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Fact Sheet – Electrochemistry
Electrochemistry is the study of chemical reactions which take place at the interface of an
electrode, usually a solid metal or a semiconductor, and an ionic conductor, the electrolyte. These
reactions involve electric charges moving between the electrodes and the electrolyte (or ionic
species in a solution). Thus electrochemistry deals with the interaction between electrical energy
and chemical change.
When a chemical reaction is caused by an externally supplied current, as in electrolysis, or if an
electrical current is produced by a spontaneous chemical reaction as in a battery, it is called an
electrochemical reaction. Chemical reactions where electrons are transferred directly between
molecules and/or atoms are called oxidation-reduction or (redox) reactions. In general,
electrochemistry describes the overall reactions when individual redox reactions are separate but
connected by an external electric circuit and an intervening electrolyte.
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