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Isotopes and mass number Atoms of elements always have equal numbers of protons (positive charges) and electrons (negative charges). The number of neutrons (which are neutral) an atom can have can vary. Generally in an atom (with the exception of hydrogen) the number of neutrons exceeds or equals the number of protons. Isotopes are atoms of the same element which have differing numbers of neutrons. Hydrogen has 3 isotopes - hydrogen, deuterium and tritium. Hydrogen 1 proton, 1 electron, no neutrons represented as Deuterium 1 proton, 1 electron, 1 neutron represented as Tritium 1 proton, 1 electron, 2 neutrons represented as Mass number This is defined as the number of protons and neutrons inside the nucleus of an atom. All the mass of the atom is in the nucleus. (we can ignore the mass of an electron) Protons and neutrons have the same mass. Electrons are around 2000 times lighter than either a proton or neutron. Atomic number This is defined as the number of protons OR electrons in an atom. Protons have a positive charge. Electrons have a negative charge. Atoms are neutral. (number of positive charges = number of negative charges). Hence IN AN ATOM number of electrons = number of protons Calculating the number of neutrons in an atom Mass number = number of protons + number of neutrons Atomic number = number of protons Mass number - atomic number = number of protons + number of neutrons - number of protons Mass number - atomic number = number of neutrons So if we know the mass number atomic number of an atom we can determine how many protons, neutrons and electrons are present in that atom. A short hand way to write all this is shown below: In this example using deuterium: EXERCISES on Mass number / atomic number