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Chemical Hygiene Plan
Part B
Table 1: Hazardous chemical classes (With specific chemical listing)
Use in conjunction with Table 3 “Incompatible Chemical Classes”
Group 1: Inorganic Acids
Hydrogen fluoride (anhydrous)
Chlorosulfonic acid
Nitric acid
Hydrochloric acid (aqueous)
Oleum
Hydrofluoric acid (aqueous)
Phosphoric acid
Hydrogen chloride (anhydrous)
Sulfuric acid
Group 2: Organic Acids
Propionic acid
Acetic acid
Rosin oil
Butyric acid (n-)
Tall oil
Formic acid
Group 3: Caustics
Caustic soda solution
Caustic potash solution
Group 4: Amines & Alkanolamines
2-Methyl-5-ethylpyridine
Dimethylamine
Aminoethylethanolamine
Ethylenediamine
Aniline
Monoethanolamine
Monoisopropanolamine
Morpholine
Diethanolamine
Pyridine
Hexamethylenetetramine
Diethylamine
Triethanolamine
Triethylenetetramine
Diethylenetriamine Diisopropanolamine
Trietylamine
Trimethylamine
Group 5: Halogenated Compounds
Chlorohydrins, crude
Ethylene dichloride
Allyl chloride
Dichlorobenzene
1,1,1-Trichloroethane
Carbon tetrachloride
Dichlorodifluoromethane
Dichloropropane
Trichloroethylene
Chlorobenzene
Chloroform
Hexamethylenediamine
Trichlorofluoromethane
Ethyl chloride
Ethylene dibromide
Group 6: Alcohols, Glycols & Glycol Ethers
Dipropylene glycol
Hexanol
Allyl alcohol
Dodecanol
Nonanol
Amyl alcohol
Ethyl alcohol
Furfuryl alcohol
1,4-Butanediol
Ethyl butanol
Glycerine
Butyl alcohols
2-Ethylbutyl alcohol
Dextrose solution
Heptanol Polypropylene
glycol methyl ether
Diacetone alcohol
Propyl alcohols
Diethylene glycol
Propylene glycol
Diisobutyl carbinol 2Ethylhexyl alcohol Ethylene
glycol
Sorbitol
Octanol
Undecanol
Butylene glycol
Corn syrup
Cyclohexyl alcohol
Decyl alcohols
Triethylene glycol
Chemical Hygiene Plan
Part B
Group 7: Aldehydes
Furfural
Acetaldehyde
Hexamethylenetetramine
Acrolein (inhibited)
Isoctyl aldehyde
Butyraldehyde
Methyl butyraldehyde
Crotonaldehyde
Methyl formal
Decaldehyde
Propionaldehyde
Formaldehyde solution
Valeraldehyde
Group 8: Ketones
Diisobutyl ketone
Acetone
Isophorone
Acetophenone
Mesityl oxide
Camphor oil
Cyclohexanone
Group 9: Saturated Hydrocarbons
Methane Nonane
Butane
Paraffines
Cyclohexane
Pentane
Ethane
Petrolatum
Heptane
Petroleum Ether
Hexanes
Propane
Isobutane
Propylene butylene polymer
Group 10: Aromatic Hydrocarbons
Benzene
Ethyl benzene
Cumene
Naphthalene
Coal tar pitch
Toluene
Diethylbenzene
Triethyl benzene
Dodecyl benzene
Xylene
Group 11: Olefins
Isobutylene
Butylene
1-Octene
1-Decene
1-Pentene
Dicyclopentadiene
Polybutene
Ethylene
Propylene
1-Heptene
Propylene butylene polymer
Nonene
1-Hexene
Group 12: Petroleum Oils
Gasolines
Asphalt
Jet fuels
Group 13: Esters
Cottonseed oil
Methyl acetate
Amyl acetate
Croton oil
Methyl amyl acetate
Amyl tallate
Dibutyl phthalate
Propyl acetates
Chemical Hygiene Plan
Butyl acetates
Butyl benzyl phthalate
Part B
Epoxidized vegetable oils
Ethyl acetate
Ethyl diacetate
Castor oil
Resin oil
Tanner's oil
Wax, carnauba
Glycol diacetate
Group 14: Monomers & Polymerized Esters
Butyl acrylate
Acrylic acid
Ethyl acrylate
Acrylonitrile
Methyl acrylate
Propiolactone
Butadiene
Vinyl acetate
Isoprene
Vinyl chloride
Vinylidene chloride
Vinyl toluene
Styrene
Group 15: Phenols
Cresols
Carbolic oil
Nonylphenol
Creosote, coal tar
Phenol
Group 16: Alkylene Oxides
Propylene oxide
Ethylene oxide
Group 17: Cyanohydrins
Ethylene cyanohydrin
Acetone cyanohydrin
Adiponitrile
Group 18: Nitriles
Acetonitrile
Group 19: Ammonia
Ammonium hydroxide
Group 20: Halogens
Chlorine
Bromine
Group 21: Ethers
Group 22: Phosphorous, elemental
Diethyl ether (ethyl ether)
1,4-Dioxane
Isoprophyl ether
Tetrahydrofuran
Group 23: Sulfur, molten
Group 24: Acid anhydride
Acetic anhydride
Propionic anhydride
Chemical Hygiene Plan
Part B
Table 2: Incompatible Chemical Classes
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
Inorganic Acids
Organic Acids
Caustics
Amines and Alkenoamines
Halogenated Compounds
Alcohols, Glycols, & Glycol
Ethers
Aldehydes
Ketones
Saturated Hydrocarbons
Aromatic Hydrocarbons
Olefins
Petroleum Oils
Esters
Monomers
&
Polymerizable Esters
Phenols
Alkylene Oxides
Cyanohydrins
Nitriles
Ammonia
Halogens
Ethers
Elemental Phosphorous
Sulfur, Molten
Acid Anhydrides
1
x
x
x
x
x
x
x
2
x
x
To be used with Table 3
3
x
4
x
CHEMICAL CLASSES (With
specific listing)
5
6
x
x
x
x
x
x
7
x
8
9
x
x
10
x
11
12
x
x
x
x
x
x
x
x
x
x
x
x
x
x
x
x
x
x
x
x
x
x
x
x
x
x
x
13
x
x
x
x
x
x
14
x 15
x
x
x
x
x
x
x
x
x
x
x
x
x
x
x
x
17
18
x
19
x
x
x
x
x
x
x
16
x
x
x
x
x
x
x
x
x
x
x
x
x
x
x
x
20
x
x
21
22
x
23
24
Chemical Hygiene Plan
Part B
Chemical Hygiene Plan
Part B
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