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Geol 285 - Petrology, Dr. Helen M. Lang, West Virginia University, Spring 2009 Differentiation of Igneous Rocks: Crystal Fractionation and Layered Mafic Intrusions Igneous Rocks are grouped into Suites Rocks in a Suite might come from the same volcano (Kilauea), a group of island volcanoes (Hawaii, the Galapagos), a single intrusion (the Skaergaard intrusion, Greenland), a chain of volcanoes (the Cascades) Different magmas (rocks) in a Suite must be related by some process • • • • • Parental magma - the one from which others are descended highest liquidus temperature most primitive composition (hi MgO, low SiO2, low incompatible elements) large volume erupted Daughters, Differentiates, Derivatives - different names for the descendants Changes are displayed on Harker Diagrams (Metal Oxide vs. SiO2) Trends on AFM Diagrams Some Differentiation Processes that can change magma composition • • Crystal fractionation (We will talk mainly about this.) Magma mixing • Assimilation of country rocks Crystal Fractionation • • Crystals are removed from the liquid in which they formed Commonly by settling under the influence of gravity ρ (olivine) = 3.22 g/cm3 (Mg) - 4.30 g/cm3 (Fe) ρ (cpx) = 2.96-3.52 g/cm3 ρ (opx) = 3.21-3.96 g/cm3 ρ (plag) = 2.63-2.76 g/cm3 ρ (magmas) = 2.4 - 2.8 g/cm3 (calculated) Norman L. Bowen popularized Crystal Fractionation • • • He thought all igneous rocks came from a basaltic parent; mainly by crystal fractionation His idea was too extreme, but very important as a starting point This is the origin of Bowen’s Reaction Series - see handout from before Bowen's Reaction Series (BRS) is inadequate for generating most granite • • • Amount of basalt in crust is approximately equal to the amount of granite Bowen’s reaction series could only produce about 1/20 as much granite as the initial volume of basalt Where are all the fractionated mafic minerals? (there would have to be a huge amount of ultramafic cumulate rocks hiding at the base of the continental crust) Layered Mafic Intrusions are the best examples of Crystal Fractionation • • • Palisades Sill along Hudson River in NJ (see textbook) Bushveld Intrusion in South Africa, pC, colossal!! 320 km in diameter Skaergaard, Tertiary, E. Greenland** • • • • Muskox, northern Canada Great Dike, Zimbabwe Duke Island Complex, SE Alaska Stillwater, pC, Montana We did an imitation of a Layered Mafic Intrusion with the M&M® Magma Chamber Skaergaard in E. Greenland • • • • Perhaps the most studied rock body on Earth Best example of an igneous body that has fractionated to an extreme degree through crystal fractionation (Bowen’s idea) Most of its thickness is exposed Explored in 1930s, 1950s and 1970s Upper Zone Layered Series (Wager 1930s photo) Evidence for Crystal Settling • • • • • • Cumulus mineral textures, euhedral-subhedral grains piled up as if they settled in a liquid Sedimentary-like structures layering graded bedding cross-bedding slump structures, etc. Cumulus Mineral Texture Layering (variation in mineral proportions and sizes) Graded Bedding (coarsest at bottom) Cross-bedding Trough banding Skaergaard is an asymmetric lopolith - see handout Crystallization What is Sandwich Horizon? There are two kinds of Layering in the Layered Series • • Rhythmic Layering - changes in the identity and proportion of minerals Cryptic Layering - changes in chemical composition of minerals upwards through the layers (hidden, you can’t see it, must have chemical analyses of minerals) Original Skaergaard Magma was a Tholeiitic Basalt • Layering and compositional changes mainly resulted from crystal fractionation by gravity settling (fractional crystallization). Current Exposure (E-W cross section) The Layered Series - see handout Why does Olivine disappear in Middle Zone? Explained by Fo-En-SiO2 diagram - see previous handout Olivine reappears in Upper Zone; Fe-rich Olivine is OK in SiO2-rich liquid Ab-An Diagram explains why plagioclase composition changes from bottom to top of Skaergaard Note other cumulus minerals Remember, there are two kinds of Layering in the Layered Series • • Rhythmic Layering - changes in the identity and proportion of minerals Cryptic Layering - changes in mineral compositions upwards through the layers Crystal Fractionation to an Extreme Degree • • • Mafic minerals are all Fe-richer toward the top of layered series (Fe-end members have lower melting/crystallization temperatures) Plagioclase is more Na-rich toward the top (Na-plag crystallizes later and at lower temperature than Ca-plag) Quartz and micropegmatite represent the little bit of "granite" that can result from crystal fractionation of a tholeiitic basalt