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Organic Chemistry Ch. 5-8 Schedule - Spring 2016 Date Fri. 5-29 Mon 5-2 Tues 5-3 Wed. 5-4 Class Activities 5.1 Structural relations 5.2 Constitutional Isomerism 5.3 Classifying and Naming Alcohols Practice Naming ~10 min 5.7 The Oxidation of Alcohols Practice identifying structures ~5 min (WS attached) Start Review of Rxns WS (pg 1 only) due in three days (attached) Correct PS 5.1 Quiz-Naming Alcohols and Ethers (start of class) Check reading notes Box 5.1, 5.2, 5.3; Quick Review of boxes Review of Oxidation Reactions; Oxidation States 5.4 Physical Properties of Alcohols 5.9 Ethers 5.6 & 5.10 Dehydration of Alcohols 6.1 Structure Aldehydes and Ketones 6.2 Naming Aldehydes and Ketones Check reading notes box 6.1, 6.2 Ald/Ket in Nature/Impt. Dichromate Testing Lab ~25 min Correct Dichromate Lab Correct Review of Reactions WS 6.4, 6.5 Oxidation/Reduction of Aldehydes/Ketones Quiz – Naming Aldehydes and Ketones Homework Read: pg. 150-157, 165-169, 176-177 Hwk: reading notes on pg. 2 of note packet (box 5.1 pg 156, box 5.2 pg 158, box 5.3 pg 160) = 13 pt Read: pg. 158-162, 172-175 Hwk: PS 5.1 Ch. 5 #2,7,8,17,18,19, 27b,35,36(1-3),41, 67 pg. 179-183 Read: pg. 175; 184-192; 195-204 (skim 6.5) Hwk: reading notes on pg. 6 packet (box 6.1, box 6.2) Hwk: PS 5.2 ,9,10,15c, 29,30,32, 43 (15c and 32 will be done in class after dehydration notes) Hwk: Review of Rxns WS (attached) Hwk: Start PS 6.1 Ch. 6 #1,2,5,9,10, 11, 12,15,21, 33,49,66,68 pg. 210-215 Cold Light Lab ~40 min Thurs. 5-5 Fri. 5-6 Mon. 5-9 Tues. 5-10 Wed. 5-11 Thurs. 5-12 Fri. 5-13 Cold Light Lab post lab Quiz – Reactions (Redox and dehydration) Check Reading Notes Box 7.1 Carboxylic Acids in Nature 7.1 Carboxylic acids 7.2 Synthesis of Carboxylic Acids 7.3 Naming Carboxylic Acids 7.5 Acidity of Carboxylic Acids 7.6 Carboxylate Salts Box 7.2 Carboxylate Salts Read: pg. 216-228 AND reading notes in packet (box 7.1) 7.7 Soaps and their cleaning action Box 7.3 Hard Water and Detergents 7.8 Esters from Carboxylic Acids and Alcohols 7.9 Names of Esters (omit physical prop) LAB – Making Soap – next unit Slush Day – Make up needed work Correct PS 7.1 LAB – Preparation of esters (Lab O-38) Read: pg. 229-232 Hwk: P.S. 7.1 Ch. 7 #1-3,7-13,15ab,16 pg. 241-245 (will correct with rest tomorrow) QUIZ – Ester formation, naming esters & acids Polyester synthesis; Hydrolysis of esters LAB – Preparation of Aspirin (Quiz while acid ppt’s) Complete test #5 on your aspirin (even if wet) 8.1 Amines and Amides 8.2 Classifying Amines 8.3 Naming Amines Correct PS 7.2 Nylon Lab ~20 min Complete Naming Amine WS and grade end of class TEST: Ch. 5-8 Read: Aspirin Lab; pg. 232-235 (attached) Hwk: : Collect Ester Lab ; aspirin pre-lab questions Hwk: PS 6.1 Ch. 6 #1,2,5,9,10, 11, 12, 15, 21, 33,49,66,68 pg. 210-215 Hwk: reading notes on pg. 8 packet (box 7.1) Correct Cold Light Lab Get your make-up work completed. Hwk: P.S. 7.1 cont. 28,29,30a,33 E.C. 34a Read: Read pg. 246-252 Hwk: PS 7.2 Ch. 7 #21,22a,27,37-39 pg. 241245 Naming Amines WS (in class) attached Collect Aspirin Lab Hwk: Study for Test; Ch. 5-8 Review WS (answers online) Essential Questions: • How do you name alcohols, ethers, aldehydes, and ketones, acids, esters, and amines? • How can you predict chemical properties alcohols, ethers, aldehydes, ketones, acids, and esters? • How can you predict physical properties alcohols and ethers? • How can you describe the cleaning action of soap? • How can you write an equation to demonstrate the acidity of a carboxylic acid? • How can you write an equation for the hydrolysis and saponification of an ester? Naming Alcohols Ethers Aldehydes Ketones Carboxylic acids Esters Amines Physical properties Solubility alkane < ether < aldehyde, ketone, alcohol, acid Melting/Boiling points: alkane < ether, aldehyde, ketone < alcohol < acid Reactions/Chemical Properties Complete combustions Organic compound (w/ H & C) + O2 CO2 + H2O Selective Oxidation: Primary alcohol aldehyde carboxylic acid Secondary alcohol ketone Reduction: Carboxylic acid aldehyde primary alcohol Ketone secondary alcohol Dehydration: Primary alcohol + primary alcohol ether + water Primary or secondary alcohol alkene Carboxylic acid + alcohol ester + water Acid/Base: Carboxylic acid + water carboxylate ion + hydronium Carboxylic acid + base carboxylate salt + water Saponification: Triclyceride + base fatty acid salt + glycerol Polyester formation/ hydrolysis: n diester polyester + water Polyester + water n ester