Download Physical Chemistry II. laboratory practice (GYFKE03P3)

Physical Chemistry II. laboratory practice
(GYFKE03P3)
A tantárgyfelelős neve: dr. Attila Bényei
A tárgy oktatójának neve/tanszéke:dr. Attila Bényei/Faculty of Pharmacy
dr. Katalin Ősz/Department of Physical Chemistry
Óraszám/hét: 3
Kreditszám: 2
A tantárgy felvételének előzetes követelménye: GYFKE03P2 Physical Chemistry I. lecture
and seminar
Tantárgyteljesítési követelmény:
a.) a tanórákon való részvétel követelményei és a távolmaradás pótlásának lehetősége:
Presence is required in accordance with the regulations of UD.
b.)a félévközi ellenőrzések száma, témaköre, időpontja, pótlás és javítás lehetősége:
Written test every week based on the topic of that week’s laboratory practice.
c.) a teljesítésértékelés (számonkérés) módja: The measurements and written tests
according to the knowledge of the associated theory are marked and the overall mark will
be given based on these.
A tárgy tematikája: 4-hour laboratory practices for 12 weeks.
1st week: Introduction, general information and safety training (1 hr)
2nd week: One of the following topics: Measuring densities by pycnometer, composition of a
binary mixture. Measuring electrical conductivity of solutions.
3rd week: One of the following topics: Measuring the concentration of a colored solute by
spectrophotometry. Determination of NaHCO3 content of a solid sample by gas
volumetry.
4th week: One of the following topics: pH-metric titration curves of hydrochloric and acetic
acids. Study of electrolysis.
5th week: One of the following topics: Mutarotation of glucose measured by polarimetry.
Measuring electromotive force of a galvanic cell.
6th week: One of the following topics: Reaction rate of decomposition of H2O2 measured by
gas volumetry. Investigation of buffers.
7th week: One of the following topics: Distillation of an alcohol-water mixture.
Determination of heat of combustion by using a bomb calorimeter.
8th week: One of the following topics: Thermodynamic quantities by measuring the
temperature dependent EMF. Determination of partial molar volumes by
measuring densities.
9th week: One of the following topics: Redox potentials from potentiometric titrations.
Determination of activity coefficient for concentration galvanic cell.
10th week: One of the following topics: Study of the iodine/iodide equilibrium. Dissociation
constant of weak acids measured by conductometry.
11th week: One of the following topics: Dissociation equilibria of ampholites, determination
of isoelectric pH. Acid catalysed hydrolyis of saccharose.
12th week: One of the following topics: Kinetics of a second order reaction: hydrolysis of
esters. Initial rates and activation energy of the iodine clock.
A felkészüléshez ajánlott irodalmak:
1. David P. Shoemaker, C. W. Garland and J. W. Nibler: Experiments in Physical
Chemistry. McGraw-Hill Book Companies, 1989.
2. Katalin Ősz, Attila Bényei: Physical Chemistry Laboratory Measurements (for
students of Pharmacy, Chemistry and Chemical Engineering). Egyetemi Kiadó, 2011.
3. Dr. György Póta: Physical Chemistry (lecture material).
URL:http://puma.unideb.hu/~potagy/targyak/gyogyszeresz/gyogyszeresz.html
(lecture)
4. P.W. Atkins: Physical Chemistry, Vols. I-III.
5. Peter Atkins and Julio de Paula: Elements of Physical Chemistry. 4th edition, Open
University Press, 2005.