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ALKYLBENZENE DERIVATIVES FOR OIL FIELD APPLICATIONS Stepan Company is a global manufacturer of specialty and intermediate chemicals used in industrial applications. Stepan has a broad product portfolio and the expertise to assist the oil industry with the improvement and enhancement of their production, drilling and stimulation processes. Stepan Company currently manufactures a wide variety of alkylbenzene sulfonic acids and their salts (i.e. sulfonates). Our linear and branched acids and their salts can be used in a variety of oil field functions and applications such as wetting agent, paraffin inhibitor, dispersant, foamer, emulsion breaker, cleaner/detergent and acidizing agent. Alkylbenzene Sulfonic Acids Product Chemical Description Region of Manufacture Activity, % Unsulfonated Matter, % Free H2SO4, % 2-Phenyl Content Tetralin Content Flash Point (PMCC), °C Pour Point, °C Freeze Point, °C BIO-SOFT® LA Acid Alkylbenzene (C11.8) Sulfonic Acid, Linear Alkylbenzene (C12.0) Sulfonic Acid, Linear Alkylbenzene (C11.4) Sulfonic Acid, Linear Alkylbenzene (C11.4) Sulfonic Acid, Linear Alkylbenzene (C11.8) Sulfonic Acid, Linear Alkylbenzene (C12.0) Sulfonic Acid, Linear EUROPE 96.5 <2.5 <1.0 Low NA >94 NA NA EUROPE 96.0 <2.5 <1.5 High NA >100 NA NA N-AMERICA, EUROPE N-AMERICA 96.0 <2.5 <2.0 High Low >94 -15 -18 95.0 <4.0 <0.4 NA Low >110 NA NA 96.5 <2.0 <2.0 Low Low >94 -15 -18 BIO-SOFT® NA Acid Linear Acids BIO-SOFT® S-101 BIO-SOFT® S-101 LS BIO-SOFT® S-118 BIO-SOFT® S-120 BIO-SOFT® S-120LP Branched Acid BIO-SOFT® S-126 Product SULFONIC 100 (STEPANTAN® H-100) Alkylbenzene(C12.0) Sulfonic Acid, Linear Alkylbenzene (C12.6) Sulfonic Acid, Linear Chemical Description Dodecylbenzene Sulfonic Acid (12.0), Branched N-AMERICA, L-AMERICA N-AMERICA, L-AMERICA, ASIA ASIA 96.5 <1.5 <2.0 Low Low >94 -15 -18 96.0 NA NA Low Low >94 -15 -18 N-AMERICA 96.0 <2.5 <2.5 Low Low >94 -18 -21 Region of Manufacture Activity, % Unsulfonated Matter, % Free H2SO4, % 2-Phenyl Content Tetralin Content Flash Point (PMCC), °C Pour Point, °C Freeze Point, °C N-AMERICA 95.0 <2.5 1.7 NA NA >94 12 9 N-America: North America. L-America: Latin America. Unsulfonated Matter: Unreacted feed stock. Free H2SO4: Unreacted sulfuric acid. 2-Phenyl: Isomer which may affect the solubility and foaming properties of a formulation. Tetralin: Component in the feedstock forming dialkyltetralin sulfonate which acts as a surfactant, hydrotrope and viscosity modifier. Flash Point: The temperature at which a surfactant’s vapor will cause combustion (PMCC Method). Pour Point: The lowest possible temperature at which a surfactant remains pourable. NA: Not available. Alkylbenzene Sulfonate Derivatives Product BIO-SOFT® D-40 Linear Sulfonates BIO-SOFT® N-300 BIO-SOFT® N-411 BIO-SOFT® SDBS 30LA NACCONOL® 90G NINATE® 60E Pour Point, °C -1 Freeze Point, °C -4 Liquid Water >94 -9 -12 Linear Liquid Water >94 NA NA 30.0 Linear Liquid Water NA NA NA N-AMERICA 92.0 Linear Powder None NA NA NA N-AMERICA, L-AMERICA, EUROPE N-AMERICA, L- AMERICA, EUROPE N-AMERICA, L-AMERICA, EUROPE N-AMERICA 59.0 Linear Liquid 2-Ethyl Hexanol 65 -17 NA 60.0 Linear Liquid Naptha Aromatic Solvent, 1-Hexanol 54 -11 NA 68.0 Linear Liquid Isobutyl Alcohol 32 7 NA 22.0 Linear Liquid Water >94 -2 -5 N-AMERICA 28.0 Linear Slurry Water >94 -5 -4 N-AMERICA 50.0 Linear Slurry Water >100 6 3 Chemical Description Region Of Manufacture Activity, % Base Type Form at 25° C Solvent Flash Point (PMCC), °C Pour Point, °C Freeze Point, °C Isopropylamine Alkylbenzene Sulfonate Sodium Dodecylbenzene Sulfonic Acid, Branched Sodium Dodecylbenzene Sulfonate, Branched Isopropylamine Dodecylbenzene Sulfonate, Branched Calcium Alkylbenzene Sulfonate, Branched N-AMERICA 90.0 Blend Liquid Water 92 -5 -8 N-AMERICA 30.0 Branched Liquid Water >94 18 15 N-AMERICA, EUROPE, ASIA N-AMERICA 22.0 Branched Liquid Water >94 10 7 88.0 Branched Liquid Water >94 -1 -4 N-AMERICA, L-AMERICA, EUROPE 60.0 Branched Liquid Naptha Aromatic Solvent, 1-Hexanol 66 -7 NA Sodium Dodecylbenzene Sulfonate, Linear Triethanolamine Dodecylbenzene Sulfonate Isopropylamine Dodecylbenzene Sulfonate, Linear Sodium Dodecylbenzene Sulfonate, Linear Sodium Dodecylbenzene Sulfonate, Linear Calcium Alkylbenzene Sulfonate, Linear NINATE® 60L Calcium Alkylbenzene Sulfonate, Linear NINATE® 70B Calcium Alkylbenzene Sulfonate, Linear POLYSTEP® A-15 Sodium Dodecylbenzene Sulfonate, Linear Potassium Dodecylbenzene Sulfonate, Linear Sodium Dodecylbenzene Sulfonate, Linear POLYSTEP® A-15/30K POLYSTEP® LAS-50 Branched Sulfonates Water Flash Point (PMCC), °C >94 Chemical Description Product G-3300 POLYSTEP® A-16 POLYSTEP® A-16-22 NINATE® 411 NINATE® 401-A Region of Manufacture N-AMERICA, EUROPE, ASIA N-AMERICA Activity, % 38.0 Base Type Linear Form at 25° C Liquid Solvent 60.0 Linear N-AMERICA 90.0 EUROPE Nothing contained herein grants or extends a license, expressed or implied, in connection with patents, issued or pending, to the manufacturer or others. The information contained herein is based on the manufacturer’s own study and the works of others. The manufacturer makes no warranties, expressed or implied, as to the accuracy, completeness or adequacy of the information contained herein. The manufacturer shall not be held liable (regardless of fault) to the vendor’s employees or anyone for any direct, special or consequential damages arising from or in connection with the accuracy, completeness, adequacy or furnishing of such information. BIO-SOFT®, NACCONOL®, NINATE® and POLYSTEP® are registered trademarks of Stepan Company. ©2012 Stepan Company. All rights reserved.