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B. Sc. (HONS.) INDUSTRIAL CHEMISTRY, SEMESTER-I S. N. Course code Subject Periods Theory Professional Communication L 03 T 01 P 00 Evaluation Scheme Sessional ESE CT TA Total 30 20 50 100 Subject Total 1. BIC-101 150 2. BIC -102 Elementary Mathematics 03 01 00 30 20 50 100 150 3. BIC-103 Inorganic Chemistry-1 03 01 00 30 20 50 100 150 4. BIC-104 Organic Chemistry-I 03 01 00 30 20 50 100 150 5. BIC-105 Physical Chemistry-1 03 01 00 30 20 50 100 150 Practicals 6. BIC -106P Industrial chemistry Lab 00 00 06 20 20 40 60 100 7. GP-101 00 00 00 00 00 50 00 50 General proficiency Total 900 PROFESSIONAL COMMUNICATION BIC- 101 LTP 310 Unit I -Technical written communication 10 A. Theory Significance, Distinctive features, The Audience factor, Technical writing VS General writing. B. Forms (i) Technical Reports: Meaning and Significance; Basic Categories (Informational, Analytical, Routine) Types: (Progress report, Lab report, Incident report, Feasibility report) (Front matter, Body, Back matter) (ii) Scientific articles & Dissertation (Source material, Topic sentence, Literature review) Tables, Figures, Footnotes, Bibliography, References (iii) Technical Proposal Definition & Types structure (Technical section, Management section, Financial section) Statement of request Unit II-Basics of Good Writing 10 (a) Remedial Grammar: (i) Sentence Errors (Sentence Fragments, Comma Splices, Fused Sentences, Sequence of Tenses, Subject-Verb Agreement, Problematic Nouns & Pronouns, Antecedents, Articles. (ii) Sentence Structure (Position of Modifiers, Connectives, Choppy Sentences, Illogical Comparisons, Split Infinitive, Parallelism, Punctuation). (b) Mechanics: Italics, Hyphenation, Capitalization, Apostrophe, Numbers. (c) Strategies of Text Organization: Coherence, Unity Deductive Method, Inductive Method, Spatial Method, Chronological Method, Linear Method, Interrupted Method. Unit III-Business Correspondence 10 Principles; Components of Business Letters; Letters of Enquiry; Response to Enquiry; Letter of Complaint; Adjustments; Job Application Letters ; Resume. Aspects of Spoken English Stress; Intonation; Rhythm; Phonemes; Allophones; Phonetic Alphabet Unit IV-Language through Literature A. (Essays) 1. Science and Human Life 10 JBS Haldane 2. Water C.V. Raman 3. A Bookish Topic R.K. Narayan 4. Of Studies Francis Bacon 5. The Civilization of Today C.E.M. Joad 6. Making Writing Simple J.B. Priestley B. 1. (Short Fiction) The Lament A. Chekhov 2. The Fly Catherine Mansfield 3. The Gift of Magi O’ Henry 4. The Barber’s Trade Union Mulk Raj Anand 5. The Eyes are not Here Ruskin Bond 6. Two Words to Avoid, Two to Remember Arthur Gordon Books recommended: 1. Huckin, T.N., and L.A. Olson. Technical Writing and Professional Communication for NonNative Speakers of English Mcgraw-Hill, Ny, 1991. 2. Alvarez, Joseph A., The Elements Of Technical Writing, New York Harcourt, 1998. 3. Gerson, S., Technical Writing: Process and Product (4th Edition), Pearson Education Asia, 2000. 4. J. Leech, & Svartvik, A Communicative Grammar of English (Pearson Education Asia,) 2003. 5. John Seely, Oxford Guide to Writing and Speaking (Oup), 2000. 6. Jones, Daniel, English Pronouncing Dictionary, Elbs, Longman, 1999. Elementary Mathematics BIC-102 LTP 310 UNIT I 10 Calculus: Limits and functions, definition of differential coefficient, differentiation of functions including function of a function, differentiation parametric forum, simple and successive differentiation. UNIT II: 10 Integration: Integration as inverse of differentiation, Indefinite integrals of standard forum, Integration by parts, substitution method and partial fraction method. Evaluation of definite integers. Unit III: 10 Statistics: Methods of sampling, measures of central tendency (mean, median and mode), measures of variation (mean deviation and standard deviation). Covariance, Karl Pearson’s Coefficient of Correlation. Regression, method of least squares UNIT IV: 10 Probability: Random experiment and associated sample space, events definition of probability, algebra of events, addition and multiplication theorems on probability (without proof). Binomial, Poisson and Normal distributions analysis. Permutation, Combination and Binomial Theorem: Fundamental principle of counting, Permutations, permutations under certain conditions. Combinations, Combinatorial identities. Binomial theorem (without proof),some applications of Binomial theorem. Books recommended: Seymour Lipschutz, 1981, Set Theory, (Schaum’s Outline Series) McGraw-Hill Book Co. Frank Ayres, J.R., 1974, Matrices, (Schaum’s Outline Series) McGraw-Hill Inc. Murray R. Spiegel, 1980, Probability and Statistics, Schaum’s (Outline Series) McGraw-Hill Book Co. Arora, P.N. and P.K. Malhan, 2002, Biostatistics, Himalaya Publishing House. E. Kreyszig, “Advanced Engineering Mathematics”, 5th Edition, Wiley Eastern, 1985. Mathematics, NCERT. Mathematics R.D. Sharma. Higher Engineering Mathematics, B. V. Ramana. Tata McGraw Hill Publishers. Inorganic Chemistry-I BIC-103 LTP 310 Unit I: Atomic Structure 10 Idea of de Broglie matter waves, Heisenberg uncertainty principle, atomic orbitals, Schrödinger wave equation, significance of ψ and ψ2, quantum numbers, radial and angular wave functions and probability distribution curves, shapes of s, p, and d orbitals. Aufbau and Pauli exclusion principles, Hund’s multiplicity rules. Electronic configurations of the elements, effective nuclear charge. Unit II: Periodic Properties 10 Atomic and ionic radii, ionization energy, electron Affinity and electronegativity: definition, method of determination, trends in periodic table and applications. Unit III: Chemical Bonding 10 Covalent bond- valence bond theory and its limitations, directional characteristic of covalent bond. Hybridization and shapes of simple molecules and ions. Valence Shell Electron Pair Repulsion (VSEPR) theory to NH3, SF4, ClF3, ICl4 and H2O Molecular Orbital theory for homonuclear and heteronuclear (CO and NO) diatomic molecules, multi-center bonding in electron deficient molecules, bond strength and the bond energy, % ionic character from dipole moment and electronegativity difference. Weak interactions , hydrogen bonding, van der Waals forces. Unit IV: Ionic Solids 10 Ionic structures , radius ratio effect and coordination number, limitation of radius ratio rule, Lattice defects, semiconductors, lattice energy and Born-Haber cycle, solvation energy and solubility of ionic solids, polarizing power and polarizability of ions. Fajan.s rule, Metallic bond free electron, Valance bond and Band theories Books recommended: Advanced Inorganic Chemistry Vol-I & II, Satya Prakash, G.D. Tuli, S.K. Basu, R.D. Madan, S. Chand & Co. Ltd. Test book of Inorganic Chemistry, P.L. Soni, Sultan Chand & Sons Simplified Course in Inorganic Chemistry, Madan & Tuli, S. Chand & Co. Ltd. Concise Inorganic Chemistry, J.D. Lee, Black Well Sciences Organic Chemistry-I BIC-104 LTP 310 Unit-I 10 Structure, Bonding and intermediates; Hybridizations, Bond lengths and bond angles, bond energy: Localized and delocalized chemical bond, resonance, hyperconjugation, aromaticity, inductive and field effects, hydrogen bonding. Unit-II 10 Electrophiles and nucleophiles. Types of organic reactions. Energy consideration. Reactive intermediates- carbocations, carbanions, free radicals and carbenes. Methods of determination of reaction mechanism. Unit-III 10 IUPAC nomenclature, classification, isomerism, properties and preparation of alkanes, alkene and alkynes. Mechanisms of dehydration of alcohols and dehydrohalogenation of alkyl halides, Saytzeff rule, Hoffmann elimination, Chemical reactions of alkenes mechanisms involved in hydrogenation, electrophilic and free radical additions, Markownikoff.s rule, hydroborationoxidation oxymercuration reduction, Epoxidation, ozonolysis, hydration, hydroxylation and oxidation with KMnO4, Substitution at the allylic positions of alkenes Unit-IV 10 Stereochemistry; Concept of isomerism, types of isomerism, optical isomerism, elements of symmetry, molecular Nomenclature E and Z system, geometrical isomerism in alicyclic compounds. Conformation, conformational analysis of n-butane. Conformations of cyclohexanes, axial and equatorial bonds, Newman projection, Saw horse projection , Fischer projection. Books recommended: Advanced Organic Chemistry, Bahl & Bahl, S. Chand & Co. Ltd. Organic Chemistry Vol.I & II, I.L. Finar Fundamentals of Organic Chemistry, Nafis Haider, S. Chand & Co. Ltd. A text book of Organic Chemistry, Bahl & Bahl, S. Chand & Co. Ltd. Organic Chemistry Vol.I, II & III, Dr. Jagdamba Singh, L.D.S. Yadav, Pragati Prakashan. Physical Chemistry-I BIC-105 LTP 310 Unit-I: Gaseous States 10 Postulates of kinetic theory of gases, deviation from ideal behaviour, vander Waals equation of State. PV isotherms of ideal gases, continuity of states, the isotherms of van der Waals equations, relationship between critical constants and van der Waals constants, the law of corresponding states, reduced equation of states. Root mean square, average and most probable velocities. Liquification of gases( based on Joule Thompson effect). Unit II: Solid State 10 Definition of space lattice, Unit cell Laws of crystallography - (i) Law of constancy of interfacial angles (ii) Law of rationality of indices (iii) Laws of symmetry. Symmetry elements in crystals. X-ray diffraction by crystals. Derivation of Bragg’s equation. Unit-III: Electrochemistry 10 Galvanic cells, standard electrode potential, types of electrodes, measurement of pH; Solubility and solubility product and its applications. Unit-IV: Chemical and Phase Equilibrium 10 Equilibrium constant and free energy. Thermodynamic derivation of law of mass action. Le Chateliers principle. Reaction isotherm and reaction isochor - Clapeyron equation and Clausius Clapeyron equation, applications. Statement and meaning of the terms - phase, component and degree of freedom, derivation of Gibbs phase rule, phase equilibria of one component system - water, and sulphur system. Books recommended: Essentials of Physical Chemistry, Bahl & Tuli, S. Chand & Co. Ltd. Principles of Physical Chemistry, Puri, Sharma & Pathania, Vishal Publishing Co. Simplified course in Physical Chemistry, Madan & Tuli, S. Chand & Co. Ltd. Atkin’s Physical Chemistry, Atkin, Oxford Press. Physical Chemistry, Vemulapalli, Prentice Hall of India Modern Physical Chemistry, R.P. Rastogi et al. United Book Department, Allahabad Industrial chemistry Lab BIC-106P Acid-base titrations. Preparation of solutions related to molarity & normality. Preparation of solutions, buffers- sensitivity, specificity, accuracy, pH measurements. To compare the strength of HCl and H2SO4 by studying the kinetics of hydrolysis of ester. To determine the velocity constant (specific reaction rate) of hydrolysis of methyl acetate/ethyl acetate catalyzed by hydrogen ions at room temperature. Oxidation-reduction titration using KMnO4 and K2Cr2O7. Iodometry titrations: Estimation of potassium dichromate and copper sulphate. Detection of functional groups present in organic compounds. Detection of elements present in organic compounds. Determination of acetic acid in commercial vinegar using NaOH.