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What is limestone?
Limestone = a biochemical sedimentary rock
made up mostly of calcium carbonate
Mineral
Crystal system
Formula
Remarks
Calcite
Rhombohedral
CaCO3
Dominant limestone mineral,
especially in rocks older than
Cenozoic
Aragonite
Orthorhombic
CaCO3
Dominant mineral in Recent
carbonate sediments; alters readily
to calcite
How do limestones form?
Most limestones are simply the
cemented remains of marine shells
Limestone “anatomy”

Grains
 Skeletal particles, ooids, peloids

Lime mud
 Microscopic crystals produced by calcareous
algae and through abrasion of larger particles

Cement
 Inorganically precipitated CaCO3 crystals
Skeletal grains
ooids
peloids
Lime mud
Calcite cement
Factors affecting precipitation
of CaCO3 in sea water
Factor
Type of change
Physical effect
Effect on CaCO3
Temperature
Increase
Loss of CO2,
increase in pH
Increase
precipitation
Pressure
Decrease
Loss of CO2,
increase in pH
Increase
precipitation
Salinity
Decrease
Decrease activity
of “foreign”
cations
Increase
precipitation
Photosynthesis
Removes CO2 from sea water; pH
increases
Increase
precipitation
Bacterial activity
Catalyzes CaCO3 precipitation
Increase
precipitation
Where do limestones form?
Because CaCO3 precipitates most
readily in warm, well lit, agitated water
of normal marine salinity…..most
limestones form in shallow, tropical
depositional environments

e.g., Bahamas, central America, Persian
Gulf, NW shelf of Australia, Great Barrier
Reef, Malaysia, Indonesia, etc.
Modern CaCO3 depositional
environments
*Note: Although cool water carbonates
Are forming in many places, they are
highly prone to dissolution and therefore
do not become major limestone accumulations
Caicos Platform
Reef tract
Quiet water
high-energy
sand shoals
Prevailing
winds
North America during the
Devonian Period
Iowa during the Devonian
Period
What are limestone products?
Whole rock


Crushed limestone
Dolomitic limestone
Burned lime (calcium oxide)


High calcium lime
Dolomitic lime
Hydrated lime (calcium hydroxide)
How is limestone used?
Construction
Soil stabilization
Flue Gas Desulfurization
Steel Production (flux for blast furnaces)
Glass Production
Water Treatment
Waste Treatment
Paper Production (filler)
Chemical Production
Masonry, Mortars and Other Building Materials
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