇÈÇ…ÇÕïKóvÇÇ• ÅB 28Si /16O BSE d18O d17O (‰) (‰) Oxygen Isotopic Ratios of Presolar Silicates A total of 41 presolar silicates were found. BSE Images of Presolar Silicates Olivine Pyroxene Olivine from Acfer 094 (ungrouped) 1µm from Adelaide (ungrouped) 1µm BSE Images of Presolar Silicates from Acfer 094 (ungrouped) 1µm from Murchison (CM2) GEMS? (Glass with Embedded Metal and Sulfide) 1µm Grain size distribution of presolar silicates 20 number 15 10 5 0 0 200 400 600 size / nm 800 1000 Note that unidentified silicates are not included. Nagashima et al., 2004; Nguyen and Zinner, 2004; Mostefaoui et al., 2004; Messenger et al., 2003; 2004; Floss and Stadermann, 2004; this study Origins (after Nittler et al., 1997) Group 1 O-rich RGB or AGB Group 2 AGB with Cool Bottom Processing Group 3 low-metallicity RGB or AGB Group 4 still uncertain origin low-mass AGB? supernovae? altered pristine Abundances of presolar silicates in meteorites number of abundance presolar silicates (ppm) meteorite class Acfer 094 C3-ungrouped 4 Yamato-81025 CO3 20 ALHA 77307 CO3 8 Adelaide C3-ungrouped 5 10 50 30 40 Murchison CM2 4 3 Abundances of presolar silicates Interplanetary Dust Particles (IDPs) 450 ~5500 ppm (Messenger et al., 2003; Floss and Stadermann, 2004) Destruction of presolar silicates by thermal processing in the solar nebula. Most pristine chondrites 10~50 ppm Destruction of presolar silicates by aqueous alterations on chondrite parent body. Aqueously altered chondrites <3 ppm Summary In situ isotopic survey of matrix materials in primitive chondrites are conducted. A total of 41 presolar silicates are identified in 5 chondrites. Most of presolar silicates are enriched in 17O, suggesting origins in O-rich RGB/AGB stars. Estimated abundances of presolar silicates in primitive chondrites are 1~50 ppm. The difference of abundances of presolar silicates between IDPs and primitive chondrites could be explained by destruction of presolar silicates by thermal processing in the solar nebula, and aqueous alteration processes on their parent bodies. Future work Further studies conducted on different meteorite types will allow us to understand more detailed origins and history of presolar grains, conditions in solar system environments. Search for new types of presolar silicate grains such as grains from supernovae.