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Chemistry 3202 Final Exam TOPICS Review Unit I: Kinetics & Equilibrium - - - - - Reaction Rates and Measuring Reaction Rates Kinetic Molecular Theory (KMT) o Definition o KMT and Physical States of Matter o Support of KMT Collision Theory Transition State Theory Activation Energy, EA Potential Energy Diagrams Endothermic & Exothermic Processes Calculations involving Potential Energy Diagrams Factors that Affect Reaction Rate o Concentration of a reactant o Pressure of a reactant o Surface area of a solid reactant o Temperature o Nature of the reactants o Presence/Absence of a catalyst Reaction Mechanisms o Elementary process o Reaction Intermediates o Catalyst o Rate Determining Step o Overall Reaction Rate Catalysts o Homogeneous o Heterogeneous Types of Elementary Reactions o Unimolecular o Bimolecular o Termolecular Reaction Rates Lab STSE #1: Smog, Catalytic Converters and You Irreversible vs. Reversible Reactions Dynamic equilibrium Conditions necessary for equilibrium Le Chatelier’s Principle - Equilibrium constant o Definition o Interpreting K o Calculations involving K Unit II: Acids and Bases - - - - Operational Definitions of Acids and Bases Arrhenius Theory Modified Arrhenius Theory Bronsted-Lowry Theory Conjugate Acid/Base Pairs Amphoteric Strong vs. Weak Acids Strong vs. Weak Bases Predicting Bronsted-Lowry Acid/Base Reactions Autoionization of Water o Kw = [H3O+][OH-] Types of Acids o Monoprotic o Diprotic o Triprotic pH and pH Scale o Calculating pH and pOH Acid and Base Dilution pH of a weak acid o % Reaction o Acid/Base Dissociation Constants (Ka and Kb) Calculations Involving Ka and Kb o ICE tables! Acid/Base Titrations o Equivalence Point vs. Endpoint o Primary standard o 4 types of Acid/Base Titrations Acid/Base Stoichiometry (XS problems) Titration Curves Indicators STSE #2: Acids Around Us Titration Lab Unit III: Thermochemistry - - Energy Temperature Potential Energy/ Kinetic Energy/ Thermal Energy Work and heat System and surroundings 1st Law of Thermodynamics Law of Conservation of Energy 3 types of systems 4 types of energy changes Heat capacity vs. Specific heat capacity q = C∆T and q = mc∆T Phase Change vs. Chemical Change Enthalpy and Enthalpy change Molar enthalpy Representing enthalpy change o Thermochemical equations o ∆H notation o Enthalpy Diagrams q = n∆H Heating and Cooling Curves Total Heat Released or Absorbed by a System Calorimetry o Coffee Cup Calorimeter o Bomb Calorimeter Hess’s Law Bond Energy STSE #3 – What Fuel’s You Unit IV: Electrochemistry - Oxidation and Reduction Reactions Oxidation vs. Reduction Half Reactions Oxidizing Agent vs. Reducing Agent Balancing Redox Reactions in Neutral solutions Oxidations Numbers/States Identifying Redox Reactions Balancing Redox Reactions o Acidic o Basic - - Redox Stoichiometry Electrochemical Cells Cell Potentials Electrolytic Cell o Electrolysis of water o Electrolysis of molten salts o Electrolysis of aqueous solutions Faraday’s Law Batteries Hydrogen Fuel Cells STSE #4: From Minerals to Metal