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Botany Student Outline – Essential Chemistry for Botany Essential Chemistry for Botany 1. Introduction A. Organic i. Monomers a. Carbohydrate Example: Glucose – C6H12O6 • b. ii. 2. Isomers Example: Amino Acid Polymers Carbohydrates A. Monosaccharide • Dehydration Synthesis Reaction Page 1 Botany Student Outline – Essential Chemistry for Botany B. Disaccharides * Maltose – glucose + glucose * Sucrose – glucoes + fructose * Lactose - glucose + galactose C. Polysaccharide i. Structural Polysaccharides • Glucose Bonds a. Cellulose • Microfibril Page 2 Botany Student Outline – Essential Chemistry for Botany ii. iii. 3. Storage Polysaccharids a. Amylose b. Amylopectin c. Inulin Storage Polysaccharids and Enzymes Proteins A. Structure i. Amino Acid NH 2 C NH NH CH2 CH2 OH NH 2 C COOH NH 2 C H H Serine Glycine CH2 CH3 H CH2 COOH NH2 C H Alanine Page 3 COOH NH2 C COOH H Araginine (E) Botany Student Outline – Essential Chemistry for Botany ii. a. Nonessential Amino Acids b. Essential Amino Acids Peptide Synthesis iii. B. C. Protein Structure a. Hydrogen Bonds b. Structural Classifications • Primary Structure • Secondary Structure • Tertiary Structure • Quaternary Structure c. Denaturation Glycoproteins i. Expansins a. extensin Functions i. Storage ii. Enzymes Page 4 Botany Student Outline – Essential Chemistry for Botany 4. Nucleic Acids A. Nucleotide i. Phosphate ii. Sugar a. Deoxyribose (in DNA) b. Ribose (in RNA) iii. Base a. Pyrimidines • Cytosine (and methylcytosine) • Thymine (in DNA) • Uricil (in RNA) b. Purines • Adenine • Guanine B. Forms i. DNA ii. RNA Page 5 Botany Student Outline – Essential Chemistry for Botany 5. 6. Lipids A. Glycerides: Basic Structure i. Glycerol ii. Fatty Acids a. Alpha End b. Omega End • – 3, – 6, –9 c. Chain Length iii. Assembly a. Ester bond * Esterification * Deesterification * Reesterification. • Mononglycerides • Diglycerides • Triglycerides iv. Saturated v. Unsaturated a. Monounsaturated * Canola Oil * Olive Oil b. Polyunsaturated * Corn Oil vi. Hydrogenation of Plant Oils a. Cis • Oleic Acid b. Trans c. Effect • Cell Membrane vii. Essential Fatty Acids a. Linolenic Acid (omega 3 ) b. Linoleic Acid (omega 6) c. Functions • Membrane Structure B. Phospholipids • Lecithin Waxes A. Cuticle i. Epicuticular Wax ii. Cutin Page 6 Botany Student Outline – Essential Chemistry for Botany 7. Metabolites • Glycosides A. Functions B. Major Metabolite Classification i. Alkaloids ii. Terpenoids from Reuch a. Classificaiton of Terpenoids • Monoterpenes • Diterpenes * Example: Giberellins • Triterpenes * Sterols • Carotenoids * Example: Beta Carotene Page 7 Botany Student Outline – Essential Chemistry for Botany iii. Phenolics a. Simple Phenolics b. Phenylpropanoids c. Flavonoids • Anthocyanins Phenolic Polymers • Tannin • Lignin (figure 2.15) polymeric phenylpropanoids d. Page 8 Botany Student Outline – Essential Chemistry for Botany C. Minor Metabolite Classification i. Cyanogenic Glycosides a. Example: Cassava b. Basic Chemistry Linamarin (Cyanogenic Glycoside) Page 9