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Applied Chemistry Department
Faculty of Technology and Engineering, The M. S. University of Baroda
VADODARA-390001
Teaching and Examination Scheme for the Four Semester Course in M. Sc. (Applied Chemistry)
(Effective from July 2014)
Sr.
Code No.
Subject
No.
First Semester of M Sc-I (F S of M Sc-I (Applied Chemistry))
1
AC 101
Advanced Inorganic Chemistry
Teaching Scheme
hrs/week
Examination
Scheme
Total Marks
4
100
2
3
AC 102
AC 103
Advanced Organic Chemistry
Advanced Physical Chemistry
4
4
100
100
4
AC 104
Analytical Chemistry
4
100
5
AC 105
Process Calculations
2
50
5
AC 106
Chemical Engineering Operations
2
50
6
AC 107
Advanced Inorganic Preparations (Practicals)
4
50
7
8
AC 108
AC 109
Advanced Organic Preparations (Practicals)
Advanced Physical Chemistry (Practicals)
4
4
50
50
32
Second Semester of M Sc-I (S S of M Sc-I (Applied Chemistry))
1
AC 201
Chemical Process Industries – I
(Inorganic)
2
AC 202
Chemical Process Industries – II
(Organic)
3
AC 203
Materials Science
650
4
100
4
100
4
100
4
AC 204
Drugs
4
100
5
6
AC 205
AC 206
Chemical Engineering Kinetics
Industrial Economics
2
2
50
50
7
AC 207
4
50
8
AC 208
Chemical and Industrial Analysis and Quality
Control (Practicals)
Engineering Drawing (Practicals)
2
50
9
AC 209
Industrial Visits
6
32
25
4
100
100
100
First Semester of M Sc-II (F S of M Sc-II (Applied Chemistry))
1
AC 301
Petrochemicals
625
2
3
AC 302
AC 303
Surfactants
Heavy Chemicals
4
4
4
AC 304
Process Control
2
50
5
AC 305
Computational Techniques in Chemistry
4
100
6
AC 306
2
50
7
8
AC 307
AC 308
Computational Techniques in Chemistry
(Practicals)
Industrial Management
Advanced organic synthesis (Practicals)
2
6
50
75
9
AC 309
Seminars
2
50
30
Second Semester of M Sc-II (S S of M Sc-II (Applied Chemistry))
1
AC 401
Agrochemicals and Fertilizers
675
4
100
2
AC 402
Dyes and Textile Auxiliaries
4
100
3
4
AC 403
AC 404
Industrial Pollution
Polymers, Plastics and Resins
4
4
100
100
5
AC 405
Industrial Chemistry
4
100
6
AC 406
Instrumental Methods of Chemical Analysis
2
50
7
AC407
Introduction to Patent and Copy rights
2
25
8
AC 408
Projects
12
200
36
129
775
Grand Total
2725
1
Applied Chemistry Department
Faculty of Technology and Engineering, The M. S. University of Baroda
VADODARA-390001
FIRST SEMESTER M. Sc. -I (APPLIED CHEMISTRY)
ADVANCED INORGANIC CHEMISTRY
(Effective from July 2014)
AC-101
4 hrs/week
Maximum Marks: 100
1. Symmetry and Group Theory
Symmetry elements and Symmetry operations, representation of Symmetry operations as matrices, definition of groups,
Sets of Symmetry operations of molecules satisfying the conditions of a group, generators, classes of operations, reducible
and irreducible representations, derivation of character table-C2v point group. Applications of group theory - atomic orbital
and Spectroscopy.
2. Organometallic Compounds
Classification based on the nature of Metal Carbon bond, ionic OMC’S, compounds containing Metal-carbon 6 bonds,
Ylides, OMC’S with multicenter Bonds, OMC’S with π bonded Ligands, Bonding in Pi-metal complexes, - Pi - Metal –
olefin, Pi – Metal acetylene. Bonding in Ferrocene and Reactions of Ferrocene.
Classification of ligands in OMC’S :a) Based on number of C atoms through which ligand is attached to metal atom. (b)
Based on number of electrons contributed by the ligand for carbon – ligand bonding.
Inert gas or 18 electron rule, Counting the effective number of electrons, basis for 18 electron rule, role of π – bonding
ligand in stabilizing complexes, Explanation for exceptions of the 18- electron rule, Nomenclature of OMC’s.
3. Magnetochemistry of Transition Metal complexes
Basic terms used in magneto chemistry, Orbital magnetic moment , Spin magnetic moment, Types of magnetismDimagnetism, Paramagnetism, Ferromagnetism and Antiferromagnetism Measurement of magnetic susceptibility, Magnetic
Behavior of Transition Metal Complexes – Theoretical Background, Valence Bond approach, its limitations, Crystal Field
approach, Quenching of orbital angular momentum.
4. Reaction Mechanism in coordination Compounds
Substitution reactions in octahedral complexes, SN1 and SN2 mechanism – Types of intermediates formed.
Lability and Inertness of Transition Metal complexes – Valence Bond approach, Crystal Field approach
Lability of Non – transition Metal complexes.
Mechanism of Acid hydrolysis in octahedral complexes under various conditions.
Mechanism of Base hydrolysis – Stereochemistry of intermediates.
Substitution reactions in square Planar Complexes- Trans effect - Oxidation – Reduction reactions- atom or group transfer
through electron transfer – outer sphere mechanism, inner sphere mechanism, two electron transfer reactions.
5. Bioinorganic Chemistry
Importance of following Biological systems – Iron in Haemoglobin and myoglobin, cooperative effect.
Zinc as ideal biosite and its role in carbonic anhydrase.
Role of Alkali metals - Na+ - K+ pump. Biological functions and toxicity of some elements. Metal ion and ligand in
therapy.
6. Inorganic Polymers: Synthesis, Structure, Properties and applications of the following:
P – N based polymers;
S –N based polymers and Silicones
7. Corrosion
Introduction, Dry or chemical corrosion, wet or` electrochemical Corrosion, mechanism, pilling Bed worth rule.
Types of corrosion-galvanic corrosion, concentration cell corrosion, Differential aeration corrosion, soil corrosion, Pitting
corrosion, Intergranular corrosion, Microbial corrosion, Stress corrosion, Waterline corrosion, Erosion corrosion, Factors
influencing corrosion.
8. Corrosion Control and Protective coatings
Corrosion Control: Proper designing, using pure metal, using metal alloys, cathodic protection, modifying the environment,
use of Inhibitors.
Protective coatings: Types, Paints, Pigments, drying oils, varnishes, enamels, lacquers.
References
1.
2.
3.
4.
5.
6.
7.
Chemical Applications of Group Theory-F.A.Cotton (Wiley-Eastern, N. Delhi).
Group Theory and its chemical Applications _ P. K. Bhattacharya (Himalaya Publishers).
Inorganic Chemistry of Biological processes – M.N. Hughes (John Wiley, London)
Bio-Inorganic Chemistry-E.Ochii (Thomas Springfield).
Inorganic Biochemistry - G.L.Eichorn Vol. I &II (Elsevier, London)
Bio-Inorganic Chemistry –H.W. Hay.
Inorganic Chemistry – Puri, Sharma & Kalia (Shobhan Lal Naginchand & Co.)2006.
2
Applied Chemistry Department
Faculty of Technology and Engineering, The M. S. University of Baroda
VADODARA-390001
FIRST SEMESTER M. Sc. -I (APPLIED CHEMISTRY)
ADVANCED ORGANIC CHEMISTRY
(Effective from July 2014)
4 hrs/week
AC –102
Maximum Marks: 100
1.
Advanced Organic Synthesis (Reactions and Reagents)
Reactions : (i) Arndt Eistert Synthesis (ii) Birch Reduction (iii) Knoevenagel reaction (iv) Michael addition
Reagents: (i) Diborane (ii) LiAlH4 (iii) OsO4 (iv) Crown ethers (v) Dicyclohexylcarbodiimide (DCC)
2.
Molecular Rearrangements
(a) (i) Beckmann rearrangement (ii) Lossen rearrangement (iii) Bayer – Villiger rearrangement (iv) Fries
rearrangement — Inter, Intra & Photo.
(b) Scales of acidity and basicity, factors affecting acidity/basicity, Superacids and their applications.
3.
Heterocyclic Compounds: (Classification, Numbering, Nomenclature and importance of the study ).
Five and six membered heterocyclic compounds with two hetero atoms e.g. pyrazole, imidazole, oxazole, Thiazole,
Pyridazine, Pyrimidine, Pyrazine etc. (synthesis of some important Hetero cyclic compounds from above class).
4.
Tautomerism And Reactivity:
Canionotropy and anionotropy, Mechanism of Prototropic transformation.
5.
Stereochemistry :
Relative stability and reactivity of diastereoisomers, Conformational analysis, Applications of Dipole moment, IR, NMR,
and Raman spectra in conformational analysis.
6.
Reactive intermediates
Structure, stability, methods of Preparation and reactions involving following organic intermediates:
(i) Free radicals (ii) Carbocations (iii) Norbornyl and other non- classical Carbocations (iv) Carbanions
(v) Carbenes (vi) Arynes
7.
Retrosynthetic Analysis :
The disconnection approach, Logic and concepts, Synthon and Synthon equivalent, Umpolung methods, Linear and
convergent synthesis, Control elements, Illustration of some Synthetic approaches.
8.
Spectroscopy:
The use of NMR and Mass spectroscopy for structure elucidation of organic compounds. Principles, Instrumentation and
applications.
References
1.
2.
3.
4.
5.
6.
Organic synthesis: The Disconnection Approach by Stuart Warren
Text book of organic chemistry Vol. I & II,by I. L. Finar.
Organic chemistry, 6th Edn. R. T. Morrison and R. N. Boyd.
Organic chemistry by Jerrry March.
Reaction Mechanism in Organic chemistry by Peter Sykes.
Organic chemistry by O. F. Agrawal.
3
Applied Chemistry Department
Faculty of Technology and Engineering, The M. S. University of Baroda
VADODARA-390001
FIRST SEMESTER M. Sc. -I (APPLIED CHEMISTRY)
ADVANCED PHYSICAL CHEMISTRY
(Effective from July 2014)
AC-103
4 hrs/week
Maximum Marks: 100
1.
Statistical Thermodynamics:
Limitations of classical thermodynamics, Statistical thermodynamics. Maxwell-Boltzmanm distribution, Molecular
Partition functions and their significance, thermodynamic information from partition function, Sackur-Tetrode equation.
Thermodynamics of living systems. (a) Chemical processes in living systems. (b) ATP hydrolysis and chemical energy.
2.
Chemical Kinetics:
Thermodynamic formulation of transition state theory, consecutive reactions, chain reactions, branching chain reactions and
parallel reaction, determination of activation energy.
3.
Photochemistry:
Laws of photochemistry, symmetry rules and selection rules, Jablonski diagram and charge transfer processes.
4.
Colloidal State:
Properties of colloids, micelle formation and Kraft temperature, surface films, Langmuir-Blodgett film, introduction to
conformation and configuration of macromolecular chains, random coils, helices and sheets.
5.
Phase Equilibrium:
Three component systems and their graphical representation, ternary system consisting of liquids, two salts and water (a)
having common ion and (b) salts forming double salt.
6.
Electrochemical processes:
Thermodynamics and kinetics of an electrochemical metal deposition and dissolution processes. Mechanism of growth and
breakdown of the passive films, Different electrochemical reactions, rapid electrochemical reactions, organic electrode
processes, electro catalysis. Polarization: Its causes, decomposition voltage and concentration polarization, polarography,
theory and applications, constant potential electrolysis, anodic stripping voltammetry, cyclic voltammetry.
7.
Solid State Chemistry:
Structural principles in solid state chemistry, bonding in solids-nature of packing in solids-types of sites/voids and their
geometrical considerations – importance of radius ratio, structures of a few binary and ternary compounds – Types of water
in crystals. (b) Defects in solids, defects in stoichiometric compounds – metal excess and metal deficient cases, detection of
defects-consequences of defects-creation of F centers.
8.
Surface Phenomenon:
Adsorption, Freundlich & Langmuir isotherms, Catalysis choice with respect to reaction velocity, selectivity and economics,
Heterogenised homogenous catalysis – catalysis by supported metal ion and metal complexes – shape selective catalysis –
phase transfer catalysis – Biocatalysts/Enzymes as catalysts – solids acid catalysts for automobile emission control.
Catalysts used in well known reactions- catalyst deactivation and reactivation – catalysts for future.
References:
1.
2.
3.
4.
5.
6.
7.
8.
9.
10.
11.
Physical Chemistry-P. W. Atkins (6th Edition, Oxford University Press, 1998).
Chemical Kinetics-K. J. Laidler (Harper & Row, 1987).
Fundamentals of Photochemistry – K. K. Rohatgi-Mukherjee (Wiley Eastern Ltd. 1992).
Molecular Spectroscopy – C. N. Banwell.
Elements of Physical Chemistry – S. Glastone (D. Van Nostrand Company Inc,).
Principles of Physical Chemistry – B. R.Puri, L. R. Sharma, M. S. Pathania (Shoban Lal Nagin Chand &Sons, 1993).
Modern Electrochemistry – Vol. I & II-J. O. M. Bockris & Technology series)
Catalysis – J. C. Kuriacose ( I. I. T Madras, Science & Technology series)
Heterogeneous Catalysis – D. K. Chakravorty (Tata – McGraw Hill).
Principles and Practice of Heterogeneous catalysis – J. M.Thomas and W. J. Thomas.
Polorographic Electrochemistry – L. Meltes.
4
Applied Chemistry Department
Faculty of Technology and Engineering, The M. S. University of Baroda
VADODARA-390001
FIRST SEMESTER M. Sc. -I (APPLIED CHEMISTRY)
ANALYTICAL CHEMISTRY
(Effective from July 2014)
AC –104
4 hrs/week
Maximum Marks: 100
1.
Evaluation of analytical Data :
Terms used in evaluation of Analytical data, Significant figures, Errors-Types, Correction of errors, Precision and
Accuracy, difference between Precision and accuracy. Reporting of analytical data.
2.
Fundamentals of spectroscopy
Principles-Electronic, Rotational and Vibrational Spectra, Selection rules, energy levels, molecular Vibrations, rotational
and Vibrational Raman Spectra of diatomic molecules, Electron Spin resonance.
3.
UV-VIS and IR SpectroscopyUV-VIS - Laws of absorption , absorption by Organic and Inorganic Systems, Instrumentation and Applications. IR-modes
of vibrations in polyatomic molecules, Instrumentation, Fourier Transform methods, interpretation of spectra, Applications.
4.
Thermal AnalysisThermo gravimetric analysis (TGA, DTA), Differential Scanning calorimetry–Instrumentation and Applications.
5.
Atomic Absorption and Emission Spectroscopy:
Atomic absorption Spectroscopy (AAS)-theoretical principles and instrumentation in Absorption flame photometry,
Analytical Applications. Flame emission Spectroscopy – principles, apparatus and applications. ICP-AES (Inductively
coupled plasma atomic emission spectroscopy)
6.
ESR and Mossbauer Spectroscopy:
Principles, Instrumentation and Analytical applications of both the techniques.
7.
Chromatography:
Introduction, Classification, Adsorption and Partition Chromatography, Exclusion chromatography, Ion Exchange
Chromatography, TLC, GC, HPLC, .Application in qualitative and quantitative analysis.
8.
Mass Spectroscopy:
Introduction to Mass Spectrometer, Application of Mass Spectrometer in Structure elucidation and Molecular Weight
determination.
Books Recommended
1.
2.
3.
Instrumental methods of chemical analysis by Willard Merrit & Dean.
Instrumental methods of chemical analysis by Ewing.
Instrumental methods of chemical analysis by B. K. Sharma
5
Applied Chemistry Department
Faculty of Technology and Engineering, The M. S. University of Baroda
VADODARA-390001
SECOND SEMESTER M.Sc. -I (APPLIED CHEMISTRY)
CHEMICAL PROCESS INDUSTRIES-I (CPI-I)
(Effective from July 2014)
4 hrs/week
Maximum Marks: 100
AC – 201
1.
Chemical Processing and routes to Synthesis of Inorganic Materials
Chemical Processing – general concepts; Soft chemistry routes - Sol-gel method of synthesis, intercalation, ion exchange
method. Deposition of thin films-CVD technique, Liquid phase epitaxy, vapour phase epitaxy, molecular beam epitaxy,
Spray pyrolysis. High purity crystal growth. Microwave assisted synthesis.
2.
Paints and Inorganic Pigments
Pigments - Manufacture of white, black and basic colour Inorganic Pigments, characteristics. Constituents of paints,
formulation of paints for various purposes, manufacture of paints, Special paints, Emulsion paints.
3.
Ceramics
Manufacture and uses of following classes of ceramic materials - Refractories, Abrasives, Pottery and Porcelain, Enamels.
4.
Glass Manufacture
Basic concepts in glass making- role of network formers, network modifiers and intermediate glass making oxides.
Manufacture of ordinary glass – melting, Shaping, Annealing; Varieties of glass, Special glasses.
5.
Industrial Carbon
Manufacture of various carbon modifications - Lamp black, carbon black, Acetylene black activated carbon by chemical
activation and gas activation process. Reactivation, regeneration of activated carbon, Applications. Manufacture of graphite
– and amorphous carbon electrodes, carbon fibres.
6.
Advanced Cementitious materials
Manufacture of Portland cement-Setting and hardening of cement, Special cements, Colored cements, Blended cementsadditives (plasticisers, organic additives) for quality improvements.
7.
Water Conditioning for Industry
Sterilization and disinfection of water chemical and physical methods of sterilization, desalination, Demineralisation, RO,
Electrodialysis.
8.
Nuclear Industries
Nuclear reactions, fission and fusion reactions, Nuclear Fuels, Nuclear reactors, Processing nuclear materials, Isotopes and
Isotope separation, Heavy water, protection from radioactivity waste disposal.
REFERENCES:
1.
2.
3.
4.
5.
6.
Industrial Chemistry – B. K. Sharma ( Goel Publishing House, Merrut ) 1998.
Dryden’s outlines of Chemical Technology – Gopala Rao and Sitting (East-West Press.)
Shreeve’s Chemical Process Industries – George T. Austin ( Mograw Hill Intl. Edn.)
Speciality Inorganic Chemicals Ed. By W. E. Thomson (Royal Society of Chemistry )1996
Reigel’s Industrial Chemistry – James. A, Kent. (CBS Publishers ).
Chemical Approaches to Synthesis of Inorganic Materials – CNR Reo (Wiley Eastern)
6
Applied Chemistry Department
Faculty of Technology and Engineering, The M. S. University of Baroda
VADODARA-390001
SECOND SEMESTER M.Sc. –I (APPLIED CHEMISTRY)
CHEMICAL PROCESS INDUSTRIES-II (CPI-II)
(Effective from July 2014)
AC-202
4 hrs/week
Maximum Marks: 100
1.
Fermentation:
Complete yeast dissimilation, Factors for successful fermentation process and abilities of selected microorganisms,
manufacturing processes of industrial alcohol, acetone & butanol and penicillin by fermentation methods.
2.
Penicillin Fermentation:
Introduction, Terminology of various penicillins, Therapeutic uses, chemistry of penicillin, chemical changes during
fermentation, commercial production of penicillin – surface culture and submerged culture fermentations. Recovery of
penicillin, Disposal of wastes.
3.
Man Made Fibers:
Chemistry, manufacturing and uses of Nylons (6 and 66), Polyesters, Acrylics.
4.
Cellulose Industries:
Introduction – structure, chemical and physical properties, Derivatives (esters, ethers) of cellulose, Rayon Manufacturing.
5.
Petroleum Refining operations:
Crude oil exploration, theories of origin of petroleum, Bubble tower refining, chemical purification of refined fractions,
Knocking, Octane and Cetane number.
6.
Petroleum Reforming operations:
Methods to increase octane number of Gasoline, Pyrolysis and cracking – fixed bed and moving bed catalytic cracking,
reforming and isomerization.
7.
Explosives
Characteristics, synthesis, physical, chemical biological effects and uses.
Explosives – Dynamite, TNT, TNT AN, RDX, PETN, Atom bomb, hydrogen bomb.
8.
Military Gases;
Characteristics, synthesis, physical, chemical and biological effects and uses
Military gases – Nitrogen mustard, phosgene, organo phosphoric compounds, screening smokes, Hexachloro ethane, oil
vapour mists.
REFERENCES
1.
2.
3.
4.
5.
6.
7.
8.
Cellulose Chemistry and its applications eds. T.P.Nevell and S. H. Zeramian.
Recent Advances in the Chemistry of Cellulose and Starch ed. J. Honeyman.
A Textbook of Synthetic Drugs – G. D. Tyagi and M. Yadav. (Anmol Publications ).
An Introduction to Synthetic Drugs and Dyes – Raokm Chawthe, Shah and Karnik (Himalaya Publishing House).
Outlines of Chemical Technology. C. E. Dryden.
Industrial Fermentation ed. By C. A. Undercoffler and Richand D. J. Hickery vol I & II.
Biochemical and Biological Engineering Science vol I ed. N. Blakeboough (Academic press).
Chemistry and Technology of Explosives – Tadeusz Urbanski vol I-IV (Pergamon Press).
7
Applied Chemistry Department
Faculty of Technology and Engineering, The M. S. University of Baroda
VADODARA-390001
SECOND SEMESTER M. Sc.-I (APPLIED CHEMISTRY)
MATERIALS SCIENCE
(Effective from July 2014)
AC-203
4 hrs/week
Maximum Marks: 100
1.
Strength of materials:
Elastic, anelastic and viscoelastic behavior, stress-strain curves, anelastic behavior, viscoelastic behavior, spring-dashpot
models, fracture in solids, ductile fracture and brittle fracture, methods of protection against fracture.
2.
Science of Nanomaterials (I):
Behavior of materials at nanometer scale, chemical methods of synthesis of nanomaterials, gold nanoparticles, carbon
nanotubes.
3.
Science of Nanomaterials (II):
Introduction to supramolecular chemistry, self assembly and supramolecular interactions, bionanotechnology,
characterization of nanomaterials, AFM, STM, TEM.
4.
Membrane materials and Membrane technology:
Types of materials for membrane applications, polymeric membranes, asymmetric membranes, surface modifications for
membrane applications, concepts of reverse osmosis, ultrafiltration and electrodialysis.
5.
Liquid Crystalline Materials – Chemistry and applications: Thermotropic & Lyptropic liquid crystals, structure and property
relationship, Smectic, nematic &cholestric liquid crystals, globular and discotic liquid crystals, liquid crystalline polymers.
Applications of liquid crystals in chemistry, electronics, medicine and non destructive testing.
6.
Lubricants:
Characteristics, Functions, Classification of lubricants: solid, semi solid and liquid lubricants and their properties. Different
types of Lubricants: Synthesis and Applications, bio lubricants and emulsions: O/W and W/O emulsions.
7.
Macrocyclic materials I:
Chemistry, Methods of preparations and Applications of Fullerenes
8.
Macrocyclic materials II:
Chemistry, Methods of preparations and Applications of Calixarenes and Cyclodextrins
REFERENCES:
1.
2.
3.
4.
5.
6.
7.
8.
9.
10.
Speciality Inorganic Chemicals ed. By W.E.Thomson (Royal Society of Chemistry) 1996.
Inclusion Compounds Vol. 4, Ed. by J. L. Atwood, J. E. D. Davies and D.D. McNicol (Oxford University Press), 1991.
Concise Inorganic Chemistry – J.D.Lee(Chapman & IIall).
Modern Aspect of Inorganic Chemistry Emeleus and Anderson (Universal Books, Delhi)
Modern Aspect of Inorganic Chemistry Emeleus and Sharp (Universal Books, Delhi)
Introduction to Superconductivity – CNR Rao (Wiley Eastern) (University Press, Longman).
Liquid Crystals and plastic Crystals eds. P.A. Winsor and G.W. Gray vol. I & II (John Wiley & sons).
Molecular structure and properties of Liquid crystals, G.M. Gray.
Liquid Crystals – S. Chandrasekhar (Cambridge University Press).
Nanomaterials : Synthesis, Properties and Application- edited by A.S. Edelsein, R.C. Cammarate (IOP publication).
8
Applied Chemistry Department
Faculty of Technology and Engineering, The M. S. University of Baroda
VADODARA-390001
SECOND SEMESTER M. Sc. -I(APPLIED CHEMISTRY)
DRUGS
(Effective from July 2014)
AC-204
4 hrs/week
Maximum Marks: 100
1.
Anitviral agents
Agents involving inhibition of early stage of viral replication; Agents interfering with viral nucleic acid replication; Agents
affecting translation on cell ribosomes
2.
Antihypertensive agents
Drugs acting at or near post – ganglionic nerve endings; Adrenergic neuron blocking agents; Drugs acting directly on
smooth muscles; Centrally acting sympathomimetic agents; β – adrenergic blocking agents
3.
Hypoglycemic agents
Biguanides, Sulfonyl ureas, plane and mixed insulin
4.
Antibiotics.
Natural and semisynthetic Penicillins, Cephalosporins, Tetracyclins, Macrolides, Aminoglycosides.
5.
Antimalarials
Cinchona Alkaloids, 4 – Aminoquinolines, 9 – aminoacridines, 8 – Aminoquinolines, Pyrimidines, Biguanides, Sulfones
6.
Anti histaminic agents
(i) H1 – Antagonists - Aminoalkylether Derivatives;
(ii)
H2 – Antagonists
7.
Antipyretics and Analgesics
Salicylic acid derivatives, Antipyrine, Melubrin, Novalgin, Amidone, Pethidine
8.
Narcotics and Non-Narcotic analgesics
Morphine, codeine, Heroin; Paracetamol, Phenylbutazone, Ibuprofen; Piroxicam (Non selective COX inhibitors);
Nimesulide, Meloxicam (Selective COX – 2 inhibitors)
REFERENCES:
1.
2.
Medicinal Chemistry and Drug Discovery Vol. I - III by Burger Alfred, edited by Manfred. E. Wolff, 5th Edn., (1995),
John Wiley & Sons Inc.
Medicinal Chemistry by Gareth Thomas, (2000), John Wiley & Sons Inc, NY, Toronto.
9
Applied Chemistry Department
Faculty of Technology and Engineering, The M. S. University of Baroda
VADODARA-390001
FIRST SEMESTER M. Sc.-II (APPLIED CHEMISTRY)
PETROCHEMICALS
(Effective from July 2014)
AC-301
4 hrs/week
Maximum Marks: 100
1.
General Principles involved in the production of Petrochemicals.
Petrochemicals obtained from synthesis gas and natural gas (mainly methane)
Methanol, Chloro methanes.
2.
Petrochemicals obtained from synthesis gas and natural gas
Formaldehyde and Perchloroethylene
3.
Products obtained from Acetylene, Trichloroethylene,
Vinyl chloride and Acetaldehyde
4.
Products obtained from Ethylene
Ethylene oxide, Ethanol amines, Ethylene chloride.
5.
Products obtained from propylene/propane:
Acrylonitrile, Chemicals by Oxo process
6.
Products obtained from propylene/propane:
Isopropyl benzene (Cumene) Isopropanol, Isoprene, Acetone
7.
Products obtained from Butane
Butadiene
8.
Aromatics Products
Phenol by Cumene process
Phenol by Raschig process
Benzene
References:
1.
2.
3.
4.
5.
6.
Chemistry and Technology of Basic Organic and Petrochemical Synthesis, Vol. 1 and 2.
N. N. Lebedev. Mir Publishers
Dryden’s Outlines of Chemical Technology – Gopala Rao and Sittig (East-West press)
Petrochemicals Industry – Market and Economics; A. B.Hahn. McGraw hill Publishers.
Handbook of Petrochemicals and Processes; Margaret Wells. Gower. 1991.
Industrial Chemistry: Harish kumar Sarup and Sons Publishers, New Delhi.
10
Applied Chemistry Department
Faculty of Technology and Engineering, The M. S. University of Baroda
VADODARA-390001
FIRST SEMESTER M. Sc.-II (APPLIED CHEMISTRY)
SURFACTANTS
(Effective from July 2014)
AC-302
4 hrs/week
Maximum Marks: 100
1.
Introduction:
General considerations, Economic considerations, Problems of surfactant industries, technical considerations, trade
names, classification of surfactants.
2.
Anionic surfactants:
Synthesis and manufacturing process - Carboxylic acids, Sulphuric esters, Alkane sulphonates, Mahogany and
petroleum sulphonates.
3.
Cationic surfactants:
Synthesis and manufacturing process, Non – quaternary nitrogen bases, Quaternary nitrogen bases – other bases.
4.
Non ionic and Ampholytic surfactants:
General Review, Hydrophilic intermediates, Polyethenoxy surfactants, Polyhydroxy surfactants, Ampholytic
surfactants. New surfactant types : Organosilicon compound, Highly Fluorinated compounds, Polymeric surfactants,
Introduction to Gemini surfactants: synthesis and properties
5.
Physical and Colloidal Chemistry of Surfactants:
Some recent advances in surface physics
a. A-Solid interfaces
b. B-Liquid interfaces
c. C-Liquid – Liquid interfaces
d. D-Solid – Liquid interfaces
6.
Bulk properties of surfactants :
Foaming, wetting and related gross effects
7.
Emulsification :
Dispersion and Detergency, Special Physical forms of surfactants
8.
Practical Applications of Surfactants :
Washing of fabrics & textile materials, medical & cosmetic applications, surfactants in metal & minerals technology,
Surfactants in Rubber, polymers, plastics and paints, Surfactants in petroleum and chemical process industries
References:
1. Surface Active Agents and Detergents., vol. 1 and 2 Anthony M. Schwartz and James W. Perry. (Interscience
Publishers)
2. Surfactants and Interfacial Phenomena – M. J. Rosen (John Wiley & Sons Inc. 1978).
3. Solvent Properties of Surfactant Solutions – K. Shinoda (Marcel Dekker Inc. 1967).
11
Applied Chemistry Department
Faculty of Technology and Engineering, The M. S. University of Baroda
VADODARA-390001
FIRST SEMESTER M. Sc.-II (APPLIED CHEMISTRY)
HEAVY CHEMICALS
(Effective from July 2014)
AC-303
4 hrs/week
Maximum Marks: 100
1.
Sulphuric acid Industries:
Methods of Production (Contact process): - Physicochemical principles involved, catalysts used, major engineering
problems, economics.
2.
Nitrogen Industries:
Ammonia – methods of production (Haber’s process): Physicochemical principles involved, catalysts used,. major
engineering problems, economics.
Nitric acid: methods of production (Arc process, Birkland and Eyde’s process), Physicochemical principles involved,
catalysts used,. major engineering problems, economics.
3.
Chloroalkali Industries:
Caustic soda, Soda ash and Chlorine-methods of production, physico chemical principles involved, engineering problems
and economics.
4.
Manufacture of Catalysts:
Preparative methods, Metals as catalysts, supported metal as catalyst; Synthesis of support materials; Oxides, mixed oxides,
monolithic supports. Synthesis of zeolites including template methods; Forms of catalysts and extrusion processes.
5.
Phthalic Anhydride industry:
Manufacture and Uses.
6.
Caprolactam :
(a) Raw materials, Manufacturing based on cyclohexane
i)
Hydrogenation of benzene
ii) Oxidation of cyclohexane
iii) Dehydrogenation of Ketone alcohol ( KA-oil) mixture
iv) Oximation of cyclohexanone and Beckmann rearrangement.
v) Synthesis of various oximating agents.
(b) Direct photo-oximation of cyclohexane
7.
Acetic Acid industry
i) Manufacture from acetaldehyde by oxidation.
ii) Manufacture from methanol by carbonylation
iii) Applications
8.
Manufacture of Analgesics and Anti-pyretic drugs.
References:
1
2
3
4
5
Outlines of Chemical Technology – C. E. Dryden, Ed. By Gopala Rao.
Chemical Process Industries – Shreeve’s (McGraw International)
Handbook of Industrial Chemistry by Riegal.
Catalyst Manufacture – A. B. Stiles, Marcel Dekker N. Y. 1983.
Industrial Chemistry – B. K. Sharma, 2006.
12
Applied Chemistry Department
Faculty of Technology and Engineering, The M. S. University of Baroda
VADODARA-390001
SECOND SEMESTER M. Sc. -II(APPLIED CHEMISTRY)
AGROCHEMICALS AND FERTILIZERS
(Effective from July 2014)
AC-401
4 hrs/week
Maximum Marks: 100
CROP PROTECTION
1.
Methods of pest control:
Mechanical and physical methods, Biological control methods, use of resistant varieties, chemical control methods etc.
Pest : Invertebrates, Vertebrates, Wild life/domestic animals, Weeds
Disease causing agents – fungi, viruses, bacteria
2.
Biocide chemistry:
Pesticides: Definition, formulations, classification,
(i) Fungicides Inorganic: Copper fungicides, Sulphur fungicides; Organic: Carbamic acid derivatives, Chlorinated
aromatics and heterocyclic fungicides; Systemic fungicides
(ii)Insecticide- Inorganic: Stomach poisons, contact poisons, Organic:Organochlorines, organophosphorus, carbamates,
nitrophenols.Attractants/pheromones, repellents and antifeeding compounds, fumigants.
(iii) Rodenticides
(iv) Herbicides – classification and Chemistry, Plant growth hormones
(v) Biopesticides
3.
Methods of pesticidal applications and control release systems.
4.
Agrochemicals for future and biofertilizers.
FERTILIZERS
5.
Introduction to Inorganic Fertilizers: Classification.
Nutrient requirement of crops and function, soil condition, over view of fertilizer industry, basic raw materials for
fertilizer manufacture.
6.
Phosphatic fertilizers:
Manufacture of phosphoric acid. Manufacture of ordinary super phosphate and triple super phosphates.
7.
Mixed Fertilizers:
Bulk Blending, intermediates used in bulk blending, fluid mixtures, solution fertilizers and suspension fertilizers.
Compound fertilizers, Nitrophos and ammonium phosphates (mono and di)
8.
Nitrogenous fertilizers:
Manufacturing process and agrochemicals properties of
(a)
Urea
(b)
Calcium cynamide(slow release nitrogen fertilizer)
References:
1
2.
3.
4.
5.
6.
7.
8.
Crop protection in the Tropics–J.P. Singh.
Pest Control – A survey, Arthur Woods, McGraw Hills.
Modes of action of herbicides - F. M. Ashton and A. S. Crafts.
The Technology of Mineral Fertilizers, I. Mo;dpnvan, N. Popovici and C. Chivu.
Fertilizer Nitrogen: Its Chemistry and Technology by Y.Sauchell (Reinhold, 1964)
Outlines of Chemical Technology by C. E. Dryden, ed. By Gopala R.
Reigal’s Handbook of Industrial Chemistry 9th edn. Ed. Jame A. kent.
Industrial Chemistry by B. K. Sharma.
13
Applied Chemistry Department
Faculty of Technology and Engineering, The M. S. University of Baroda
VADODARA-390001
SECOND SEMESTER M. Sc. -II (APPLIED CHEMISTRY)
DYES AND TEXTILE AUXILIARIES
(Effective from July 2014)
AC-402
1.
4 hrs/week
Maximum Marks: 100
Introduction
Historical development of synthetic Dyes - Introduction, Nomenclature, colour and constitution of dyes
2.
Classification of Dyes.
(i)
Based on structure
(ii)
Based on mode of application to fibers
(iii)
Types – Acid dyes, Basic dyes, Direct dyes, Mordant dyes, Vat dyes, Food dyes
3.
Dye Intermediates - I
Unit processes for Nitration – Nitrating agents, kinetics and mechanism of Nitration, Nitration of benzene,
chlorobenzene and Toluene
Continuous and batch Nitration processes.
Amination by reduction, methods of reduction, commercial manufacture of Aniline and m-nitro aniline.
4.
Dye Intermediates – II
Sulfonation – Sulfonating agents, chemical and physical factors in sulfonation, sulfonation of benzene, toluene,
Naphthalene and Anthraquinone
Continuous and Batch Sulfonation.
Halogenation, mechanism, chlorination of paraffinic hydrocarbons – benzene and toluene, Alkylation.
5.
Study of few typical members (non-benzidine) of various classes of dyes :
(i)
(ii)
(iii)
(iv)
(v)
(vi)
(vii)
(viii)
Acidic azodyes –tartrazine
Azodyes – Direct red 23
Basic dyes – saframine, malachite green
Vat dyes
Indigoid and thioindigoid dyes.
Heterocyclic dyes
Reactive dyes
Disperse dyes
6.
Non – Textile uses of dyes:
Dyes in medicine, leather, paper, colour photography and electro photography, food and drugs, cosmetics, displays and
laser dyes.
7.
Types of fibres and theories of dyeing methods.
8.
Textile auxiliaries:
Fluorescent brighteners and optical whitening agents, crease resistant agents, water repellent finishing agents, fire
proofing agents.
References:
1.
2.
3.
4.
5.
Synthetic Dyes – Vol. 1 to 7 ed. By Venkat Raman
Synthetic Dyes by Lubs
Dyes and Intermediates by Fiertz, David and Blangley
Science of surface coating ed. By Chatfield
Handbook of Synthetic dyes an pigments by K. M. Shah, 2 nd Edn. Multitech Publishing Co.
14
Applied Chemistry Department
Faculty of Technology and Engineering, The M. S. University of Baroda
VADODARA-390001
SECOND SEMESTER M. Sc. -II (APPLIED CHEMISTRY)
INDUSTRIAL POLLUTION
(Effective from July 2014)
AC-403
1.
2.
3.
4.
5.
6.
7.
8.
4 hrs/week
Maximum Marks: 100
Toxicology of environmental pollutants: Toxicology – major areas in toxicology, toxicity – types, dosage – standard
notations – LD50, ED50, TLV, MAC, Toxic Substances – classes and routes of absorption, waste minimization, pollution
prevention and First Aid – occupational health, concepts of green chemistry.
Chemical Toxicology: Biochemical effects of Hg, Cd, Pb, As, Cu and their speciation, Biochemical effects of cyanide and
pesticides, DDT in the food chain MIC.
Waste water treatment Technologies:- Terminologies, water pollutants – sources, criteria for detection - pH, acidity,
alkalinity, Dissolved solids. - TS, TDS, TSS, DO, BOD, COD, TOC – Treatment levels - pretreatment, primary, secondary
and tertiary treatment, sludge disposal.
Air pollution: Air pollutants and their toxic effects – CO, CO2 (green house effect) NOx, SOx, H2S Ozone – effects of
ozone layer by NOx and fluoro carbons, particulates – sources, toxic effects, smog – classical, photochemical, sampling
and monitoring of air pollutants – control of air pollutants. Motor vehicular pollution and control.
Radiological contamination and impact of large Radiation sources on the Environment: Sources of contamination – Natural,
Man Made –Breeder reactors, Fuel reprocessing, Nuclear weapons. Radioactive contamination in Drinking water,
Regulation and control. Medical applications Radiopharmaceuticals, Radioprotiens Isotope power pace makers, Isotope
satellite power unit – summary of benefits and environmental impact.
Thermal pollution and Environment: Sources – central power station, return of irrigated water, sewage water, different
water ways, thermophillic bacteria. Effect of temperature on water quality, mechanism of heat dissipation, techniques of
heated water discharges, cooling towers, benefits of waste heating cooling ponds.
Automobile pollution and noise pollution.
i.
Automobile exhaust gases: Definition, sources and causes, Effects of automobile pollution, control
measures
ii. Noise pollution: Definition, sound intensity, sources and causes of noise, Effects of noise pollution, control
measures
Waste Management and Recycling-case studies
i.
Plastic Recycling
ii.
Dye Industry
iii.
Evaluation of VOC recovery Systems.
iv.
Utilisation of Flyash.
v.
Fine chemicals
References:
1.
2.
3.
4.
5.
6.
7.
8.
Industrial pollution – N. Irwin Sax ( Van Nostrand Reinhold ) 1974.
Industrial Chemistry _ B. K. Sharma (Goel Publishing House, Meerut) 1998.
Inorganic chemistry – Puri, Sharma and Kalia (Shobhan Lal Naginchandra and Co.) 1995.
Reigel’s Industrial Chemistry – ed. J. A. Kent (CBS Publishers)1997.
Environmental Chemistry –Samir K. Banerjee (Prentice Hall of India ) 1994.
Environmental Chemistry – A. K. De (Willey eastern Ltd.) 1987.
Profitably Preventing Pollution – M. H. Mehta (Ankur Publishing Co.)
Environmental Chemistry of Dyes and Pigments – eds. Abraham Reife and Harold freeman (John Wiley and Sons )
1996.
15
Applied Chemistry Department
Faculty of Technology and Engineering, The M. S. University of Baroda
VADODARA-390001
SECOND SEMESTER M. Sc. -II (APPLIED CHEMISTRY)
POLYMERS, PLASTICS AND RESINS
(Effective from July 2014)
AC-404
4 hrs/week
Maximum Marks: 100
1.
Chemistry of Polymerization:
Chain polymerization, Step polymerization, Miscellaneous polymerization, Copolymerization.
2.
Polymerization Techniques and Synthesis:
Bulk, Emulsion, Dispersion, Melt and Solution polymerization.
Synthesis of some Polymers – isolation, purification and fractionation.
Elastomers, Plastics – Thermoplastic and Thermosetting resins.
Polymer Reactions: Hydrolysis, Acidolysis polymer degradation and anti oxidants.
4.
Molecular weight (MW) determination and Size of Polymers:
Number average (Mn), Weight average (Mw), Sedimentation average (M2) and Viscosity average (Mv) molecular
weights. Derivation of Mn and Mw. MW and degree of Polymerization, Polydispersity and Mw distribution curves.
Determination of MW – Osmometry, Viscometry, Sedimentation, Cryoscopy, Ebulliometry.
Chemical and geometrical Structure of Polymers, Glass transition temperature(GTT), factors effecting GTT, MW and
melting point.
Polymers and X - ray Diffraction – degree of Crystallinity in Polymers, Polymer crystallization, Crystallisability,
Factors affecting crystallinity in Polymers, Spherulites, Helix Structure, Effect of Crystallinity on the properties of
polymers.
5.
Kinetics of polymerization :
Free radical, cationic, anionic, condensation polymerization. Copolymerization.
6.
Polymer solutions :
Thermodynamic treatment of dissolution process, Flory –Huggins theory of polymer solutions, size and shape of
polymers in solution, light scattering.
7.
Polymer processing :
Calendering, die casting, rotational casting, film casting compression moulding, blow moulding etc.
8.
Polymer technology:
Manufacture of polymers, polyethylene and polypropylene, Ziegler – Natta catalysis.
References:
1.
2.
3.
4.
Polymer Science –V. R. Gowarikar, N. V. Vishwanathan & J. Sreedhar (New Age International (P) Ltd., 2001)
Text book of Polymer Science – F. W. Billmeyer (Wiley – Interscience 1971)
Principles of Polymer Chemistry – P. J. Flory (Cornell University Press, 1953)
Physical Chemistry of Polymers – A. Tager (MIR Publishers, 1978)
16
Applied Chemistry Department
Faculty of Technology and Engineering, The M. S. University of Baroda
VADODARA-390001
SECOND SEMESTER M. Sc.-II (APPLIED CHEMISTRY)
INDUSTRIAL CHEMISTRY
(Effective from July 2014)
AC- 405
4 hrs/week
Maximum Marks: 100
1.
Fuels:
Introduction ; Calorific value and its determination; Characteristics of a good fuel; Classification; Advantages and
disadvantages of solid, liquid and gaseous fuels; Coal: Definition, selection, Analysis – proximate and ultimate; Gaseous
fuels: Producer Gas, Water Gas ; carbureted water gas; biogas.
2.
Water Analysis:
Water Hardness: types, units, determination; methods of removal; problems based on hardness. Formation of deposits in
boiler units and heat exchangers – treatment-phosphate method, complexing agents, Alkali treatment, preventing deposit
formation in turbine condensors.
3.
High Polymers:
Classification of polymers; Thermoplastics and thermosetting resins: Properties and uses; elastomers, natural and synthetic
rubber, vulcanization, laminates, fibres; spinning processes.
4.
Vitamins:
Classification and nomenclature; Vitamin activities; metabolic, physiological or biological functions of vitamins; Vitamin
A, Vitamin B complex; Vitamin C: occurance and sources, isolation, absorption, storage and excretion, diseases caused by
deficiency, requirements and structure.
5.
Fats, Oils and Waxes:
Distinction between fats and oils; Properties; Classification; Manufacture of cotton seed and soya bean oil. Waxes –
classification of waxes, some common waxes.
6.
Synthesis, properties and applications of the following materials:
Superconducting materials - concepts, types, high Tc superconductor, Fast ion conductors (NAFION and NASICONS),
inorganic materials in the electronic industry.
Insulating materials- concept, dielectric properties, insulating materials, thermal insulators, semiconductors.
7.
Green Chemistry:
Clean synthesis using alternative reaction media; Super critical solvents in industrial applications, scale up & industrial
applications of clean synthesis including asymmetric synthesis.
8.
Industrial Zeolites and its applications:
MELS (Molecularly Engineered Layered Structures) – pillared layered compounds, clay materials, Zeolites, Feldspars,
Clathrasils, Zeosils, porosils, micro and meso porous compounds – Hetero and iso- poly acids and their salts.
REFERENCES:
1.
2.
3.
4.
5.
6.
7.
Industrial Chemistry – B. K. Sharma ( Goel Publishing House, Merrut ).
Engineering chemistry- Jain and Jain, Dhanpatrai Publishing House
Dryden’s outlines of Chemical Technology – Gopala Rao and Sitting (East-West Press.)
Shreeve’s Chemical Process Industries – George T. Austin ( Mograw Hill Intl. Edn.)
Speciality Inorganic Chemicals Ed. By W. E. Thomson (Royal Society of Chemistry )
Reigel’s Industrial Chemistry – James. A, Kent. (CBS Publishers ).
Chemical Approaches to Synthesis of Inorganic Materials – CNR Rao (Wiley Eastern)
17
Applied Chemistry Department
Faculty of Technology and Engineering, The M. S. University of Baroda
VADODARA-390001
SECOND SEMESTER M. Sc. -II (APPLIED CHEMISTRY)
INSTRUMENTAL METHODS OF CHEMICAL ANALYSIS
(Effective from July 2014)
AC-406
1.
2.
3.
4.
5.
6.
50 Marks
2 hrs /week
Evaluation of Analytical data, problems - based on significant figures, Precision accuracy, Errors, F-test, Q-test, t-test,
Basic concepts in gravimetric and volumetric analysis – expression of metal ion concentration as pM at various stages
of titration.
UV-VIS-IR- problems based on Beer Lamberts Law, force constants, concepts etc, interpretation of spectra.
AAS – problems based on concepts.
Thermal analysis – TGA, DTA, DSC. Problems based on calculation of weight loss, identification of endotherms,
exotherms, interpretation of thermograms.
Chromatographic methods of analysis – HPLC, GC. Problems based on basic concepts, retention time, progress of
reactions, % yield etc.
(a) Interpretation and Application of the following spectral technique towards Structure elucidation of organic
compounds. -Mass spectroscopy, UV Spectroscopy, Infrared spectroscopy, 1H-NMR Spectra, 13C-NMR Spectra.
(b) Structure elucidation using a combination of UV, IR, NMR and Mass Spectral data.
Books Recommended:
1.
2.
3.
4.
5.
6.
7.
R.M. Silverstein; G.Clayton; T.C.Morril, Spectrometric Identification of Organic Compounds, 5 th edition, John Wiley
& sons, New York 1991.
Derome, A.E.”Modern NMR Techniques for Chemistry Research”(1988).
Donald L. Pavia; Gary M. Lampman; george S.Kriz, Introduction to Spectroscopy, Books Cole, New York 2000.
Douglas A. Skoog, Principles of Instrumental Analysis 3re Editiojn, Saunders College Publishing, New Yourk 1985.
H. Gunther, NMR Spectroscopy: Basics, Principles, Concepts and Application in Chemistry, John wiley & Sons, New
York 1995.
J.D. Roberts, Nuclear Magnetic Resonance application to organic chemistry McGraw-Hill, New York, 1959.
Derome, A.E “Modern NMR Techniques for Chemistry Research”(1988)
18
Applied Chemistry Department
Faculty of Technology and Engineering, The M. S. University of Baroda
VADODARA-390001
SECOND SEMESTER M. Sc.-II (APPLIED CHEMISTRY)
INTRODUCTION TO PATENT AND COPY RIGHTS
(Effective from July 2014)
AC- 407
2 hrs/week
Maximum Marks: 25
1.
Introduction to IPR and its tools
Understanding Intellectual Property Rights (IPR)
Introduction to various IPR Tools
2.
Patents
Definition and requirements for filing a patent
Types of Patents relevant to Pharmaceuticals
Parts of Patent
Filing a patent application and its prosecution in India
3.
Rights Conferred by a Patent under Indian Regime
The Indian patent Act, 1970
Infringement of Patent
4.
Literature Search
Importance of Literature Search
Prior Art
5.
American and Europe Patent Systems
American patent System
European Patent System
6.
Trade Marks
Introduction to Trade Mark
Importance of Trade Mark
Matter not protected under Trade Mark
Registration of Trade Mark
Infringement and Remedies available under the Trade Mark Act
7.
Case Laws
19
Applied Chemistry Department
Faculty of Technology and Engineering, The M. S. University of Baroda
VADODARA-390001
FIRST SEMESTER M. Sc. -I(APPLIED CHEMISTRY)
ADVANCED INORGANIC PREPARATIONS
(Effective from July 2014)
AC-107
4 hrs/week
Maximum Marks: 50
Preparation of the following compounds
Double salts
1.
Chrome Alum K2SO4.Cr2(SO4)3.24H2O
2.
Ferrous ammonium sulphate FeSO4(NH4)2SO4.6H2O
Complex salts
1.
2.
3.
4.
5.
6.
Tris ethylene diamine Ni(II) sulphate Ni[(NH2CH2CH2NH2)3]SO4
Tetraammine Cu(II) sulphate [Cu(NH3)4]SO4
Sodium trioxalato ferrate trihydrate Na3[Fe(C2O4)3].3H2O
Potassium trioxalatochromate(III) K3[Cr(C2O4)3].3H20
Hexa-ammine nickel(II) chloride [Ni2(NH3)6]Cl2
Hexa-ammine Cobalt(III) chloride [Co3(NH3)6]Cl2
Binuclear Complexes
1.
Binuclear Cu(II) Salen
Macrocyclic Complexes
1.
Manganese Phthalocyanin MnC6H4(CN)4
Inorganic materials
1.
Lead Chromate PbCrO4
2.
Sodium thiosulphate Na2S2O3.5H2O
Any other new preparation of current interest.
20
Applied Chemistry Department
Faculty of Technology and Engineering, The M. S. University of Baroda
VADODARA-390001
FIRST SEMESTER M. SC. -I(APPLIED CHEMISTRY)
ADVANCED ORGANIC PREPARATIONS
(Effective from July 2014)
AC-108
4 hrs/week
Maximum Marks: 50
Preparation of the following compounds
1.
Preparation of Methyl orange from sulphanilic acid
2.
Preparation of p-nitroaniline from Acetamide
3.
Preparation of m-nitroaniline from m-dinitrobenzene
4.
Preparation of 4-n-butoxy benzoic acid from p-hydroxy benzoic acid
5.
Preparation of Nerolin from B-Naphthol
6.
Preparation of dibenzal acetone from benzaldehyde
7.
Preparation of Cinnamic acid from Malonic acid
8.
Preparation of Benzoic acid from Benzanilide.
9.
Preparation of Adduct of anthracene and maleic anhydride.
10.
Preparation of 2,5-Dihydroxy acetophenone from Hydroquinone.
Any other new preparation of current interest.
21
Applied Chemistry Department
Faculty of Technology and Engineering, The M. S. University of Baroda
VADODARA-390001
FIRST SEMESTER M. SC. -I(APPLIED CHEMISTRY)
ADVANCED ORGANIC PREPARATIONS
(Effective from July 2014)
AC-109
4 hrs/week
Maximum Marks: 50
1.
Investigation of the hydrolysis of an ester in the presence of acid and calculation of energy of activation.
2.
Investigation of the reaction between potassium persulphate & potassium iodide and calculation of rate constant.
3.
Determination of partition coefficient of I2 between H2O and CCl4.
4.
Investigation of inversion of cane sugar or sucrose using a polarimeter.
5.
Mutual solubility curve of two immiscible liquids and the critical solution temperature of the phenol water system and
determination of the effect of electrolyte on the critical solution temperatures of Phenol water system.
6.
Determination of the solubility product constant (ksp) of a sparingly soluble salt through the measurement of the
conductance of its saturated solution.
7.
Finding the molecular weight of the given polymer by the viscosity method.
8.
Determination of concentration of the ferric ions by spectroscopic technique.
9.
Finding the critical micelle concentration of a surfactant solution by conductivity method.
10. Adsorption
11. Electrochemistry
Any other new experiment of current interest.
22
Applied Chemistry Department
Faculty of Technology and Engineering, The M. S. University of Baroda
VADODARA-390001
SECOND SEMESTER M. SC. -I(APPLIED CHEMISTRY)
CHEMICAL AND INDUSTRIAL ANALYSIS AND QUALITY CONTROL (PRACTICALS)
(Effective from July 2014)
AC-208
4 hrs/week
Maximum Marks: 50
1.
To determine the molecular weight of the given amine by non- aqueous titration.
2.
To determine the molecular weight of the given organic acid by non -aqueous titration.
3.
To determine the percentage purity of ascorbic acid.
4.
To determine the concentration of the ferric ions by spectroscopic technique.
5.
To determine the strength of HCl & CH3COOH Solutions in mixture by using pH meter.
6.
To determine the dissolved oxygen present in a water sample.
7.
To determine C. O. D. in given water sample.
8.
To determine % of protein in a given sample of milk.
9.
To determine % of Vitamin C in given tablet.
10. Determination of milk adulteration by Conductivity Measurement.
Any other new experiment of current interest.
23
Applied Chemistry Department
Faculty of Technology and Engineering, The M. S. University of Baroda
VADODARA-390001
FIRST SEMESTER M. SC. -II(APPLIED CHEMISTRY)
ADVANCED ORGANIC SYNTHESIS
(Effective from July 2014)
AC-308
12 hrs/week
Maximum Marks: 75
1.
Preparation of Anthranilic Acid from Phthalic anhydride
2.
Preparation of Sulphadrug (p-Aminobenzene sulphanilamide
3.
Preparation of 4-n-butoxy phenyl azo 4’benzoic acid from p-aminobenzoic acid
4.
Preparation of chalcone from benzene
5.
N, N, - Diethyl m – Toluamide from m – toluic acid
6.
Preparation of Acetanilide from Acetophenone
7.
Preparation of Acridone from Anthranilic acid
8.
Synthesis of Anthraquinone from Phthalic anhydride
9.
Preparation of Reactive Dye from sulphanilic acid
10.
p- Nitro iodobenzene from acetanilide
11.
Chloramine –T from Toluen (via p-Toluene Sulfonyl Chloride)
(II) Separation of Ternary Mixtures based on following types
1.
Acid + Phenol + Neutral (APN)
2.
Acid + Base + Neutral (ABN)
3.
Phenol + Base + Neutral (PBN)
4.
Acid + Phenol + Base (APB)
Any other new experiment of current interest.
24