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Journal of Geochemical Exploration 89 (2006) 124 – 128 www.elsevier.com/locate/jgeoexp Hydrothermal alteration and fluid inclusion study of the Lower Cretaceous porphyry Cu–Au deposit of Tiámaro, Michoacán, Mexico Carlos Garza-González a,⁎, Antoni Camprubí b , Eduardo González-Partida b , Germán Arriaga-García a , Fernando Rosique-Naranjo a a Facultad de Ingeniería, Universidad Nacional Autónoma de México, Ciudad Universitaria, 04510 México D.F., Mexico b Centro de Geociencias, Universidad Nacional Autónoma de México, Campus Juriquilla, Carretera 57 km. 15.5, 76023 Santiago de Querétaro, Qro., Mexico Received 11 August 2005; accepted 4 November 2005 Available online 23 March 2006 Abstract The Tiámaro deposit in Michoacán state has been dated as Lower Cretaceous (Valanginian), though most of the porphyry deposits in central Mexico were dated or have an attributed Eocene–Oligocene age. The host rocks belong to a volcanoplutonic complex overlain by red conglomerates. These rocks were intruded by pre-Valanginian plutonic and hypabissal rocks. Propylitic, phyllic, and argillic alteration assemblages developed, and their superimposition draws the evolution of the deposit. Stage I is represented by propylitic assemblages, stage II contains the main ore forming stockworks and both phyllic and argillic assemblages, and stage III contains late carbonatization assemblages. The obtained temperatures and salinities from inclusion fluids are low for a porphyry-type deposit, but we interpret that the known part of the deposit represents the shallow portion of a bigger deposit. The evolution of mineralizing fluids draws a dilution trend of brines from “porphyry-like” to “epithermal-like” stages. The richest ore zone is roughly located between the 300 and 350 °C isotherms, though unnoticed resources may occur at depth. © 2006 Elsevier B.V. All rights reserved. Keywords: Tiámaro; Mexico; Porphyry Cu–Au; Hydrothermal alteration; Fluid inclusions 1. Introduction In south-central Mexico up to 16 porphyry type deposits have been identified. They can be generally distributed into three ranges of age: (1) associated with the Laramide orogeny, as La Sorpresa in Jalisco, (2) Eocene–Oligocene, as La Verde, Inguarán and Tumbiscatío in Michoacán, and (3) Miocene–Pliocene, as Ixtacamaxtitlán in Puebla, Santa Fe and Tolimán in ⁎ Corresponding author. E-mail address: [email protected] (C. Garza-González). 0375-6742/$ - see front matter © 2006 Elsevier B.V. All rights reserved. doi:10.1016/j.gexplo.2005.11.046 Chiapas. The formation of porphyry type deposits in northwestern Mexico is generally associated with Laramide tectonomagmatic activity (75–50 Ma; Clark et al., 1982; Damon et al., 1983), but in central Mexico the deposits that have been dated, or have an attributed age, mostly formed during the Eocene–Oligocene (Valencia-Moreno et al., 2006). Two deposits, however, were recently reported to have formed between Upper Jurassic and Lower Cretaceous: El Arco in Baja California (164.1 ± 0.4 Ma, Re–Os; Valencia et al., 2004), and Tiámaro in Michoacán (140 to 131 Ma, U–Pb and Ar/Ar; Garza-González et al., 2004: A. Iriondo, C. Garza-González et al. / Journal of Geochemical Exploration 89 (2006) 124–128 2005, pers. commun.). These ages will widen exploration efforts to previously neglected areas, especially in southern Mexico. Estimated grades for the porphyry Cu–Au deposit of Tiámaro are 0.60% Cu and 0.1 g/t Au for 500 Mt (Garza-González et al., 2004). Despite the economic importance of porphyry type deposits in Mexico, these deposits still lack systematic studies on their mineralogy and fluid chemistry, and the metallogenic provinces that contain them also need further regional characterization. This paper is the first attempt to characterize the temperature and composition of the mineralizing fluids and their evolution in the Tiámaro porphyry copper deposit, by means of fluid inclusion microthermometry. 2. Regional geology The Tiámaro porphyry copper deposit is located in the northeastern part of the Michoacán state, ∼155 km 125 SW of Mexico City, within the Sierra Madre del Sur (SMS) and close to the Trans-Mexican Volcanic Belt (TMVB). In this zone are found the northernmost outcrops of intrusive Cretaceous rocks of the SMS (Fig. 1). The host rocks belong to a pre-Valanginian volcanoplutonic complex (Garza-González et al., 2004) that includes porphyry andesites, subvolcanic breccias, aglomerates, and calcalkaline dacite flows on top, all overlain by red conglomerates. These rocks were intruded by dioritic and tonalitic plutonic and hypabissal rocks. These rocks can be characterized as primitive tholeiites formed in an island arc setting, from their trace element composition (Garza-González et al., 2004). The above complex was intruded by the Tuzantla batholith (Fig. 1), whose composition varies from quartz monzonite to granodiorite with calcalkaline affinity, close to the compositional field of adakites. These rocks have yielded U–Pb ages in zircon of 132.3 ± 1.4 and 131.0 ± 1.1 Ma, respectively (Garza-González et al., Fig. 1. Geological map of the Tiámaro area, Michoacán. Key: SMO = Sierra Madre Occidental, SMS = Sierra Madre del Sur, TMVB = Trans-Mexican Volcanic Belt. 126 C. Garza-González et al. / Journal of Geochemical Exploration 89 (2006) 124–128 2004). Another part of the porphyry deposit occurs within a tonalitic stock, and in adamellitic, tonalitic, and granitic hypabissal bodies that intrude the volcanoplutonic complex. This second set of intrusive rocks shows geochemical and geochronological evidence for a genetic link with the Tuzantla batholith. There is a late generation of monzonitic intrusives, but they are barren. The above rocks are unconformably overlain by Tertiary and Quaternary volcanic and sedimentary rocks. 3. Structure of the deposit The Cu–Au mineralization, mostly found as stockworks, is associated with the tonalitic stock in the east, and with adamellitic and granitic–tonalitic hypabissal bodies in the west (Fig. 1). About 70% of the ore bodies are hosted by the above rocks, and the rest are hosted by microdiorites of the volcanoplutonic complex. Propylitic, phyllic, and argillic alteration assemblages were identified in the deposit, and potassic alteration was identified in the northern part of the Tuzantla batholith. The evolution of the deposit can be characterized by three major hypogenic alteration stages. Stage I, or early hypogenic alteration, basically consists of propylitic alteration, found either as a selective alteration of mafic minerals, or as a chlorite–epidote–calcite–sericite association in veinlets within a microdiorite intruded by tonalite in the central part of the deposit. Such alteration, however, is commonly pervasive and represented by the association of chlorite, epidote, carbonates, Fig. 2. Above: Geological section of the Tiámaro deposit, showing the distribution of isotherms after Th of fluid inclusions, the ranges of Tmi, the general distribution of alteration assemblages,and the position of the tonalite stock. Below: Correlation of average Th and Tmi obtained in fluid inclusions in different associations of the deposit, in order of formation in the legend. Key: Th = temperature of homogenization, Tmi = temperature of ice melting. C. Garza-González et al. / Journal of Geochemical Exploration 89 (2006) 124–128 pyrite, sericite, various clay minerals ± actinolite, found in the southern part of the deposit. It contains deep mineralized zones as stockworks with early chalcopyrite–pyrite and late bornite where phyllic alteration is superimposed on propylitic alteration. Stage II, or intermediate hypogenic alteration, contains both phyllic and argillic alteration assemblages. Most of the copper ores are associated with phyllic alteration, as pyrite–chalcopyrite ± bornite stockworks. In tonalites, microtonalites and microdiorites, phyllic alteration is usually pervasive and consists of quartz, sericite and pyrite (± chlorite and clay minerals), and a conspicuous subordinate carbonatization. Phyllic alteration also occurs as abundant sericite stringers and veinlets, as massive sericite associations replacing plagioclase fenocrysts and microcrystals, and abundant quartz–chlorite–pyrite–chalcopyrite ± bornite veinlets. A sericite sample from phyllic alteration in the host microgranite at the El Rey mine (Tiámaro area) yielded a 40Ar/39Ar age of 140 ± 5 Ma (A. Iriondo, 2005, pers. comm.). The similarity between this age and the U–Pb ages obtained in the Tuzantla batholith, and their closeness in space suggests that both sets of intrusive rocks are part of the same event and that they may have formed from the same magmas. The argillic alteration assemblage is superimposed on the phyllic assemblage, and occurs at depth between the propylitic and phyllic assemblages, at the contact zone between tonalites and microdiorites and between microdiorites and microtonalites. It generally consists of illite–smectite and other clay minerals, chlorite, calcite, and epidote. This assemblage contains a pyrite–chalcopyrite stockwork grading up to 2730 ppb Au. Stage III, or late hypogenic alteration, consists of quartz ± sphalerite veinlets and two carbonatization stages, the first of them associated with the last occurrence of chalcopyrite in the evolution of the deposit, and the second carbonatization stage is barren and may represent the final waning stage of hydrothermal activity in the deposit. 4. Fluid inclusions A microthermometric study of fluid inclusions was carried out on 23 samples from ore zones (stockworks), 25 samples from phyllic and argillic alteration zones (stage II), and 16 samples from late calcite (stage III), obtained from both surface exposures in mine workings and drill cores. The analyzed minerals were quartz and calcite. We analyzed only inclusions hosted by minerals lacking evidence for recrystallization. Primary, secondary, and pseudosecondary inclusions were found, which 127 are two-phase at room temperature, liquid-rich inclusions with no daughter minerals. The fluid inclusions are mostly 5 to 15 μm in size, but range up to 50 μm. S(NaCl,KCl) + L + V fluid inclusions, typical for most porphyry type deposits, were not found at the Tiámaro deposit, probably because drilling has not yet reached either any zone with boiled-off paleofluids or the deepest part of metal ores. This deposit also exhibits a prominent late “epithermal” event that might allow us to trace a complete evolution for mineralizing fluids. The results are shown in Fig. 2. In stockworks, homogenization temperatures (Th) range from 295 to 350 °C, and ice melting temperatures (Tmi) from − 7 to − 16 °C. These correspond to calculated salinities that range from 10.5 to 19.5 wt.% NaCl eq. (using the equation for the H2O–NaCl system of Bodnar, 1993), and an average pressure of 145 bars. In phyllic and argillic assemblages, Th ranges from 110 and 295 °C, Tmi from − 5 to − 11 °C, and salinities from 7.8 to 15 wt.% NaCl eq. In late calcite veinlets (stage III), Th ranges from 101 to 220 °C, Tmi from − 3 to − 11 °C, and salinities from 5 to 15 wt.% NaCl eq., for an average pressure of 1.3 bars. Thus, the evolution of mineralizing fluids shows a dilution of brines from “porphyry” to “epithermal” stages, more noticeable regarding minimum or average values than the variation ranges. Microthermometric data from stage II display a bimodal distribution, but only due to the distribution of temperatures of homogenization, and there is no clear evidence for mixing at any stage. The richest ore zone is located roughly between the 300 and 350 °C isotherms (Fig. 2), but that perspective is expected to change as deeper zones of the deposit are drilled and studied. 5. Conclusions The porphyry Cu–Au deposits at Tiámaro, Michoacán, Southern Mexico, is hosted by a pre-Valanginian volcanoplutonic complex, and is due to the intrusion of mainly tonalitic hypabissal rocks dated as ∼132–131 Ma (U–Pb) and 140 ± 5 Ma (Ar/Ar) that have a geochemical signature similar to that of adakites. As porphyry-type deposits in south-central Mexico were dated or have attibuted Eocene–Oligocene ages, the ages obtained in Tiámaro may necessarily change the exploration strategies for this type of deposits in the region. The evolution of the deposit can be defined by the superimposition of alteration assemblages: stage I corresponds to propylitic alteration, stage II to phyllic and argillic alteration, and contains the main ores in stockwork zones, and stage III corresponds to late carbonatization. 128 C. Garza-González et al. / Journal of Geochemical Exploration 89 (2006) 124–128 In stockworks, homogenization temperatures (Th) range from 295 to 350 °C, ice melting temperatures (Tmi) from − 7 to − 16 °C, and salinities from 10.5 to 19.5 wt.% NaCl eq. In phyllic and argillic assemblages Th ranges from 110 and 295 °C, Tmi from − 5 to − 11 °C, and salinities from 7.8 to 15 wt.% NaCl eq. In late calcite veinlets (stage III), Th ranges from 101 to 220 °C, Tmi from − 3 to −11 °C, and salinities from 5 to 15 wt.% NaCl eq. These data suggest that the known part of the deposit may only be its upper portion, and more resources may be found at depth, that are related to more saline and hotter fluids, indicating more typical temperatures for the environment of formation of a porphyry-type deposit. Acknowledgements This work was funded through the research project IN103703 granted by DGAPA-PAPIIT-UNAM. We also thank the staff at the Tiámaro mine for their kind assistance, and Juan Tomás Vázquez, from the Centro de Geociencias for the elaboration of thin sections. We also gratefully acknowledge the critical reviews of Steven Kesler and an anonymous referee. References Bodnar, R.J., 1993. Revised equation and table for determining the freezing point depression of H2O–NaCl solutions. Geochimica et Cosmochimica Acta 57, 683–684. Clark, K.F., Foster, C.T., Damon, P.E., 1982. Cenozoic mineral deposits and subduction-related magmatic arcs in Mexico. Geological Society of America Bulletin 93, 533–544. Damon, P.E., Shafiqullah, M., Clark, K.F., 1983. Geochronology of porphyry copper deposits and related mineralization of Mexico. Canadian Journal of Earth Sciences 20 (6), 1052–1071. Garza-González, C., González-Partida, E., Tritlla, J., Levresse, G., Arriaga-García, G., Rosique-Naranjo, F., Medina-Ávila, J.J., Iriondo, A., Aguilar-Lovera, A., Zúñiga-Hernández, N., 2004. 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