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Chemical Hygiene Plan Part B Table 1: Hazardous chemical classes (With specific chemical listing) Use in conjunction with Table 3 “Incompatible Chemical Classes” Group 1: Inorganic Acids Hydrogen fluoride (anhydrous) Chlorosulfonic acid Nitric acid Hydrochloric acid (aqueous) Oleum Hydrofluoric acid (aqueous) Phosphoric acid Hydrogen chloride (anhydrous) Sulfuric acid Group 2: Organic Acids Propionic acid Acetic acid Rosin oil Butyric acid (n-) Tall oil Formic acid Group 3: Caustics Caustic soda solution Caustic potash solution Group 4: Amines & Alkanolamines 2-Methyl-5-ethylpyridine Dimethylamine Aminoethylethanolamine Ethylenediamine Aniline Monoethanolamine Monoisopropanolamine Morpholine Diethanolamine Pyridine Hexamethylenetetramine Diethylamine Triethanolamine Triethylenetetramine Diethylenetriamine Diisopropanolamine Trietylamine Trimethylamine Group 5: Halogenated Compounds Chlorohydrins, crude Ethylene dichloride Allyl chloride Dichlorobenzene 1,1,1-Trichloroethane Carbon tetrachloride Dichlorodifluoromethane Dichloropropane Trichloroethylene Chlorobenzene Chloroform Hexamethylenediamine Trichlorofluoromethane Ethyl chloride Ethylene dibromide Group 6: Alcohols, Glycols & Glycol Ethers Dipropylene glycol Hexanol Allyl alcohol Dodecanol Nonanol Amyl alcohol Ethyl alcohol Furfuryl alcohol 1,4-Butanediol Ethyl butanol Glycerine Butyl alcohols 2-Ethylbutyl alcohol Dextrose solution Heptanol Polypropylene glycol methyl ether Diacetone alcohol Propyl alcohols Diethylene glycol Propylene glycol Diisobutyl carbinol 2Ethylhexyl alcohol Ethylene glycol Sorbitol Octanol Undecanol Butylene glycol Corn syrup Cyclohexyl alcohol Decyl alcohols Triethylene glycol Chemical Hygiene Plan Part B Group 7: Aldehydes Furfural Acetaldehyde Hexamethylenetetramine Acrolein (inhibited) Isoctyl aldehyde Butyraldehyde Methyl butyraldehyde Crotonaldehyde Methyl formal Decaldehyde Propionaldehyde Formaldehyde solution Valeraldehyde Group 8: Ketones Diisobutyl ketone Acetone Isophorone Acetophenone Mesityl oxide Camphor oil Cyclohexanone Group 9: Saturated Hydrocarbons Methane Nonane Butane Paraffines Cyclohexane Pentane Ethane Petrolatum Heptane Petroleum Ether Hexanes Propane Isobutane Propylene butylene polymer Group 10: Aromatic Hydrocarbons Benzene Ethyl benzene Cumene Naphthalene Coal tar pitch Toluene Diethylbenzene Triethyl benzene Dodecyl benzene Xylene Group 11: Olefins Isobutylene Butylene 1-Octene 1-Decene 1-Pentene Dicyclopentadiene Polybutene Ethylene Propylene 1-Heptene Propylene butylene polymer Nonene 1-Hexene Group 12: Petroleum Oils Gasolines Asphalt Jet fuels Group 13: Esters Cottonseed oil Methyl acetate Amyl acetate Croton oil Methyl amyl acetate Amyl tallate Dibutyl phthalate Propyl acetates Chemical Hygiene Plan Butyl acetates Butyl benzyl phthalate Part B Epoxidized vegetable oils Ethyl acetate Ethyl diacetate Castor oil Resin oil Tanner's oil Wax, carnauba Glycol diacetate Group 14: Monomers & Polymerized Esters Butyl acrylate Acrylic acid Ethyl acrylate Acrylonitrile Methyl acrylate Propiolactone Butadiene Vinyl acetate Isoprene Vinyl chloride Vinylidene chloride Vinyl toluene Styrene Group 15: Phenols Cresols Carbolic oil Nonylphenol Creosote, coal tar Phenol Group 16: Alkylene Oxides Propylene oxide Ethylene oxide Group 17: Cyanohydrins Ethylene cyanohydrin Acetone cyanohydrin Adiponitrile Group 18: Nitriles Acetonitrile Group 19: Ammonia Ammonium hydroxide Group 20: Halogens Chlorine Bromine Group 21: Ethers Group 22: Phosphorous, elemental Diethyl ether (ethyl ether) 1,4-Dioxane Isoprophyl ether Tetrahydrofuran Group 23: Sulfur, molten Group 24: Acid anhydride Acetic anhydride Propionic anhydride Chemical Hygiene Plan Part B Table 2: Incompatible Chemical Classes 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 Inorganic Acids Organic Acids Caustics Amines and Alkenoamines Halogenated Compounds Alcohols, Glycols, & Glycol Ethers Aldehydes Ketones Saturated Hydrocarbons Aromatic Hydrocarbons Olefins Petroleum Oils Esters Monomers & Polymerizable Esters Phenols Alkylene Oxides Cyanohydrins Nitriles Ammonia Halogens Ethers Elemental Phosphorous Sulfur, Molten Acid Anhydrides 1 x x x x x x x 2 x x To be used with Table 3 3 x 4 x CHEMICAL CLASSES (With specific listing) 5 6 x x x x x x 7 x 8 9 x x 10 x 11 12 x x x x x x x x x x x x x x x x x x x x x x x x x x x 13 x x x x x x 14 x 15 x x x x x x x x x x x x x x x x 17 18 x 19 x x x x x x x 16 x x x x x x x x x x x x x x x x 20 x x 21 22 x 23 24 Chemical Hygiene Plan Part B Chemical Hygiene Plan Part B