Download Takanori SHIMA

Takanori SHIMA
Date of birth
:
June 6, 1972
Tel. number
:
+81-(0)48-467-9390
Fax number
:
+81-(0)48-467-9391
E-mail address
:
[email protected]
Education
1996
B.Sc. Chemistry, 1996, Tokyo Institute of Technology (Japan)
1998
年
M.Sc. Chemistry, 1998, Tokyo Institute of Technology (Japan)
(Supervisor: Prof. Hiroharu Suzuki)
2001
Ph.D. Chemistry, 2001, Tokyo Institute of Technology (Japan)
(Supervisor: Prof. Hiroharu Suzuki)
Research and professional experience
1998-2001
Research Fellow of the Japan Society for the Promotion of Science
2001-2002
年
Postdoctoral Fellow of Japan Science and Technology Corporation (JST)
(Prof. Hiroharu Suzuki)
2003-2004
Research Fellow of Humboldt Foundation from 2003 to 2004
Prof. John, A. Gladysz (Universitaet fuer Erlangen-Nuernberg)
2004-2008
Special Postdoctoral Researcher, Organometallic Chemistry Laboratory, RIKEN
(Director: Dr. Zhaomin Hou)
2009-2011
Research Scientist, Organometallic Chemistry Laboratory, RIKEN
(Director: Dr. Zhaomin Hou)
2011-
Senior Research Scientist, Organometallic Chemistry Laboratory, RIKEN
(Director: Dr. Zhaomin Hou)
2013-
Senior Research Scientist, Advanced Catalysis Research Group, Center for Sustainable
Resource Science, RIKEN
Publications
31)
S. Hu, T. Shima, and Z. Hou,
"Carbon-Carbon Bond Cleavage and Rearrangement of Benzene by a Trinuclear Titanium
Hydride",
Nature, 2014, 512, 413-415.
30)
T. Shima, S. Hu, G. Luo, X. Kang, Y. Luo, Z. Hou,
"Dinitrogen Cleavage and Hydrogenation by a Trinuclear Titanium Polyhydride Complex",
Science, 2013, 340, 1549-1552.
29)
S. Hu, T. Shima, Y. Luo, and Z. Hou,
"Tetranuclear Zirconium and Hafnium Polyhydride Complexes Composed of the "CpMH 2"Units",
Organometallics, 2013, 32, 2145-2151.
28)
T. Shima and Z. Hou,
"Heterometallic Polyhydride Complexes Containing Yttrium Hydrides with Different Cp
Ligands: Synthesis, Structure, and Hydrogen-Uptake/Release Properties",
Chem. Eur. J., 2013, 19, 3458-3466.
27)
M. Nagaoka, T. Shima, T. Takao, and H. Suzuki,
"Synthesis of a heterometallic trinuclear cluster of ruthenium and iridium containing a
perpendicularly coordinated alkyne ligand and its dynamic behavior",
J. Organomet. Chem., 2013, 725, 68-75.
26)
T. Shima, Y. Luo, T. Stewart, R. Bau, G. J. Mclntyre, S. A. Mason and Z. Hou,
"Molecular heterometallic hydride clusters composed of rare-earth and d-transition metals",
Nature Chem., 2011, 3, 814-820.
25)
T. Shima, M. Nishiura, and Z. Hou,
"Tetra-,Penta-,and Hexanuclear Yttrium Hydride Clusters from Half-Sandwich
Bis(aminobenzyl)Complexes Containing Various Cyclopentadienyl Ligands",
Organometallics, 2011, 30, 2513-2524.
24)
M. Nishiura, J. Baldamus, T. Shima, K. mori, and Z. Hou,
"Synthesis and Structures of the C5Me4SiMe3-Supported Polyhydride Complexes over the Full
Size Range of the Rare Earth Series",
Chem. Eur. J., 2011, 17, 5033-5044.
23)
J. Cheng, T. Shima, and Z. Hou,
"Rare-Earth Polyhydride Complexes Bearing Bis(phosphinophenyl) Amido Pincer Ligands",
Angew. Chem. Int. Ed., 2011, 50, 1857-1860.
22)
T. Shima and Z. Hou,
"Selective Ammonolysis of Half-Sandwich Rare-Earth Metal Dialkyl and Polyhydride
Complexes: Synthesis of Polyamido Rare-earth Complexes Having Novel Structures",
Dalton Trans., 2010, 39, 6858-6863.
21)
A. J. Nawara-Hultzsch, K. Skopek, T. Shima, M. Barbasiewicz, G. D. Hess, D. Skaper, and J. A.
Gladysz,
"Syntheses and Palladium, Platinum, and Borane Adducts of Symmetrical Trialkylphosphines
with Three Terminal Vinyl Groups, P((CH2)mCH=CH2)3",
Z. Naturforsch., 2010, 65b, 414-424.
20)
T. Shima, K. Namura, H. Kameo, S. Kakuta, and H. Suzuki,
"1,4,7-Trimethyl-1,4,7-triazacyclononane Ligand: A Useful Precursor for Synthesis of
Heterometallic Complexes",
Organometallics, 2010, 29, 337-346.
19)
Y. Takenaka, T. Shima, J, Baldamus, and Z. Hou,
"Reduction of Transition-Metal-Coordinated Carbon Monoxide by a Rare-Earth Hydride
Cluster: Isolation of Well-Defined Heteromultimetallic Oxycarbene, Oxymethyl, Carbene, and
Methyl Complexes",
Angew. Chem. Int. Ed., 2009, 48, 7888-7891.
18)
H. Kameo, T. Shima, Y. Nakajima, and H. Suzuki,
"Synthesis of Heterometallic Trinuclear Polyhydrido Clusters Containing Ruthenium and
Osmium and Their Electronic and Structural Deviation from Homometallic Systems",
Organometallics, 2009, 28, 2535-2545.
17)
T. Shima, Z. Hou,
"Rare Earth/d-Transition Metal Heteromultimetallic Polyhydride Complexes Based on
Half-Sandwich Rare Earth Moieties",
Organometallics, 2009, 28, 2244-2252.
16)
T. Shima, Y. Sugimura, and H. Suzuki,
"Heterometallic Trinuclear Polyhydrido Complexes Containing Ruthenium and a Group 9 Metal,
[Cp*3Ru2M(μ3-H)(μ-H)3] (M = Ir or Rh); Cp* = η5-C5Me5): Synthesis, Structure, and
Site-Selectivity in Reactions with Phosphines",
Organometallics, 2009, 28, 871-881.
15)
T. Shima and Z. Hou,
"Activation and Dehydrogenative Silylation of the C-H Bonds of Phosphine-coordinated
Ruthenium in Lu/Ru Heteromultimetallic hydride complexes",
Chem. Lett., 2008, 37, 298-299.
14)
Z. Hou, M. Nishiura, T. Shima,
"Synthesis and Reactions of Polynuclear Polyhydrido Rare Earth Metal Complexes Containing of
"(C5Me4SiMe3)LnH2" Units: A New Frontier in Rare Earth Metal Hydride Chemistry",
Eur. J. Inorg. Chem., 2007, 2535-2545.
13)
T. Shima, T. Ichikawa, and H. Suzuki,
"Reaction of a Heterobimetallic Polyhydrido Cluster, [Cp*Ru(μ-H)4OsCp*] (Cp* = η5-C5Me5),
with Diphenylacetylene. Regioselective C-H Bond Activation at the Osmium Center",
Organometallics, 2007, 26, 6329-6337.
12)
F. Jaroschik, T. Shima, X. Li, K. Mori, L. Ricard, X. -F. Le Goff, F. Nief, and Z. Hou,
"Synthesis, Characterization, and Reactivity of Mono(phospholyl)lanthanoid(III)
Bis(dimethylaminobenzyl) Complexes",
Organometallics, 2007, 26, 5654-5660.
11)
L. Wang, T. Shima, F. Hampel and J. A. Gladysz,
"Gyroscope-like molecules consisting of three-spoke stators that enclose “switchable” neutral
dipolar rhodium rotators; reversible cycling between faster and slower rotating Rh(CO)I and
Rh(CO)2I species"
Chem. Commun., 2006, 4075-4077.
10)
T. Shima and Z. Hou,
"Hydrogenation of Carbon Monoxide by Tetranuclear Rare Earth Metal Polyhydrido Complexes.
Selective Formation of Ethylene and Isolation of Well-Defined Polyoxo Rare Earth Metal
Clusters",
J. Am. Chem. Soc., 2006, 128, 8124-8125.
9)
A. J. Nawara, T. Shima, F. Hampel, and J. A. Gladysz,
"Gyroscope-like Molecules Consisting of PdX2/PtX2 Rotators Encased in Three-Spoke Stators:
Synthesis via Alkene Metathesis, and Facile Substitution and Demetalation",
J. Am. Chem. Soc., 2006, 128, 4962-4963.
8)
J. Ito, T. Shima, and H. Suzuki,
"Synthesis of Group 8-Group 6 Heterotrimetallic Polyhydrido Complexes Having Only a C5Me5
Group as Auxiliary Ligand",
Organometallics, 2006, 25, 1333-1336.
7)
T. Shima and H. Suzuki,
"Heterobimetallic Polyhydride Complex, Cp*Ru(μ-H)4OsCp* (Cp*=η5-C5Me5). Synthesis, and
Reaction with Ethylene",
Organometallics, 2005, 24, 3939-3945.
6)
T. Shima and H. Suzuki,
"P-C Bond Cleavage by a Heterobimetallic Polyhydrido Complex, (C5Me5)Ru(μ-H)3Ir(C5Me5).
Structure Determination and Fluxional Behavior of a Bridging Phosphido Complex,
(C5Me5)Ru(μ-PPh2)(μ-H)(μ-η1:η2-C6H5)Ir(C5Me5)",
Organometallics, 2005, 24, 1703-1708.
5)
T. Shima, F. Hampel, and J. A. Gladysz,
"Molecular Gyroscopes Consisting of Fe(CO)3 and Fe(CO)2(NO)+ Rotators Encased in
Three-Spoke Stators; Facile Assembly via Alkene Metatheses",
Angew. Chem. Int. Ed., 2004, 43, 5537-5540.
4)
J. Ito, T. Shima, and H. Suzuki,
"Di- and Trinuclear Polyhydride Complexes Containing Ruthenium and Rhenium. Synthesis,
Site Exchange, and H/D Exchange of Hydride Ligands",
Organometallics, 2004, 23, 2447-2460.
3)
T. Shima, E. B. Bauer, F. Hampel, and J. A. Gladysz,
"Alkene Metatheses in Transition Metal Coordination Spheres: Dimacrocyclizations that join
trans Positions of Square-Planar Platinum Complexes to give Topologically Novel Diphosphine
Ligands",
Dalton Trans., 2004, 1012-1028.
2)
T. Shima, J. Ito and H. Suzuki,
"Synthesis, Characterization and Structure Determination of Heterobimetallic Polyhydride
Complexes (C5Me5)Ru(μ-H)3MH3(C5Me5) (M = Mo, W) Containing Group VI and Group VIII
Metal",
Organometallics, 2001, 20, 10-12.
1)
T. Shima and H. Suzuki,
"Heterobimetallic Polyhydride Complex Containing Ruthenium and Iridium. Synthesis and
Site-selectivity in the Reaction with Unsaturated Hydrocarbons",
Organometallics, 2000, 19, 2420-2422.