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Organic: Reactions
1.
Chlorine gas, Cl2(g), is reacted with several hydrocarbons. When reacted with _________, one of the products of the
reaction will be hydrogen chloride, HCl(g)
a)
c)
2.
C6H6
C8H18
2-methyl butane
3,3-diethyl octane
hex- 2- ene
benzene
C4H10
C6H10
b)
d)
C5H12
C7H14
Butylpropanoate
Propylbutanoate
Butylpropanone
Propylbutenoate
water
water
Hydrogen
hydrogen
A student has been asked to prepare octylethanoate, an artificial orange flavour. The student could prepare the
octylethanoate by reacting ___________ with ______________.
a
b
c
d
7.
b)
d)
The esterification of propanol with butanoic acid forms _____________ and _____________
a
b
c
d
6.
C4H10
C7H14
Given 1.0 mol of each substances below, the compound that would require the most Br 2(l) for an addition reaction is ___
a)
c)
5.
C5H8
C6H6
Chemical properties of an unknown organic compound were tested with bromine and potassium permanganate solution.
It was found that the unknown compound decolorized potassium permanganate solution and gave a non- acidic product
with bromine. The unknown organic compound was most likely ____________________.
a)
b)
c)
d)
4.
b)
d)
A few drops of bromine, Br2(l), is added to each of the following hydrocarbons. The color of the bromine would disappear
the most quickly in ___________.
a)
c)
3.
C3H6
C5H10
Heptanol
Octanol
Ethanol
Octanol
Ethanoic acid
Ethanoic acid
Octanoic acid
Methanoic acid
Ethanol is a byproduct of the process of __________, where __________ reacts with ___________.
a
b
c
d
Hydrogenation
Hydration
Hydrogenation
Hydration
Ethane
Ethene
Ethene
ethane
Hydrogen
Water
Hydrogen
water
8.
Consider the following addition reaction.
CH3CHCHCH2CH3 + Cl2  _______________
The expected product(s) is/are ____________________________
a)
b)
c)
d)
9.
The most likely species to undergo a substitution reaction would be _________________
a)
b)
c)
d)
10.
2-methyl-prop-1-ene
o-dimethylbenzene
acetylene
but-2-yne
The most likely species to undergo an addition reaction would be ______________________
a)
b)
c)
d)
11.
2-chloropentane and hydrogen chloride
3,4-dichloropentane
2,3-dichloropentane
2-chloropent-3-ene and hydrogen chloride
benzoic acid
2-methylpropane
propyne
propan-1,2-diol
Name the most likely product(s) for the following reaction.
CH3CH2 CH3 + Cl2  ____________________________
a)
b)
c)
d)
12.
The most likely species to undergo a substitution reaction would be __________________
a)
b)
c)
d)
13.
1,2-dichloropropane and hydrogen
1-chloropropane and hydrogen
2-chloropropane and hydrogen chloride
3-chloroprop-1-ene and hydrogen chloride
3-methylpent-1ene
2,3 - dimethylbutane
1,1-dichlorobut-2-yne
octa-1,3-diene
The most likely species to undergo an addition reaction would be ___________________
a)
b)
c)
d)
p-chlorofluorobenzne
2-phenylpropane
propyne
propan-1,2-diol
14.
Compounds that will undergo addition reactions are:
a)
b)
a)
a)
15.
alcohols and alkanes
alkenes and alkynes
aromatics and alkanes
esters and aromatics
If an alkene undergoes hydration it will form _______whereas when it undergoes hydrogenation it will form a(n) _______.
a)
b)
c)
d)
alkane, alcohol
alkyne, acid
aromatic, alcohol
alcohol, alkane
16. The organic compound that will undergo an addition reaction with F 2(g) is
a)
b)
c)
d)
17.
C4H8
C6H6
CCl4
CH3COOH
The ester ethylmethanoate is formed by the reaction between the alcohol ______ and the carboxyllic acid _________
a)
b)
c)
d)
18.
C2H5OH, HCOOH
CH3OH, CH3OOH
C2H5OH, CH3COOH
CH3OH, HCOOH
Consider the incomplete reaction as follows:
C2H4(g) + Br2(l)  product
This is a(n) _________ reaction and the product(s) will be _____________
a
b
c
d
19.
Addition
Addition
Substitution
substitution
Bromoethane and hydrogen bromide
1,2-dibromoethane
Bromoethane and hydrogen bromide
1,2-dibromoethane
A sample of propene undergoes a reaction with chlorine.
The reaction will be called a(n) _________ reaction, and the product(s) will be _____________
a)
b)
c)
d)
substitution, 1-chloropropane and hydrochloric acid
addition, 1,1-dichloropropane
substitution, 1,2-dichloropropane
addition, 1,2-dichloropropane
20.
Consider the diagram below. It is formed by the addition of _____________ and _____________
CH3COOCH2CH2CH2CH3
a)
b)
c)
d)
21.
hexanoic acid, water
butanol, ethanoic acid
ethanol, butanoic acid
propanol, water
The chemical below that is most likely to undergo an addition reaction with Br 2(l) is
a)
b)
c)
d)
22.
benzene
fluoroethane
acetylene
ethanol
Consider the reactions in the table below.
prop-1-ene + chlorine  1,2-dichloropropane
ethanol  ethene + water
ethane + fluorine  fluorethane + hydrogen fluoride
benzene + bromine bromobenzene + hydrogen bromide
Methanol + Ethanoic acid  methylethanoate + water
There is / are _________ addition reaction(s) given in the table above.
a)
1
b)
2
c)
3
d)
4
23. Numerical response question
Left justify your answer in the boxes provided.
Jake just bought a propane-fuelled mini-bus. The combustion of propane can be written as:
a C3H8(g) + b O2(g)  c CO2(g) + d H2O(g)
Balance the equation with the lowest possible whole numbers and record the values of ‘a,b,c,d’ in that order
24. Numerical response question
Left justify your answer in the boxes provided.
Colin mixed a sample of Ethanoic acid and methanol in the presence of a catalyst.
Identify the product(s) for this esterification reaction. Record the answers in ascending order
1. Ethyl methanoate
2. Methyl ethanoate
3. Water
4. Ethyl ethanoate
5. Methyl methanoate
Solutions:
1.
2.
3.
4.
5.
6.
7.
8.
9.
10.
11.
12.
13.
14.
15.
16.
17.
18.
19.
20.
21.
22.
23.
24.
D
C
C
C
B
B
B
C
B
C
C
B
C
B
D
A
A
B
D
b
C
A
1534
23
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